Interconnect for a solid oxide fuel cell, its manufacturing method, and a solid oxide fuel cell

Patent metadata

Field	Value
Publication number	US-11855309-B2
Application number	US-201816641093-A
Country	US
Kind code	B2
Filing date	Sep 6, 2018
Priority date	Sep 8, 2017
Publication date	Dec 26, 2023
Grant date	Dec 26, 2023

Abstract

An interconnect for a solid oxide fuel cell, its manufacturing method, and a solid oxide fuel cell including the same are provided.

First claim

The invention claimed is:

1. An interconnect for a solid oxide fuel cell, comprising:
a conductive substrate having a first and a second surface; and
a ceramic protective layer present on one or both of the first and the second surface of the conductive substrate,
wherein the ceramic protective layer comprises a spinel structure oxide represented by Formula 2 below:
Ni a A′ 1-a Co b B′ 2-b O 4   [Formula 2]

wherein in Formula 2, A′ is one or more element selected from the group consisting of Mg, Fe, Mn, Cr and Zn; B′ is one or more element selected from the group consisting of Al, Fe, Cr and Mn; 0<a<1; and 0<b<2;
wherein the ceramic protective layer further comprises one or more cobalt-based oxide selected from the group consisting of Co 3 O 4 , CoCr 2 O 4 and CoFe 2 O 4 ,
wherein an average value of a ratio of an atomic percentage (at %) of the Co to an atomic percentage (at %) of the Ni in the ceramic protective layer is 3 to 5, measured at two or more points of the ceramic protective layer,
wherein the ceramic protective layer has an area specific resistance (ASR) analyzed as a function of the atomic percentage of Ni and Co of 0.05 Ω·cm −2 or less as measured in an air atmosphere at 650° C., and
wherein the ceramic protective layer has a thickness ranging from 5 μm to 20 μm.

2. The interconnect for the solid oxide fuel cell according to claim 1 , wherein the ceramic protective layer further comprises a spinel structure oxide represented by Formula 1 below:
AB 2 O 4   [Formula 1]

wherein in Formula 1,
A represents one or more element selected from the group consisting of Mg, Fe, Ni, Mn, Cr and Zn; and
B represents one or more element selected from the group consisting of Al, Co, Fe, Cr and Mn.

3. The interconnect for the solid oxide fuel cell according to claim 1 , wherein the conductive substrate comprises a ferritic stainless steel (FSS) substrate.

4. A method for manufacturing the interconnect for the solid oxide fuel cell according to claim 1 , comprising:
a step of preparing a conductive substrate; and
a step of providing a ceramic protective layer on the conductive substrate.

5. The method for manufacturing the interconnect for the solid oxide fuel cell of claim 4 , wherein the step of preparing of the conductive substrate further comprises sand-blasting the conductive substrate with metallic particles.

6. The method for manufacturing the interconnect for the solid oxide fuel cell of claim 4 , wherein the step of providing of the ceramic protective layer is performed by electroplating, and further comprises a step of oxidizing the conductive substrate having the ceramic protective layer provided thereon.

7. The method for manufacturing the interconnect for the solid oxide fuel cell of claim 6 , wherein the step of oxidizing of the conductive substrate having the ceramic protective layer provided thereon comprises heat-treating the conductive substrate having the ceramic protective layer provided thereon at 600° C. to 800° C. for 1 hour to 10 hours.

8. A solid oxide fuel cell comprising:
two or more unit cells; and
an interconnect layer provided between the two or more unit cells and comprising the interconnect for the solid oxide fuel cell according to claim 1 ,
wherein each of the unit cells comprises an anode, a cathode, and an electrolyte provided between the anode and the cathode, and
the interconnect layer contacts the cathode or anode of each of the unit cells.

9. The interconnect for the solid oxide fuel cell according to claim 1 , wherein the ceramic protective layer has an area specific resistance (ASR) analyzed as a function of the atomic percentage of Ni and Co of 0.03 Ω#cm −2 or less as measured in an air atmosphere at 650° C.

10. The interconnect for the solid oxide fuel cell according to claim 2 , wherein the spinel structure oxide represented by Formula 1 is NiCo 2 O 4 .

11. The interconnect for the solid oxide fuel cell according to claim 1 , wherein the ceramic protective layer has a thickness ranging from 8 μm to 16 μm.

12. The interconnect for the solid oxide fuel cell according to claim 1 , wherein the ceramic protective layer has a thickness ranging from 10 μm to 15 μm.

Assignees

• Lg Chemical Ltd

Inventors

• Noh Tai Min
• Kim Daehwan
• Chung Chanyeup
• Park Sanghyun
• Ryoo Changseok
• Choi Kwangwook

Classifications

• H01M8/0228 Primary

  in the form of layered or coated products · CPC title

• C25D5/50

  by heat-treatment · CPC title

• H01M8/0217

  Complex oxides, optionally doped, of the type AMO3, A being an alkaline earth metal or rare earth metal and M being a metal, e.g. perovskites · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• C25D3/562 Primary

  containing more than 50% by weight of iron or nickel or cobalt · CPC title