Fast fabrication of fiber reinforced polymers using solid epoxy powder containing an initiator

Patent metadata

Field	Value
Publication number	US-11866559-B2
Application number	US-202117147217-A
Country	US
Kind code	B2
Filing date	Jan 12, 2021
Priority date	Jan 12, 2021
Publication date	Jan 9, 2024
Grant date	Jan 9, 2024

Abstract

A method of manufacturing includes producing a powder resin comprising a polymer precursor and a thermal initiator, packing a fiber structure with the powder resin, resulting in a resin-packed structure, and heating the resin-packed structure to a curing temperature high enough to melt and cure the resin-packed structure to form a final structure.

First claim

What is claimed is:

1. A method of manufacturing fiber reinforced polymers comprising:
producing a powder resin comprising a polymer precursor and a thermal initiator, wherein the powder resin is produced by mixing an epoxy monomer as the polymer precursor in a concentration range of 80-99.99 wt % and thermal initiator in a concentration range of 0.001-20 wt %;
packing a fiber structure with the powder resin resulting in a resin-packed structure by one or more of repeatedly spraying the powder resin onto a layer of the fiber structure and adding layers, densifying the powder resin, electrodepositing the powder resin, and rolling the powder resin over the fiber structure; and
heating the resin-packed structure to a curing temperature high enough to melt and cure the resin-packed structure to form a final structure.

2. The method as claimed in claim 1 , wherein producing a powder resin comprises:
mixing the polymer precursor and the thermal initiator in a solvent to form a mixture;
removing the solvent and drying the mixture to form a solid;
grinding the solid to produce powder resin.

3. The method as claimed in claim 1 , further comprising adding protective layers to the fiber structure.

4. The method as claimed in claim 1 , wherein the fiber structure comprises a pre-formed fiber structure.

5. The method as claimed in claim 1 , wherein the fiber structure comprises at least one mat and the method further comprises shaping the resin-packed structure either prior to or during the heating.

6. The method as claimed in claim 5 , wherein shaping the resin-packed structure comprises vacuum and autoclave compressing the resin-packed structure.

7. The method as claimed in claim 1 , wherein heating the resin-packed structure comprises heating the resin-packed structure in a chamber at a temperature of at least 60° C.

8. The method as claimed in claim 1 , wherein producing the resin powder comprises producing one selected from the group consisting of: solid epoxy with solid amine and solid epoxy with anhydride.

9. The method as claimed in claim 1 , wherein producing the resin powder comprises producing one selected from the group consisting of: thermoplastic polyurethane powder, polyether powder, vinyl ester powder, and nylon powder.

10. The method as claimed in claim 1 , wherein the powder resin is comprised of particles having a size in the range of 1 μm to 500μ.

11. The method as claimed in claim 1 , wherein the powder resin comprises two components in a combination, wherein the combination comprises one of: a solid epoxy with one of solid amine or anhydride, a powder resin containing both epoxy and one of either amine or anhydride, or two powder resins wherein one contains epoxy and one contains one of either amine or anhydride but mixed for packing.

12. The method as claimed in claim 11 , wherein the melting point of a first of the two components is lower than the melting point of a second of the two components is such that the first component wets and infiltrates the fiber structure before the second component melts to start the curing.

13. The method as claimed in claim 1 , wherein producing the resin powder comprises adding particle fillers to the polymer precursor and the thermal initiator.

14. The method as claimed in claim 13 , wherein the at least one particle filler comprises at least one selected from the group consisting of: clay, graphene, and fumed silica.

15. The method as claimed in claim 1 , wherein the fiber structure has a shape that is one of a single fiber, a tow of fiber, and a fabric having a pattern of at least one of a unidirectional pattern, a 1×1 pattern, a 2×2 twill weave pattern, a 4 Harness-Satin pattern, a 5 Harness-Satin pattern, an 8 Harness-Satin pattern, and a 4×4 twill weave pattern.

Assignees

• Palo Alto Res Ct Inc
• Xerox Corp

Inventors

• Wei Junhua
• Iftime Gabriel
• Benedict Michael
• Chintapalli Mahati

Classifications

• C08J5/243 Primary

  using carbon fibres · CPC title

• C08K3/042

  Graphene or derivatives, e.g. graphene oxides · CPC title

• C08K3/346

  Clay · CPC title

• C08K3/36

  Silica · CPC title

• C08L101/00

  Compositions of unspecified macromolecular compounds · CPC title