Colored glass-ceramics having petalite and lithium silicate structures

Patent metadata

Field	Value
Publication number	US-11840475-B2
Application number	US-202217864693-A
Country	US
Kind code	B2
Filing date	Jul 14, 2022
Priority date	May 29, 2019
Publication date	Dec 12, 2023
Grant date	Dec 12, 2023

Abstract

A glass-ceramic article comprises a petalite crystalline phase and a lithium silicate crystalline phase. The weight percentage of each of the petalite crystalline phase and the lithium silicate crystalline phase in the glass-ceramic article are greater than each of the weight percentages of other crystalline phases present in the glass-ceramic article. The glass-ceramic article has a transmittance color coordinate in the CIELAB color space of: L*=from 20 to 90; a*=from −20 to 40; and b*=from −60 to 60 for a CIE illuminant F02 under SCI UVC conditions. In some embodiments, the colorant is selected from the group consisting of TiO2, Fe2O3, NiO, Co3O4, MnO2, Cr2O3, CuO, Au, Ag, and V2O5.

First claim

What is claimed is:

1. A glass-ceramic article comprising:
a petalite crystalline phase;
a lithium silicate crystalline phase; and
one or more colorants selected from the group consisting of TiO 2 , Fe 2 O 3 , NiO, Co 3 O 4 , MnO 2 , Cr 2 O 3 , Au, and V 2 O 5 ,
wherein a weight percentage of each of the petalite crystalline phase and the lithium silicate crystalline phase in the glass-ceramic article are greater than each of the weight percentages of other crystalline phases present in the glass-ceramic article; and
wherein the glass-ceramic article has a transmittance color coordinate in CIELAB color space of:
L*=from 20 to 90;
a*=from −20 to 40; and
b*=from −60 to 60

for a CIE illuminant F02 under SCI UVC conditions.

2. The glass-ceramic article according to claim 1 , wherein the glass-ceramic article has a composition comprising, in wt %:
SiO 2 in an amount of from 55 to 80;
Al 2 O 3 in an amount of from 2 to 20;
Li 2 O in an amount of from 5 to 20;
P 2 O 5 in an amount of from 0.5 to 6; and
ZrO 2 in an amount of from 0.2 to 15.

3. The glass-ceramic article according to claim 2 , wherein the composition further comprises, in wt %, from 0.01 to 5 of the one or more colorants.

4. The glass-ceramic article according to claim 3 , wherein at least 80 wt % of the one or more colorants in the composition is present in a residual glass phase of the glass-ceramic article.

5. The glass-ceramic article according to claim 3 , wherein at least 95 wt % of the one or more colorants in the composition is present in a residual glass phase of the glass-ceramic article.

6. The glass-ceramic article according to claim 2 , wherein the composition further comprises, in wt %:
Au in an amount of from 0.1 to 1.5; or
Cr 2 O 3 in an amount of from 0.05 to 1.0; or
NiO in an amount of from 0.1 to 2.0; or
V 2 O 5 in an amount of from 0.1 to 2.0; or
Co 3 O 4 in an amount of from 0.01 to 2.0.

7. The glass-ceramic article according to claim 6 , wherein the glass-ceramic article has a transmittance color coordinate in the CIELAB color space of:
L*=from 50 to 90;
a*=from −20 to 30; and
b*=from 0 to 40

for a CIE illuminant F02 under SCI UVC conditions.

8. The glass-ceramic article according to claim 1 , wherein the one or more colorants selected from the group consisting of NiO, Co 3 O 4 , MnO 2 , Cr 2 O 3 , Au, and V 2 O 5 .

9. A glass-ceramic article comprising:
a petalite crystalline phase;
a lithium silicate crystalline phase; and
a residual glass phase comprising a colorant,
wherein the colorant comprises one or more colorants selected from the group consisting of TiO 2 , Fe 2 O 3 , NiO, Co 3 O 4 , MnO 2 , Cr 2 O 3 , Au, and V 2 O 5 ;
wherein:
the glass-ceramic article has a fracture toughness of 1 MPa·m 1/2 or greater; and
the glass-ceramic article has a transmittance color coordinate in CIELAB color space of:
L*=from 20 to 90;
a*=from −20 to 40; and
b*=from −60 to 60

for a CIE illuminant F02 under SCI UVC conditions.

10. The glass-ceramic article according to claim 9 , wherein the glass-ceramic article has a composition comprising, in wt %:
SiO 2 in an amount of from 55 to 80;
Al 2 O 3 in an amount of from 2 to 20;
Li 2 O in an amount of from 5 to 20;
P 2 O 5 in an amount of from 0.5 to 6; and
ZrO 2 in an amount of from 0.2 to 15.

11. The glass-ceramic article according to claim 10 , wherein the composition further comprises, in wt %, from 0.01 to 5 of the one or more colorants.

12. The glass-ceramic article according to claim 9 , wherein at least 80 wt % of the colorant is present in the residual glass phase of the glass-ceramic article.

13. The glass-ceramic article according to claim 9 , wherein at least 95 wt % of the colorant is present in the residual glass phase of the glass-ceramic article.

14. The glass-ceramic article according to claim 10 , wherein the composition further comprises, in wt %:
Au in an amount of from 0.01 to 1.5; or
Cr 2 O 3 in an amount of from 0.05 to 1.0; or
NiO in an amount of from 0.1 to 2.0; or
V 2 O 5 in an amount of from 0.1 to 2.0; or
Co 3 O 4 in an amount of from 0.01 to 2.0.

15. The glass-ceramic article according to claim 14 , wherein the glass-ceramic article has a transmittance color coordinate in the CIELAB color space of:
L*=from 50 to 90;
a*=from −20 to 30; and
b*=from 0 to 40

for a CIE illuminant F02 under SCI UVC conditions.

16. The glass-ceramic article according to claim 9 , wherein each of the petalite crystalline phase and the lithium silicate crystalline phase in the glass-ceramic article have greater weight percentages than other crystalline phases present in the glass-ceramic article.

17. The glass-ceramic article according to claim 9 , wherein the one or more colorants selected from the group consisting of NiO, Co 3 O 4 , MnO 2 , Cr 2 O 3 , Au, and V 2 O 5 .

18. A glass-ceramic article comprising:
a petalite crystalline phase; and
a lithium silicate crystalline phase,
wherein:
each of the petalite crystalline phase and the lithium silicate crystalline phase in the glass-ceramic article have greater weight percentages than other crystalline phases present in the glass-ceramic article;
the glass-ceramic article comprises one or more colorants selected from the group consisting of TiO 2 , Fe 2 O 3 , NiO, Co 3 O 4 , MnO 2 , Cr 2 O 3 , Au, and V 2 O 5 ; and
the glass-ceramic article has a transmittance color coordinate in CIELAB color space of:
L*=from 50 to 90;
a*=from −20 to 30; and
b*=from 0 to 40

for a CIE illuminant F02 under SCI UVC conditions.

19. The glass-ceramic article according to claim 18 further comprising, in wt %:
SiO 2 in an amount of from 55 to 80;
Al 2 O 3 in an amount of from 2 to 20;
Li 2 O in an amount of from 5 to 20;
P 2 O 5 in an amount of from 0.5 to 6; and
ZrO 2 in an amount of from 0.2 to 15.

20. The glass-ceramic article according to claim 18 , wherein the glass-ceramic article has a fracture toughness of 1 MPa·m 1/2 or greater.

21. The glass-ceramic article according to claim 18 , wherein the glass-ceramic article has a Vickers hardness of 600 kgf/mm 2 or greater.

22. The glass-ceramic article according to claim 18 , wherein the glass-ceramic article has a ring-on-ring strength of at least 300 MPa.

23. The glass-ceramic article according to claim 18 , wherein the one or more colorants selected from the group consisting of NiO, Co 3 O 4 , MnO 2 , Cr 2 O 3 , Au, and V 2 O 5 .

24. The glass-ceramic article according to claim 18 , wherein the glass-ceramic article comprises 0.01 wt. % to 5 wt. % of the one or more colorants.

Assignees

• Corning Inc

Inventors

• Beall George Halsey
• Fu Qiang
• Smith Charlene Marie

Classifications

• C03C10/0027 Primary

  containing SiO2, Al2O3, Li2O as main constituents · CPC title

• C03C3/097

  containing phosphorus, niobium or tantalum · CPC title

• C03C10/0009 Primary

  containing silica as main constituent · CPC title

• C03C1/04

  Opacifiers, e.g. fluorides or phosphates; Pigments · CPC title

• C03C4/02

  for coloured glass · CPC title