Integrated process for the conversion of crude to olefins
US-2023115510-A1 · Apr 13, 2023 · US
US11840673B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11840673-B2 |
| Application number | US-202217843990-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 18, 2022 |
| Priority date | Mar 15, 2019 |
| Publication date | Dec 12, 2023 |
| Grant date | Dec 12, 2023 |
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Processes herein may be used to thermally crack various hydrocarbon feeds, and may eliminate the refinery altogether while making the crude to chemicals process very flexible in terms of crude. In embodiments herein, crude is progressively separated into at least light and heavy fractions. Depending on the quality of the light and heavy fractions, these are routed to one of three upgrading operations, including a fixed bed hydroconversion unit, a fluidized catalytic conversion unit, or a residue hydrocracking unit that may utilize an ebullated bed reactor. Products from the upgrading operations may be used as feed to a steam cracker.
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We claim: 1. A system for converting whole crudes and other heavy hydrocarbon streams to produce olefins and aromatics, the system comprising: a first integrated separation device for separating a hydrocarbon feedstock into at least a light boiling fraction, a medium boiling fraction, and a high boiling residue fraction; a first hydroprocessing system configured for hydrotreating the high boiling residue fraction and producing a hydrotreated effluent; a second integrated separation device configured for separating the hydrotreated and hydrocracked effluent and producing an ultra-low sulfur fuel oil and a hydroprocessed fraction; a second hydroprocessing system configured for hydrocracking the hydroprocessed fraction and producing a steam cracker feedstream; a steam cracker unit for converting the steam cracker feedstream and the light boiling fraction into one or more light olefins and a pyrolysis oil, a separation system for separating the pyrolysis oil into a heavy pyrolysis gasoline fraction and a light pyrolysis gasoline fraction; and an aromatics unit for receiving the light pyrolysis gasoline fraction and converting at least a portion of the light pyrolysis gasoline fraction to aromatics. 2. The system of claim 1 , wherein the first integrated separation device is configured to provide the light boiling fraction comprising hydrocarbons having a 95% boiling point temperature in the range from about 130° C. to about 200° C. a hydrogen content of at least 14 wt %, a BMCI of less than 5, an API gravity of greater than 40°, a sulfur content of less than 1000 ppm, a nitrogen content of less than 10 ppm, a viscosity, measured at 40° C., of less than 1 cSt, less than 1 wt % MCRT, and less than 1 ppm total metals, and the high boiling residue fraction comprising hydrocarbons having a 5% boiling point temperature of about 200° C. a hydrogen content in the range from about 12 wt % to about 14 wt %, an API gravity of up to about 40°, a viscosity, measured at 40° C., of greater than 1 cSt, greater than 1 wt % MCRT, and greater than 10 ppm total metals. 3. The system of claim 1 , where the first integrated separation device is configured to provide the light boiling fraction comprising hydrocarbons having a 95% boiling point temperature in the range from about 130° C. to about 200° C., a hydrogen content of at least 14 wt %, a BMCI of less than 5, an API gravity of greater than 40°, a sulfur content of less than 1000 ppm, a nitrogen content of less than 10 ppm, a viscosity, measured at 40° C., of less than 1 cSt, less than 1 wt % MCRT, and less than 1 ppm total metals, the medium boiling fraction comprising hydrocarbons having a 5% boiling point temperature in the range from about 130° C. to about 200° C. and a 95% boiling point temperature in the range from about 400° C. to about 600° C., a hydrogen content in the range from about 12 wt % to about 14 wt %, a BMCI in the range from about 5 to less than 50, an API gravity of in the range from about 10° to about 40°, a sulfur content in the range from about 1000 ppm to about 10000 ppm, a nitrogen content in the range from about 1 ppm to about 100 ppm, a viscosity, measured at 40° C., of greater than 1 cSt, less than 5 wt % MCRT, and less than 50 ppm total metals, and the high boiling residue fraction comprising hydrocarbons having a 5% boiling point temperature in the range from about 400° C. to about 600° C., a hydrogen content of less than 12 wt %, a BMCI of greater than 50, an API gravity of less than 10°, a sulfur content of greater than 10000 ppm, a nitrogen content of greater than 100 ppm, a viscosity, measured at 100° C., of greater than 100 cSt, greater than 5 wt % MCRT, and greater than 50 ppm total metals. 4. The system of claim 3 , further comprising a flow line configured to feed the medium boiling fraction to the second hydroprocessing system. 5. The system of claim 4 , further comprising a mixing unit or a t-junction configured for combining the medium boiling fraction and the hydroprocessed fraction upstream of the second hydroprocessing system. 6. The system of claim 4 , wherein the second hydroprocessing system comprises a catalyst configured for converting hydrocarbons in the hydroprocessed fraction and the medium boiling fraction to primarily steam crackable products.
Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions (C10G15/00 takes precedence; destructive hydrogenation of non-melting solid carbonaceous or similar materials C10G1/06) · CPC title
Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds · CPC title
plural parallel stages only · CPC title
with heated gases or vapours · CPC title
Preventing or removing incrustation · CPC title
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