System and method for manufacturing ester-based composition

Patent metadata

Field	Value
Publication number	US-11840510-B2
Application number	US-202117443781-A
Country	US
Kind code	B2
Filing date	Jul 27, 2021
Priority date	Apr 4, 2019
Publication date	Dec 12, 2023
Grant date	Dec 12, 2023

Abstract

The present disclosure relates to a manufacturing system and a manufacturing method which are capable of continuously manufacturing an ester-based composition, and has a technical feature of being capable of manufacturing an ether-based composition continuously, economically, and efficiently.

First claim

The invention claimed is:

1. A method for manufacturing an ester-based composition, the method comprising:
a step S1 of forming a reaction mixture of a polycarboxylic acid and a first alcohol;
a step S2 of performing an esterification reaction of the reaction mixture to form a first unpurified product mixture including a first ester compound;
a step S3 of performing a trans-esterification reaction of the first unpurified product mixture and a second alcohol to form a second unpurified product mixture including a second ester compound;
a step S4 of performing a neutralization and water separation of the second unpurified product mixture to form a water layer stream and an organic layer stream;
a step S5 of distilling the organic layer stream to obtain an alcohol-rich stream and an ester-rich stream; and
a step S6 of removing the first alcohol and the second alcohol remaining in the ester-rich stream to obtain a mixed alcohol stream and a product stream,
wherein the steps S1 to S6 are continuously performed.

2. The method of claim 1 , further comprising a step S7 of mixing the alcohol-rich stream obtained in the step S5 and the mixed alcohol stream obtained in the step S6 to form a first recovery alcohol stream and separating the first recovery alcohol stream into a water stream, a first alcohol stream, and a second alcohol stream to form the water stream, the first alcohol stream, and the second alcohol stream.

3. The method of claim 2 , wherein the first alcohol stream obtained in the step S7 is used as the first alcohol in the step S1, and the second alcohol stream obtained in the step S7 is used as the second alcohol in the step S2.

4. The method of claim 2 , further comprising a step S8 of mixing the water layer stream obtained in the step S4 and the water stream obtained in the step S7 to form a preliminary wastewater stream and adding alcohol having a larger number of carbon atoms between the first alcohol and the second alcohol to the preliminary wastewater stream to form a second recovery alcohol stream including the first alcohol and the second alcohol, and a wastewater stream.

5. The method of claim 1 , wherein the step S2 is performed in N number of reactors connected in series, wherein each reactor satisfies Formulas 1) and 2), and N is an integer of 2 or greater:
T n1−1 ≤T n1   1)

E n2−1 ≥E n2 ≥E 1   2)

wherein in Formulas 1) and 2), n1 is an integer of 2 to N, and n2 is an integer of 3 to N,
T x =Temperature of an x -th reactor
E x ={(Number of moles of alcohol injected into an x -th reactor− c *Number of moles of dicarboxylic acid injected into an x-th reactor/ c *Number of moles of dicarboxylic acid injected into the first reactor)*100%},

wherein in T x and E x , x is an integer of 1 to N, and c is the number of carboxylic acid groups contained in one molecule of polycarboxylic acid.

6. The method of claim 1 , wherein
the step S2 is performed in N number of reactors connected in parallel,
the formation of the first unpurified product mixture in each reactor is performed semi-continuously across the N number of reactors, and
N is an integer of 2 or greater.

7. The method of claim 1 , wherein the number of carbon atoms of the first alcohol is greater than the number of carbon atoms of the second alcohol.

Assignees

• Lg Chemical Ltd

Inventors

• Kim Hyun Kyu
• Lee Sung Kyu
• Jun Hyoung
• Jin Chan Hyu
• Moon Jeong Ju
• Kim Joo Ho

Classifications

• C07C67/08 Primary

  by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds · CPC title

• B01D3/14 Primary

  Fractional distillation {or use of a fractionation or rectification column} · CPC title

• B01J8/04

  the fluid passing successively through two or more beds · CPC title

• B01J19/0013

  Controlling the temperature of the process · CPC title

• B01J19/0046

  Sequential or parallel reactions, e.g. for the synthesis of polypeptides or polynucleotides; Apparatus and devices for combinatorial chemistry or for making molecular arrays (synthesis methods per se C40B50/00) · CPC title