Rechargeable transition metal battery

Patent metadata

Field	Value
Publication number	US-11848445-B2
Application number	US-202117340115-A
Country	US
Kind code	B2
Filing date	Jun 7, 2021
Priority date	Mar 11, 2021
Publication date	Dec 19, 2023
Grant date	Dec 19, 2023

Abstract

A rechargeable transition metal battery includes a negative electrode, a positive electrode and an electrolyte. The negative electrode includes a negative electrode material which is a transition metal or an alloy of the transition metal. The positive electrode is electrically connected to the negative electrode and includes a host material and a positive electrode material. The host material includes a carbon. The positive electrode material is connected to the host material, and the positive electrode material is a compound of a metal, an elemental chalcogen or an elemental halogen. The electrolyte is disposed between the positive electrode and the negative electrode.

First claim

What is claimed is:

1. A rechargeable transition metal battery, comprising:
a negative electrode comprising:
a negative electrode material which is a transition metal or an alloy of the transition metal;

a positive electrode electrically connected to the negative electrode and comprising:
a host material comprising a carbon; and
a positive electrode material connected to the host material, and the positive electrode material is a compound of a metal, an elemental chalcogen or an elemental halogen; and

an electrolyte disposed between the positive electrode and the negative electrode, wherein the electrolyte is a eutectic mixture formed by mixing a first compound, a second compound and a third compound, the first compound is an organic alcohol, an organic acid or an organic amine, the second compound is a transition metal halide, a transition metal oxide or a transition metal salt, and the third compound is a choline chlorid, and the electrolyte is not gelled;
wherein when the rechargeable transition metal battery is discharging, a transition metal ion is released from the negative electrode material of the negative electrode, and the transition metal ion migrates to the positive electrode, and when the rechargeable transition metal battery is charging, the transition metal ion migrates from the positive electrode back to the negative electrode to form the negative electrode material;
wherein the rechargeable transition metal battery uses the transition metal ion as a working ion.

2. The rechargeable transition metal battery of claim 1 , wherein the transition metal is Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Hg, Al, Ga, In, TI, Sn, Pb, Bi, Sc, Y, lanthanide or actinide.

3. The rechargeable transition metal battery of claim 1 , wherein the positive electrode material is embedded on the host material.

4. The rechargeable transition metal battery of claim 1 , wherein the positive electrode material is the compound of the metal, and the positive electrode material is dissolved in the electrolyte.

5. The rechargeable transition metal battery of claim 1 , wherein the metal is Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Tc, Re, Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Hg, Al, Ga, In, TI, Sn, Pb, Bi, Sc, Y, lanthanide or actinide.

6. The rechargeable transition metal battery of claim 5 , wherein the compound of the metal is a chalcogen compound of the metal, a pnictide compound of the metal, a halide of the metal or a salt of the metal.

7. The rechargeable transition metal battery of claim 6 , wherein the chalcogen compound of the metal is a metal oxide, a metal sulfide, a metal selenide or a metal telluride, the pnictide compound of the metal is a metal nitride or a metal phosphide, the halide of the metal is a metal fluoride, a metal chloride, a metal bromide or a metal iodide, and the salt of the metal is a metal phosphinate, a metal borate, a metal perchlorate, a metal hypochlorite, a metal acetate, a metal phosphite, a metal sulfate, a metal sulfite, a metal carbonate, a metal oxalate or a metal phosphate.

8. The rechargeable transition metal battery of claim 1 , wherein the elemental chalcogen is S, Se or Te, and the elemental halogen is F, Cl, Br or I.

9. The rechargeable transition metal battery of claim 1 , wherein the host material is a carbon fiber, a carbon nanotube or a carbon black.

10. The rechargeable transition metal battery of claim 1 , wherein the negative electrode is a sheet form or a powder form.

11. The rechargeable transition metal battery of claim 1 , further comprising a separator, wherein the separator is disposed between the negative electrode and the positive electrode, and is disposed in the electrolyte.

Assignees

• Univ Nat Tsing Hua

Inventors

• Chueh Yu-Lun
• Wu Shu-Chi

Classifications

• H01M4/581 Primary

  Chalcogenides or intercalation compounds thereof · CPC title

• H01M4/136 Primary

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M4/364

  as mixtures · CPC title

• H01M4/582

  Halogenides · CPC title

• H01M4/625

  Carbon or graphite · CPC title