Method of producing a mineral wool product comprising a multiple of lamellae and a product of such kind

Patent metadata

Field	Value
Publication number	US-11865826-B2
Application number	US-202318160130-A
Country	US
Kind code	B2
Filing date	Jan 26, 2023
Priority date	May 13, 2016
Publication date	Jan 9, 2024
Grant date	Jan 9, 2024

Abstract

A method and a mineral wool product include a multiple of lamellae, such as a sandwich panel core. The product includes a plurality of lamellae cut from a mineral wool web, and bonded together by applying an adhesive on the surfaces of two adjacent lamellae to form a web-like product, wherein the adhesive comprises at least one hydrocolloid.

First claim

What is claimed:

1. A method of producing a mineral wool product comprising a multiple of lamellae, said method comprising the steps of:
providing a cured mineral wool web;
cutting said mineral wool web longitudinally into a plurality of lamellae;
turning each of the plurality of lamellae 90° about their longitudinal axis;
bonding the lamellae in the turned orientation together by an adhesive on surfaces of two adjacent of the plurality of turned lamellae; and
curing the adhesive, the step of curing comprising a drying process involving blowing air or gas through the mineral wool product, the step of curing being carried out at temperatures from 5 to 95° C., wherein the adhesive comprises at least one hydrocolloid,
wherein the adhesive comprises:
proteins from vegetable sources, and the adhesive further comprises at least one phenol containing compound, wherein the at least one phenol containing compound is tannin selected from one or more components from the group consisting of tannic acid, condensed tannins (proanthocyanidins), hydrolysable tannins, gallotannins, ellagitannins, complex tannins, and tannin originating from one or more of oak, chestnut, staghorn sumac and fringe cups, and/or proteins from vegetable sources, and wherein the adhesive further comprises at least one enzyme selected from the group consisting of transglutaminase (EC 2.3.2.13), protein disulfide isomerase (EC 5.3.4.1), thiol oxidase (EC 1.8.3.2), polyphenol oxidase (EC 1.14.18.1), lysyl oxidase (EC 1.4.3.13), and peroxidase (EC 1.11.1.7);
and a density of the mineral wool product being in the range of 50-300 kg/m3.

2. The method according to claim 1 , further comprising applying the adhesive to a surface of the cured mineral wool web before cutting the mineral wool web into lamellae.

3. The method according to claim 1 , wherein the at least one hydrocolloid is selected from the group consisting of gelatine, pectin, starch, alginate, agar, carrageenan, gellan gum, guar gum, gum arabic, locust bean gum, xanthan gum, and cellulose derivatives.

4. The method according to claim 1 , wherein the at least one hydrocolloid is a polyelectrolytic hydrocolloid.

5. The method according to claim 1 , wherein the at least one hydrocolloid is selected from the group consisting of gelatine, pectin, alginate, carrageenan, gum arabic, xanthan gum, and cellulose derivatives.

6. The method according to claim 1 , wherein at least one hydrocolloid of the adhesive comprises at least two hydrocolloids, wherein one hydrocolloid is gelatine and the at least one other hydrocolloid is selected from the group consisting of pectin, starch, alginate, agar, carrageenan, gellan gum, guar gum, gum arabic, locust bean gum, xanthan gum, and cellulose derivatives.

7. The method according to claim 6 , wherein the gelatine is present in the adhesive in an amount of 10 to 95 wt. % based on the weight of the hydrocolloids.

8. The method according to claim 6 , wherein the one hydrocolloid and the at least one other hydrocolloid have complementary charges.

9. The method according to claim 1 , wherein the adhesive is not a thermoset adhesive.

10. The method according to claim 1 , wherein the adhesive does not contain a poly(meth)acrylic acid, a salt of a poly(meth)acrylic acid or an ester of a poly(meth)acrylic acid.

11. The method according to claim 1 , wherein the at least one hydrocolloid is a biopolymer or modified biopolymer.

12. The method according to claim 1 , wherein the adhesive is formaldehyde-free.

13. The method according to claim 1 , wherein the adhesive further comprises
at least one of
at least one oil,
at least one pH-adjuster,
at least one crosslinker,
at least one anti-fouling agent,
at least one anti-swelling agent, and water.

14. The method according to claim 1 , wherein the mineral wool product is a sandwich panel core.

15. The method according to claim 1 , wherein the adhesive corresponds with a binder in the mineral wool product.

16. The method according to claim 1 , wherein the step of curing comprising a drying process further comprises increasing temperature.

17. The method according to claim 1 , wherein a main fibre orientation of the mineral wool is substantially in a plane perpendicular to surfaces of the mineral wool product after the bonding.

18. The method according to claim 1 , wherein the density of the mineral wool product is in the range of 50-200 kg/m3.

19. The method according to claim 1 , wherein the polyphenol oxidase (EC1.14.18.1) is catechol oxidase, tyrosine oxidase and phenoloxidase.

20. The method according to claim 3 , wherein the cellulose derivatives is carboxymethylcellulose, arabinoxylan, cellulose, curdlan, or β-glucan.

21. The method according to claim 5 , wherein the cellulose derivatives is carboxymethylcellulose.

22. The method according to claim 6 , wherein the cellulose derivatives is carboxymethylcellulose, arabinoxylan, cellulose, curdlan, or β-glucan.

23. The method according to claim 1 , wherein the adhesive is cured in the bonding step in not more than 120 seconds.

24. The method of claim 1 , wherein the step of curing is carried out at temperatures from 10 to 80° C.

25. The method of claim 1 , wherein the step of curing is carried out at temperatures from 20 to 60° C.

26. The method of claim 1 , wherein the step of curing is carried out at temperatures from 40 to 50° C.

27. The method according to claim 6 , wherein the gelatine is present in the adhesive in an amount of 20 to 80 wt. % based on the weight of the hydrocolloids.

28. The method according to claim 6 , wherein the gelatine is present in the adhesive in an amount of 30 to 70 wt. % based on the weight of the hydrocolloids.

29. The method according to claim 6 , wherein the gelatine is present in the adhesive in an amount of 40 to 60 wt. % based on the weight of the hydrocolloids.

30. The method according to claim 1 , wherein the density of the mineral wool product is in the range of 65-100 kg/m3.

Assignees

• Rockwool Int
• Rockwool As

Inventors

• Hjelmgaard Thomas
• Meres Oskar
• Jacobsen Bent

Classifications

• B32B37/12 Primary

  characterised by using adhesives · CPC title

• B32B5/12 Primary

  characterised by the relative arrangement of fibres or filaments of {different layers, e.g. the fibres or filaments being parallel or perpendicular to each other} · CPC title

• B32B5/26

  another layer {next to it} also being fibrous or filamentary {(relative arrangement of fibres or filaments of different layers B32B5/12)} · CPC title

• B32B7/12

  using interposed adhesives or interposed materials with bonding properties · CPC title

• B32B15/14

  next to a fibrous or filamentary layer · CPC title