Microchemical system apparatus and related methods of fabrication

Patent metadata

Field	Value
Publication number	US-11857959-B2
Application number	US-202117184509-A
Country	US
Kind code	B2
Filing date	Feb 24, 2021
Priority date	Aug 24, 2016
Publication date	Jan 2, 2024
Grant date	Jan 2, 2024

Abstract

The disclosure relates to microchemical (or microfluidic) apparatus as well as related methods for making the same. The methods generally include partial sintering of sintering powder (e.g., binderless or otherwise free-flowing sintering powder) that encloses a fugitive phase material having a shape corresponding to a desired cavity structure in the formed apparatus. Partial sintering removes the fugitive phase and produces a porous compact, which can then be machined if desired and then further fully sintered to form the final apparatus. The process can produce apparatus with small, controllable cavities shaped as desired for various microchemical or microfluidic unit operations, with a generally smooth interior cavity finish, and with materials (e.g., ceramics) able to withstand harsh environments for such unit operations.

First claim

What is claimed is:

1. A microchemical apparatus comprising:
a fully sintered metal oxide body comprising an interior cavity within the body; and
a plurality of inlet ports, an outlet port, and a combustion area defined by the interior cavity;
wherein:
the interior cavity has a minimum dimension in a range from 1 μm to 1000 μm;
the interior cavity has a surface roughness of 20 μm or less, and
a plane of the interior cavity has a surface area of 50% or less of a surface area of a layer of the body;
each of the inlet ports and the outlet port are in fluid communication with the combustion area;
each of the inlet ports and the outlet port are in fluid communication with each other via the combustion area; and
the metal oxide body, the plurality of inlet ports, the outlet port, and the combustion area define a structure adapted to function as a combustor.

2. The microchemical apparatus of claim 1 , wherein the fully sintered metal oxide body has a density of at least 80% relative to the theoretical density of the metal oxide.

3. The microchemical apparatus of claim 1 , wherein the interior cavity is fully enclosed by the fully sintered metal oxide body.

4. The microchemical apparatus of claim 1 , wherein the interior cavity is partially enclosed by the fully sintered metal oxide body.

5. The microchemical apparatus of claim 1 , wherein the microchemical apparatus comprises a first side and a second side and wherein the combustion area has a longitudinal axis that extends between the first and second sides and wherein the inlet ports are arranged along the longitudinal axis.

6. The microchemical apparatus of claim 1 , wherein the plane of the interior cavity has a surface area of 5% to 30% of a surface area of the layer of the body.

7. The microchemical apparatus of claim 1 , wherein at least one inlet port is disposed on a first side of the interior cavity and at least one other inlet port is disposed on a second side of the interior cavity.

8. The microchemical apparatus of claim 1 , wherein:
the microchemical apparatus further comprises a plurality of inlet channels and an outlet channel defined by the interior cavity;
each inlet channel provides fluid communication between its corresponding inlet port and the combustion area; and
the outlet channel provides fluid communication between the outlet port and the combustion area.

9. The microchemical apparatus of claim 1 , wherein the metal oxide body comprises one or more of aluminum oxide, zirconium oxide, hydroxyapatite, and zirconiatungstate.

10. The microchemical apparatus of claim 1 , wherein the channel a minimum dimension in a range from 1 μm to 100 μm.

11. The microchemical apparatus of claim 1 , wherein the channel the interior cavity has a surface roughness of 5 μm or less.

12. The microchemical apparatus of claim 1 , wherein the fully sintered metal oxide body has a density of at least 95% relative to the theoretical density of the metal oxide.

Assignees

• Univ Michigan State

Inventors

• Kwon Patrick
• Yeom Junghoon

Classifications

• B01L3/502707 Primary

  characterised by the manufacture of the container or its components · CPC title

• B01J8/008

  Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction (B01J8/0285, B01J8/067, B01J8/087, B01J8/1836 take precedence) · CPC title

• B01J8/34

  with stationary packing material in the fluidised bed, e.g. bricks, wire rings, baffles · CPC title

• B01J19/0093

  Microreactors, e.g. miniaturised or microfabricated reactors (laboratory containers with capillary fluid transport in microfabricated channels or chambers B01L3/5027) · CPC title

• B01J19/02

  Apparatus characterised by being constructed of material selected for its chemically-resistant properties · CPC title