Abrasive article

Patent metadata

Field	Value
Publication number	US-11865673-B2
Application number	US-201816770652-A
Country	US
Kind code	B2
Filing date	Dec 6, 2018
Priority date	Dec 8, 2017
Publication date	Jan 9, 2024
Grant date	Jan 9, 2024

Abstract

The disclosure relates to layers comprising a body having a thickness, T, comprising a curable composition comprising a polymerizable epoxy-acrylate resin composition and abrasive particles at least partially embedded in the polymerizable epoxy-acrylate resin composition, wherein the body includes a plurality of void spaces free of the curable composition extending into the body from the first major surface and the depth of the plurality of void spaces is at least 10 percent of thickness T. The disclosure also relates to cured compositions formed from such curable compositions and, in turn, abrasive articles made from such cured compositions as well as methods for making abrasive articles.

First claim

What is claimed is:

1. A layer for an abrasive article, the layer comprising:
a body having a thickness, T, comprising:
a first major surface; and
a second major surface opposite the first major surface;
the body comprising a curable composition comprising:
(a) a polymerizable epoxy-acrylate resin composition comprising from about 15 to about 50 parts by weight of an acrylic copolymer relative to 100 parts of the curable composition and having a complex viscosity at 25° C. and 1 Hz frequency of about 1,000 Pa-s to about 100,000 Pa-s and a complex viscosity at 125° C. and 1 Hz frequency of about 10 Pa-s to about 10,000 Pa-s; and
(b) abrasive particles at least partially embedded in the polymerizable epoxy-acrylate resin composition; and

wherein the body includes a plurality of void spaces free of the curable composition extending into the body from the first major surface and the depth of the plurality of void spaces is at least 10 percent of thickness T.

2. The layer of claim 1 , wherein at least a portion of the plurality of void spaces extend to the second major surface.

3. The layer of claim 1 , wherein the plurality of void spaces forms a regular or an irregular pattern.

4. The layer of claim 1 , wherein the acrylic copolymer comprises a tetrahydrofurfuryl (THF) (meth)acrylate copolymer component, and the polymerizable epoxy-acrylate resin composition further comprises one or more epoxy resins and one or more hydroxy-functional polyethers.

5. The layer as in claim 4 , wherein the polymerizable epoxy-acrylate resin composition further comprises at least one polyhydroxyl-containing compound.

6. The layer of claim 1 , further comprising one or more photoinitiators.

7. The layer of claim 4 , wherein the THF (meth)acrylate copolymer component comprises one or more polymerized THF (meth)acrylate monomers, one or more polymerized C 1 -C 8 (meth)acrylate ester monomers, and one or more optional polymerized cationically reactive functional (meth)acrylate monomers.

8. The layer of claim 4 , wherein the THF (meth)acrylate copolymer component comprises polymerized monomer units of: (A) 40-60 wt % of tetrahydrofurfuryl (meth)acrylate; (B) 40-60 wt % of C 1 -C 8 alkyl (meth)acrylate ester monomers; and (C) 0-10 wt % of cationically reactive functional monomers, wherein the sum of (A)-(C) is 100 wt % of the THF (meth)acrylate copolymer.

9. The layer of claim 4 , wherein the curable composition comprises: i) the acrylic copolymer; ii) from about 25 to about 50 parts by weight of the one or more epoxy resins; iii) from about 5 to about 15 parts by weight of the one or more hydroxy-functional polyethers; iv) in the range of from about 10 to about 25 parts by weight of at least one polyhydroxyl-containing compound; where the sum of i) to iv) is 100 parts by weight; and v) from about 0.1 to about 5 parts by weight of a photoinitiator, relative to the 100 parts of i) to iv).

10. The layer of claim 4 , wherein the one or more hydroxy-functional polyethers is a liquid at a temperature of 25° C. and pressure of 1 atm (101 kilopascals).

11. The layer of claim 6 , wherein the photoinitiator is a cationic photoinitiator.

12. The layer of claim 1 , wherein at least a portion of the abrasive particles comprise shaped abrasive particles.

13. A layer for an abrasive article, the layer comprising:
a body comprising:
a first major surface;
a second major surface opposite the first major surface;
wherein the body comprises the polymerization product of the curable composition according to claim 1 and wherein the body includes a plurality of void spaces free of the polymerization product of the curable composition and the depth of the plurality of voids is spaces is at least 10 percent of thickness T.

14. The layer of claim 13 , wherein at least a portion of the plurality of void spaces extend to the second major surface.

15. The layer of claim 13 , wherein the polymerized epoxy-acrylate resin composition has a stiffness of from about 0.01 to about 0.2 N-mm.

16. An abrasive article comprising the layer as in claim 13 as an abrasive layer.

17. The abrasive article of claim 16 , further comprising at least one of a size coat, a supersize coat, and a backing.

18. The abrasive article of claim 17 , wherein the size coat, supersize coat, or the backing comprise size coat void spaces, supersize coat void spaces, or backing void spaces, respectively, that substantially overlap with the plurality of void spaces of the abrasive layer.

19. The abrasive article of claim 16 , further comprising a size coat having a size coat first major surface and a size coat second major surface, wherein the body first major surface is in direct contact with the size coat second major surface.

20. The abrasive article of claim 16 , further comprising a backing having a backing first major surface and a backing second major surface, wherein the backing first major surface is in direct contact with the body second major surface.

21. The abrasive article of claim 19 , further comprising a supersize coat having a supersize coat first major surface and a supersize coat second major surface, wherein the supersize coat second major surface is in direct contact with the size coat first major surface.

Assignees

• 3M Innovative Properties Company

Inventors

• Jangu Chainika
• Annen Michael J
• Eilers Deborah J
• Mahli David M
• Morel Caroline E
• Shafer Kathleen S
• Sorenson Gregory P

Classifications

• B24D3/28 Primary

  Resins {or natural or synthetic macromolecular compounds (B24D3/22 takes precedence)} · CPC title

• B24D11/001

  Manufacture of flexible abrasive materials · CPC title

• B24D3/004

  with special coatings · CPC title

• B24D11/02

  Backings, e.g. foils, webs, mesh fabrics · CPC title

• B24D2203/00

  Tool surfaces formed with a pattern · CPC title