Ironmaking feedstock
US-2020347467-A1 · Nov 5, 2020 · US
US11851725B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11851725-B2 |
| Application number | US-202217938104-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 5, 2022 |
| Priority date | May 3, 2019 |
| Publication date | Dec 26, 2023 |
| Grant date | Dec 26, 2023 |
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The present invention relates to an ironmaking feedstock comprising a solid CaFe3O5 phase. The ironmaking feedstock may be produced by a process comprising reacting a combination of a calcium source and magnetite at elevated temperature under reducing conditions sufficient to produce the solid CaFe3O5 phase. The product may be in the form of agglomerates such as pellets, with a compressive strength such that the product is suitable for transportation.
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The invention claimed is: 1. A process for the production of an ironmaking feedstock for ironmaking, the process comprising reacting a combination of a calcium source and magnetite, having a molar ratio of calcium to magnetite of between 0.1:1.0 and 0.8:1.0, at elevated temperature under reducing conditions sufficient to produce an ironmaking feedstock comprising a solid CaFe 3 O 5 phase. 2. The process of claim 1 , wherein the magnetite in the combination is present in a magnetite concentrate. 3. The process of claim 2 , further comprising processing an iron ore to yield the magnetite concentrate, and combining the magnetite concentrate with the calcium source to form the combination of a calcium source and magnetite. 4. The process of claim 1 , wherein the molar ratio of calcium to magnetite is between 0.2:1.0 and 0.8:1.0. 5. The process of claim 1 , wherein the molar ratio of calcium to magnetite is between 0.4:1.0 and 0.8:1.0. 6. The process of claim 5 , wherein the reducing conditions comprise a partial pressure of oxygen from 1.3×10 −11 atm to 9.8×10 −16 atm. 7. The process of claim 1 , wherein the ironmaking feedstock comprises at least 10% CaFe 3 O 5 by weight with respect to all iron-containing components in the ironmaking feedstock as measured by quantitative phase analysis using the Rietveld method. 8. The process of claim 1 , wherein the elevated temperature is a temperature between about 850° C. and 1050° C. 9. The process of claim 1 , wherein the reducing conditions comprise a partial pressure of oxygen from 6.3×10 −8 atm to 9.8×10 16 atm. 10. The process of claim 1 , wherein the reaction is conducted over a time period of between 20 minutes and 8 hours. 11. The process of claim 1 , comprising an agglomeration step to produce the ironmaking feedstock as an agglomerated product. 12. The process of claim 1 , comprising a pelletising step to produce the ironmaking feedstock in the form of pellets. 13. The process of claim 12 , wherein the pelletising step comprises pelletising the combination of the calcium source and the magnetite prior to conducting the reaction at elevated temperature under reducing conditions. 14. The process of claim 12 , wherein the solid CaFe 3 O 5 is present at the surface of the pellets after reacting the combination of a calcium source and magnetite. 15. The process of claim 12 , wherein the pellets have a compressive strength of at least 14 MPa after reacting the combination of a calcium source and magnetite. 16. The process of claim 1 , wherein the calcium source is selected from the group consisting of calcium carbonate, calcium oxide, dolomite, gypsum and combinations thereof. 17. The process of claim 1 , further comprising producing iron from the ironmaking feedstock. 18. The process of claim 17 , wherein the ironmaking feedstock is reduced to iron in a blast furnace.
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