Systems and methods for recycling waste ion exchange materials

Patent metadata

Field	Value
Publication number	US-11865532-B2
Application number	US-202117400161-A
Country	US
Kind code	B2
Filing date	Aug 12, 2021
Priority date	Aug 17, 2020
Publication date	Jan 9, 2024
Grant date	Jan 9, 2024

Abstract

Embodiments of the present disclosure are directed to methods for recycling waste ion exchange materials comprising a first alkali metal salt and a second alkali metal salt comprising reducing the size of the waste ion exchange materials to produce a plurality of waste ion exchange particles having particle sizes from 0.10 mm to 5.0 mm, and regenerating the plurality of waste ion exchange particles to produce a plurality of regenerated ion exchange particles having a concentration of the first alkali metal salt greater than a concentration of the first alkali metal salt in the waste ion exchange materials. Systems for recycling a waste ion exchange materials comprising a first alkali metal salt and a second alkali metal salt are also disclosed.

First claim

What is claimed is:

1. A method for recycling waste ion exchange materials comprising a first alkali metal salt and a second alkali metal salt, the method comprising:
reducing the size of the waste ion exchange materials to produce a plurality of waste ion exchange particles having particle sizes from 0.10 mm to 5.0 mm; and
regenerating the plurality of waste ion exchange particles to produce a plurality of regenerated ion exchange particles having a concentration of the first alkali metal salt greater than a concentration of the first alkali metal salt in the waste ion exchange materials,
wherein regenerating the plurality of waste ion exchange particles comprises:
contacting the plurality of waste ion exchange particles with an aqueous solution saturated with the first alkali metal salt to form a regenerated ion exchange slurry; and
separating the regenerated ion exchange slurry to produce a recycled aqueous solution and the plurality of regenerated ion exchange particles.

2. The method of claim 1 , wherein the waste ion exchange materials comprise less than or equal to 95 wt. % of the first alkali metal salt based on the total weight of the waste ion exchange materials.

3. The method of claim 1 , wherein the waste ion exchange materials comprise greater than or equal to 4 wt. % of the second alkali metal salt based on the total weight of the waste ion exchange materials.

4. The method of claim 1 , wherein reducing the size of the waste ion exchange materials comprises introducing the waste ion exchange materials to a size reduction unit operable to crush the waste ion exchange materials.

5. The method of claim 1 , wherein the plurality of waste ion exchange particles contacts the aqueous solution saturated with the first alkali metal salt for a time of from 0.5 hours to 24 hours.

6. The method of claim 1 , wherein the plurality of waste ion exchange particles contacts the aqueous solution saturated with the first alkali metal salt at a temperature less than 20° C.

7. The method of claim 1 , wherein contacting the plurality of waste ion exchange particles with the aqueous solution saturated with the first alkali metal salt comprises passing the plurality of waste ion exchange particles to a regeneration unit operable to contact the plurality of waste ion exchange particles with the aqueous solution saturated with the first alkali metal salt.

8. The method of claim 1 , wherein separating the regenerated ion exchange slurry comprises passing the regenerated ion exchange slurry to a separation unit operable to separate solid particles of the regenerated ion exchange materials from liquid of the recycled aqueous solution.

9. The method of claim 1 , further comprising drying the plurality of regenerated ion exchange particles to produce recycled ion exchange materials.

10. The method of claim 9 , wherein the recycled ion exchange materials comprise less than 1 wt. % of water based on the total weight of the recycled ion exchange materials.

11. The method of claim 9 , wherein the recycled ion exchange materials comprise greater than 95 wt. % of the first alkali metal salt based on the total weight of the recycled ion exchange materials.

12. The method of claim 9 , wherein the recycled ion exchange materials have particle sizes from 0.10 mm to 5.0 mm.

13. The method of claim 9 , wherein drying the plurality of regenerated ion exchange particles comprises passing the plurality of regenerated ion exchange particles to a drying unit operable to heat the plurality of regenerated ion exchange particles.

14. The method of claim 9 , further comprising:
heating the recycled ion exchange materials to an ion exchange temperature to form a molten salt; and
submerging a glass article into the molten salt such that an ion exchange between the molten salt and the glass article occurs.

15. A system for recycling a waste ion exchange materials comprising a first alkali metal salt and a second alkali metal salt, the system comprising:
a size reduction unit operable to crush the waste ion exchange materials to produce a plurality of waste ion exchange particles having particle sizes from 0.10 mm to 5.0 mm;
a regeneration unit downstream of the size reduction unit, the regeneration unit operable to contact the plurality of waste ion exchange particles with an aqueous solution saturated with the first alkali metal salt, the contact causing at least a portion of the second alkali metal salt to diffuse from the waste ion exchange particles and produce a regenerated ion exchange slurry; and
a separation unit downstream of the regeneration unit, the separation unit operable to separate the regenerated ion exchange slurry to produce a plurality of regenerated ion exchange particles and a recycled aqueous solution.

16. The system of claim 15 , wherein the regeneration unit is operable to contact the plurality of waste ion exchange particles with the aqueous solution saturated with the first alkali metal salt for a time of from 1.0 hours to 2.0 hours.

17. The system of claim 15 , wherein the regeneration unit is operable to contact the plurality of waste ion exchange particles with the aqueous solution saturated with the first alkali metal salt at a temperature less than 20° C.

18. The system of claim 15 , further comprising a drying unit downstream of the separation unit, the drying unit operable to heat the regenerated ion exchange particles to produce recycled ion exchange materials comprising less than 1 wt. % of water based on the total weight of the recycled ion exchange materials.

19. The system of claim 18 , wherein the recycled ion exchange materials comprise greater than 95 wt. % of the first alkali metal salt based on the total weight of the recycled ion exchange materials.

Assignees

• Corning Inc

Inventors

• Gomez-Mower Sinue
• Jarosch Kai Tod Paul
• Sevem Matthew Andrews

Classifications

• B01J49/00 Primary

  Regeneration or reactivation of ion-exchangers; Apparatus therefor (ion-exchange chromatography processes or apparatus B01D15/08) · CPC title

• B01J20/04

  comprising compounds of alkali metals, alkaline earth metals or magnesium · CPC title

• B01J20/28016

  Particle form · CPC title

• B01J39/09

  Inorganic material · CPC title

• B09B3/00

  Destroying solid waste or transforming solid waste into something useful or harmless · CPC title