Processes and compositions for carbon foam materials

Patent metadata

Field	Value
Publication number	US-11858818-B2
Application number	US-201916662750-A
Country	US
Kind code	B2
Filing date	Oct 24, 2019
Priority date	Oct 24, 2019
Publication date	Jan 2, 2024
Grant date	Jan 2, 2024

Abstract

Described herein are processes for preparation of a carbon foam material, the processes including the steps of heating in a microwave heating apparatus a mixture including a coal material and at least one additional agent. The additional agent can be a flux agent such a carbohydrate syrup, a secondary flux agent, a lignocellulosic waste material, a conductive carbon compound, a solvent, and combinations thereof. Also described are processes for calcining a carbon foam material in a furnace, a microwave heating apparatus, or an inductive field heater. The described calcining process can impart electrical conductivity and mechanical strength to carbon foams. Also described are carbon foam materials, calcined carbon foams, and composite materials. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

First claim

What is claimed is:

1. A process for producing a carbon foam material, the process comprising:
a heating step comprising heating a homogeneous mixture of a coal material, at least one conductive carbon material, and a flux agent in a microwave heating apparatus, thereby forming the carbon foam material;
wherein the coal material has a particle size of between about 10 mesh and about 400 mesh;
wherein the coal material is present in an amount of from about 20 wt % to about 75 wt % based on the total weight of the mixture;
wherein the at least one conductive carbon material is present in an amount of from about 25 wt % to about 80 wt % based on the total weight of the mixture;
wherein the flux agent comprises a carbohydrate syrup; and
wherein the at least one conductive carbon material is capable of absorbing microwave radiation.

2. The process of claim 1 , wherein the heating step comprises heating the mixture to a temperature of from about 250° C. to about 700° C. for from about 1 minute to about 60 minutes.

3. The process of claim 1 , wherein the coal material comprises a high-volatile or low-volatile sub-bituminous coal material, pitch, or a combination thereof.

4. The process of claim 1 , wherein the homogeneous mixture further comprises a lignocellulosic waste material, a secondary flux agent, a solvent, or a combination thereof.

5. The process of claim 4 , wherein the secondary flux agent comprises a volatile compound produced in a coal conversion process, a coal tar, a product of petroleum distillation, or a combination thereof.

6. The process of claim 4 , wherein the solvent comprises N-methyl-2-pyrrolidone, kerosene, or a combination thereof.

7. The process of claim 1 , wherein the carbohydrate syrup is high fructose corn syrup.

8. The process of claim 1 , wherein the at least one conductive carbon material comprises a carbon fiber, a carbon nanofiber, a carbon nanotube, a carbon flake, carbon black, a needle coke, graphene, graphene oxide, graphite, or a combination thereof.

9. The process of claim 1 , the process further comprising calcining the carbon foam material, the calcining comprising:
heating the carbon foam material to a temperature of from about 900° C. to about 1350° C. for a period of from about 10 seconds to about 3 hours, thereby forming a calcined carbon foam material;
wherein calcining imparts electrical conductivity and mechanical stability to the carbon foam material; and
wherein the carbon foam material is calcined in a furnace, microwave heating apparatus, an inductive field heater, or a combination thereof.

10. The process of claim 9 , wherein the carbon foam material is calcined in a furnace.

11. The process of claim 9 , wherein the carbon foam material is calcined in a microwave heating apparatus.

12. The process of claim 9 , wherein the carbon foam material is calcined in an inductive field heater.

13. A process for producing a carbon foam material, the process comprising:
a heating step comprising heating a homogeneous mixture of a coal material and at least one conductive carbon material in a heating apparatus, thereby forming the carbon foam material;
wherein the coal material has a particle size of between about 10 mesh and about 400 mesh;
wherein the coal material is present in an amount of from about 20 wt % to about 75 wt % based on the total weight of the mixture; and
wherein the at least one conductive carbon material is present in an amount of from about 25 wt % to about 80 wt % based on the total weight of the mixture;
wherein the heating apparatus provides electromagnetic radiation with a wavelength of about 1 m to 1 mm and a frequency between 300 MHz and 300 GHz, provides an alternating magnetic field for inductive heating, or a combination thereof;
wherein the at least one conductive carbon material is capable of absorbing microwave radiation, interacting with an electromagnetic field, or a combination thereof;
wherein the homogeneous mixture further comprises a flux agent, a secondary flux agent, a lignocellulosic waste material, a solvent, or a combination thereof; and
wherein the solvent comprises N-methyl-2-pyrrolidone, kerosene, or a combination thereof.

14. The process of claim 13 , wherein the heating apparatus provides electromagnetic radiation with a wavelength of about 1 m to 1 mm and a frequency between 300 MHz and 300 GHz.

15. The process of claim 13 , wherein the heating apparatus provides an alternating magnetic field for inductive heating.

16. The process of claim 13 , wherein the at least one conductive carbon material comprises a carbon fiber, a carbon nanofiber, a carbon nanotube, a carbon flake, carbon black, a needle coke, graphene, graphene oxide, graphite, or a combination thereof.

17. The process of claim 13 , wherein the at least one conductive carbon material is capable of interacting with an alternating magnetic field for inductive heating.

18. The process of claim 13 , the process further comprising calcining the carbon foam material, the calcining comprising:
heating the carbon foam material to a temperature of from about 900° C. to about 1350° C. for a period of from about 10 seconds to about 3 hours, thereby forming a calcined carbon foam material;
wherein calcining imparts electrical conductivity and mechanical stability to the carbon foam material; and
wherein the carbon foam material is calcined in a furnace, microwave heating apparatus, an inductive field heater, or a combination thereof.

19. The process of claim 18 , wherein the carbon foam material is calcined in a furnace.

20. The process of claim 18 , wherein the carbon foam material is calcined in a microwave heating apparatus.

21. The process of claim 18 , wherein the carbon foam material is calcined in an inductive field heater.

22. The process of claim 13 , wherein the flux agent comprises a carbohydrate syrup.

23. The process of claim 13 , wherein the secondary flux agent comprises a volatile compound produced in a coal conversion process, a coal tar, a product of petroleum distillation, or a combination thereof.

Assignees

• Univ West Virginia

Inventors

• Stiller Alfred H

Classifications

• C01B32/33 Primary

  from distillation residues of coal or petroleum; from petroleum acid sludge · CPC title

• C01B32/05 Primary

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• C01B32/342

  characterised by non-gaseous activating agents · CPC title

• C01B32/354

  After-treatment · CPC title

• C01P2002/60

  Compounds characterised by their crystallite size · CPC title