Three-Dimensional (3D) Printed Mortar and Preparation Method Therefor, and 3D Printing Method for Mortar
US-2024190039-A1 · Jun 13, 2024 · US
US11845695B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11845695-B2 |
| Application number | US-201917277590-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 16, 2019 |
| Priority date | Sep 18, 2018 |
| Publication date | Dec 19, 2023 |
| Grant date | Dec 19, 2023 |
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An additive for mineral binder composition, in particular accelerators for mineral binder compositions, in particular cementitious binder compositions. The accelerator includes 35 to 99.7 w % of at least one mineral filler F with a particle size D50<5 μm, preferably <4 μm, most preferred <3.5 μm, 0.3 to 65 w % of a sodium aluminate SA, and 0 to 45 w % of at least one other inorganic compound I selected from the group consisting of calcium aluminate cements and/or sulfates of alkali or alkaline earth metals. Further, corresponding mineral binder compositions as well as uses and processes, including the acceleration of setting and curing of mineral binder compositions at low temperatures.
Opening claim text (preview).
The invention claimed is: 1. A composition comprising: a) 35-99.7 w % of at least one mineral filler F with a particle size D50 <5μm; b) 0.3-65 w % of a sodium aluminate SA; c) 0.1-45 w % of at least one other inorganic compound I selected from the group consisting of calcium aluminate cements and lithium sulfate; and d) optionally further additives for mineral binder compositions. 2. A composition according to claim 1 , wherein the mineral filler F is selected from the group consisting of carbonates, hydrogencarbonates of alkali, and alkaline earth metals. 3. A composition according to claim 1 , wherein the sodium aluminate SA is NaAlO 2 . 4. A composition according to claim 1 , wherein the composition further comprises a superplasticizer, in an amount of 0.1-10 w %, related to the total weight of the composition. 5. A process for the production of a composition according to claim 1 , the process comprising a step of mixing of the ingredients and a step of reducing at least one of dust formation during storage, transportation, metering, and dosage of the composition. 6. A process according to claim 5 , wherein the composition is packaged into a water soluble pouch. 7. An article consisting of: 1) at least one container that readily breaks or dissolves when mixed with water and/or other ingredients of mineral binder compositions; and 2) an accelerator for mineral binder compositions according to claim 1 , wherein the whole mass of accelerator is contained within the at least one container. 8. A method for accelerating at least one of the setting and the curing of a mineral binder or of a mineral binder composition, the method comprising adding the composition of claim 1 to a mineral binder or a mineral binder composition. 9. The method according to claim 8 , wherein the mineral binder comprises a mixture of OPC and CAC in a weight ratio of OPC to CAC of >1. 10. The method according to claim 8 , wherein the at least one of the setting and the curing is accelerated at temperatures between +10° C. and 15° C. 11. The method according to claim 8 , wherein the mixing water for a mineral binder composition has a temperature of <10° C. 12. A method for accelerating a mineral binder compositions comprising the steps of: a) providing the composition according to claim 1 in the form of a slurry, granulated, coated, encapsulated or packaged in a water-soluble pouch; b) providing a mineral binder or mineral binder composition; c) providing water; d) mixing the ingredients a) —c) in any given order; and e) placing the mixed composition. 13. A method according to claim 12 , wherein any of steps a) to e) are executed at temperatures between +10° C. and 15° C. 14. A mineral binder composition containing at least one mineral binder, aggregate, optionally water, and, in each case based on the mineral binder content, a) 0.05-5 w % of at least one mineral filler F, b) 0.0003-2.5 w % of sodium aluminate SA, c) 0.0001-1 w % of at least one additional inorganic compound I, and d) 0-0.5 w % of additional additives. 15. A process for at least of one of producing and placing a mineral binder composition, as claimed in claim 14 , the process comprising mixing the mineral binder composition with a composition comprising: a) 35-99.7 w % of at least one mineral filler F with a particle size D50<5 μm, b) 0.3-65 w % of a sodium aluminate SA, c) 0-45 w % of at least one other inorganic compound I selected from the group consisting of calcium aluminate cements and sulfates of alkali or alkaline earth metals, and d) optionally further additives for mineral binder compositions. 16. A shaped body obtained by curing a mineral binder composition as claimed in claim 14 after the addition of water.
Aluminous cements (monolithic refractories or refractory mortars C04B35/66) · CPC title
of calcium · CPC title
Aluminates · CPC title
Alkali-metal sulfates; Ammonium sulfate · CPC title
Powdery mixtures · CPC title
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