Cathode for all-solid-state battery

Patent metadata

Field	Value
Publication number	US-11855286-B2
Application number	US-202017105943-A
Country	US
Kind code	B2
Filing date	Nov 27, 2020
Priority date	Oct 23, 2020
Publication date	Dec 26, 2023
Grant date	Dec 26, 2023

Abstract

Disclosed are a cathode for an all-solid-state battery including a cathode thin film for an all-solid-state battery or a cathode composite membrane for an all-solid-state battery, and an all-solid-state battery including the same. The cathode for an all-solid-state battery contains a grain that has a plane having a low surface energy and has a grain boundary arranged parallel to the electron movement direction, thus effectively lowering the interfacial resistance of the thin film while suppressing the dissolution and diffusion of the transition metal, thereby improving the cycle stability of the all-solid-state battery including the same.

First claim

What is claimed is:

1. A cathode thin film for an all-solid-state battery comprising a grain containing Li and Mn,
wherein the grain comprises;
a first plane disposed on the upper side and having a polygonal shape; and
a plurality of second planes having a polygonal shape including at least one of an edge and a vertex of the first plane,
wherein the plurality of second planes have a crystal orientation that differs from the first plane, and are disposed adjacent to each other and are inclined in a thickness direction to surround the periphery of the first plane, and
wherein the grain suppresses dissolution and diffusion of the Mn; and
wherein the grain comprises a compound represented by Formula 1 below:
Li a Ni b M c N d L e O x   [Formula 1]

wherein M represents one or two elements selected from Mn and Co;
N represents one or two or more elements selected from the group consisting of Mg, Al, Ti, Cr, and Fe; and
L represents one or two or more elements selected from the group consisting of B, C, Na, Si, P, S, K, Ca, and Ba; and
a, b, c, d, e, and x satisfy the following requirements of a/(b+c+d) is 0.80 to 1.30, b/(b+c+d) is 0 to <0.65, c/(b+c+d) is 0.05 to 1, d/(b+c+d) is 0 to 0.10, e/(b+c+d) is 0 to 0.010, b+c+d is 1 or 2, and x is 1.5 to 4; and
wherein the cathode thin film for an all-solid-state battery is a thin film including a grain predominantly including an exposed grain plane having a minimum surface energy.

2. The cathode thin film according to claim 1 , wherein the grain comprises a spinel structure, which is a space group of Fd-3m.

3. The cathode thin film according to claim 1 , wherein the polygonal shape of the first plane comprises at least one selected from the group consisting of a square, a rectangle, a triangle and an octagon.

4. The cathode thin film according to claim 1 , wherein the polygonal shape of the second plane comprises at least one selected from the group consisting of a trapezoid, a hexagon, a rectangle, and a triangle.

5. The cathode thin film according to claim 1 , wherein the first plane of the grain dominantly including the exposed grain plane having the minimum surface energy is an exposed grain plane having a rectangular shape, and
the plurality of second planes of the grain dominantly including the exposed grain plane having the minimum surface energy comprises an exposed grain plane including a long edge of the first plane and having a hexagonal shape.

6. The cathode thin film according to claim 1 , wherein an area ratio of the exposed grain plane having the minimum surface energy is 50 to 100% based on 100% of a total area of the first and second planes.

7. The cathode thin film according to claim 1 , wherein the exposed grain plane having the minimum surface energy is a (111) plane.

8. The cathode thin film according to claim 1 , wherein the grain boundary in the grain is disposed parallel to an electron movement direction.

9. An all-solid-state battery comprising:
a cathode layer comprising the cathode thin film for an all-solid-state battery according to claim 1 and a current-collecting layer;
an anode layer; and
a solid electrolyte layer disposed between the cathode layer and the anode layer,
wherein a charge/discharge rate after 100 cycles is 96% or more due to suppression of side reactions at an interface between the cathode layer and the solid electrolyte layer.

10. A pouch cell comprising the all-solid-state battery according to claim 9 .

Assignees

• Korea Inst Sci & Tech

Inventors

• Park Sang Baek
• Kim Byung Kook
• Lee Jong Ho
• Son Ji Won
• Yoon Kyung Joong
• Kim Hyoung Chul
• Ji Ho Il
• Yang Sung Eun
• Lee Seung Hwan
• Kim Joo Sun

Classifications

• H01M4/525 Primary

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/131 Primary

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title

• H01M4/366

  as layered products · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title