Binder solution for all-solid-state battery including binder in form of particles and method of manufacturing same

Patent metadata

Field	Value
Publication number	US-11855290-B2
Application number	US-202017099100-A
Country	US
Kind code	B2
Filing date	Nov 16, 2020
Priority date	Jun 16, 2020
Publication date	Dec 26, 2023
Grant date	Dec 26, 2023

Abstract

Disclosed are a binder solution for an all-solid-state battery including a binder in the form of particles, and a method of manufacturing the same. The binder solution may include a rubber-based binder, a first solvent for dissolving the rubber-based binder, and a second solvent in which the rubber-based binder is insoluble and which is miscible with the first solvent.

First claim

What is claimed is:

1. A binder solution for an all-solid-state battery, comprising:
a rubber-based binder material;
a first solvent for dissolving the rubber-based binder material; and
a second solvent in which the rubber-based binder is insoluble and which is miscible with the first solvent,
wherein the rubber-based binder material is in a supersaturated state and aggregates, thereby precipitating in the form of particles,
the first solvent comprises one or more selected from the group consisting of benzyl acetate, ethyl 4-methyl benzoate, methyl 4-methyl benzoate, ethyl p-anisate, benzyl isobutyrate, and a combination thereof,
the second solvent comprises one or more selected from the group consisting of heptane, butyl butyrate, pentyl butyrate, hexyl butyrate, heptyl butyrate, and a combination thereof.

2. The binder solution of claim 1 , wherein the rubber-based binder material comprises one or more selected from the group consisting of nitrile butadiene rubber (NBR), hydrogenated nitrile butadiene rubber (HNBR), styrene butadiene rubber (SBR), and butadiene rubber (BR).

3. The binder solution of claim 1 , wherein the rubber-based binder material has an average diameter of about 100 nm to 1,000 nm.

4. The binder solution of claim 1 , wherein the rubber-based binder material has a polydispersity index (PDI) of about 0.1 to 0.5.

5. The binder solution of claim 1 , wherein a difference (R a ) between Hansen solubility parameters of the first solvent and the rubber-based binder material is about 2.4 to 7.

6. The binder solution of claim 1 , wherein a difference (R a ) between Hansen solubility parameters of the second solvent and the rubber-based binder material is about 7 to 11.8.

7. The binder solution of claim 1 , wherein a difference (R a ) between Hansen solubility parameters of the first solvent and the second solvent is about 2.83 to 20.

8. The binder solution of claim 1 , wherein a ratio (V 1 :V 2 ) of a volume (V 1 ) of the first solvent to a volume (V 2 ) of the second solvent is about 2:8 to 8:2.

9. The binder solution of claim 1 , wherein a content of the rubber-based binder material is greater than 0 wt % and of about or less than about 20 wt %, and a sum total of contents of the first solvent and the second solvent is about 80 wt % or greater and less than about 100 wt %, wherein the wt % based on the total weight of the binder solution.

10. An electrode slurry for an all-solid-state battery, comprising:
the binder solution of claim 1 ;
an electrode active material;
a conductive material; and
a solid electrolyte material,
wherein the solid electrolyte material comprises Li 2 S—P 2 S 5 , Li 2 S—P 2 S 5 —LiI, Li 2 S—P 2 S 5 —LiCI, Li 2 S—P 2 S 5 —LiBr, Li 2 S—P 2 S 5 —Li 2 O, Li 2 S—P 2 S5—Li 2 O—LiI, Li 2 S—SiS 2 , Li 2 S—SiS 2 —LiI, Li 2 S—SiS 2 —LiBr, Li 2 S—SiS 2 —LiCI, Li 2 S—SiS 2 —B 2 S 3 —LiI, Li 2 S—SiS 2 —P 2 S 5 —LiI, Li 2 S—B 2 S 3 , Li 2 S—P 2 S 5 —Z m S n (m and n being positive numbers, and Z selected from the group consisting of Ge, Zn, and Ga), Li 2 S—GeS 2 , Li 2 S—SiS 2 —Li 3 PO 4 , Li 2 S—SiS 2 —Li x MO y (x and y being positive numbers, and M selected from the group consisting of P, Si, Ge, B, AI, Ga, and In), or Li 10 GeP 2 S 12 .

11. The electrode slurry of claim 10 , wherein the electrode slurry comprise the binder solution in an amount of greater than 0 wt % and of about or less than about 30 wt %, the conductive material in an amount of greater than 0 wt % and of about or less than about 10 wt %, the solid electrolyte material in an amount of greater than 0 wt % and of about or less than about 20 wt %, and a remaining amount of the electrode active material, wherein the wt % based on the total weight of the electrode slurry.

12. An electrode for an all-solid-state battery, comprising:
the electrode slurry of claim 10 .

13. The electrode of claim 12 , wherein a ratio (B/A) of an electrochemical area (B) of the electrode active material to a total surface area (A) of the electrode active material is about 0.2 or greater and less than 1, and
the electrochemical area (B) of the electrode active material means the electrochemical contact area between the electrode active material and the solid electrolyte material.

14. The electrode of claim 13 , wherein the ratio (B/A) is increased as a content of a second solvent in a binder solution is increased.

15. A method of manufacturing the binder solution of claim 1 , comprising:
admixing the rubber-based binder material in a first solvent to form forming an admixture; and
adding the second solvent, in which the rubber-based binder material is insoluble and which is miscible with the first solvent, to the admixture of the rubber-based binder material and the first solvent to precipitate the rubber-based binder material in a form of particles.

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp
• Univ Hanyang Ind Univ Coop Found

Inventors

• Kim Sang Mo
• Lee Ju Yeon
• Kwon Tae Young
• Jung Sung Hoo
• Jung Yoon Seok
• Kim Kyu Tae
• Oh Dae Yang

Classifications

• H01M4/622 Primary

  being polymers · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/62

  Selection of inactive substances as ingredients for active masses, e.g. binders, fillers · CPC title

• H01M4/625

  Carbon or graphite · CPC title