Systems for separating isotopes from a sample of fission products

Patent metadata

Field	Value
Publication number	US-11839852-B2
Application number	US-202117154658-A
Country	US
Kind code	B2
Filing date	Jan 21, 2021
Priority date	Oct 5, 2018
Publication date	Dec 12, 2023
Grant date	Dec 12, 2023

Abstract

Systems and methods for efficient, effective, and safe separation and isolation of multiple isotopes (e.g., Mo, Zr, Ba, Sr, Te, and lanthanide isotopes) from fission products includes use of a plurality of chromatography columns, each containing a chromatographic resin formulated to target one or more particular isotopes. The system is operable in a “series” configuration to load the multiple columns by a single pass of the sample. Then, the system may be transitioned (e.g., using valves) to a “parallel” configuration in which multiple columns of the system may be operated simultaneously to elute targeted isotopes. Additional parallel operations of the columns, using different eluent compositions, may be used to elute different targeted isotopes. The system may be reconditioned in preparation for a subsequent sample.

First claim

What is claimed is:

1. A system for separating isotopes from a sample of fission products, the system comprising:
a plurality of chromatography columns, each containing a chromatographic resin differing in isotope selectivity from other chromatographic resins of the system; and
a plurality of valves in operative connection to lines communicating between at least some of the chromatography columns, the valves being adjustable to transition the system between a series configuration, wherein a fluid passage is defined through at least some of the chromatography columns in series, and a parallel configuration, wherein a plurality of fluid passages is defined through the chromatography columns in parallel, without physically repositioning the chromatography columns; and
at least one acid source in selective communication into at least one of the chromatography columns, the at least one acid source comprising:
at least one source of nitric acid in selective communication into at least one of the chromatography columns when the valves are adjusted to the parallel configuration; and
at least one source of hydrochloric acid in selective communication into at least one other of the chromatography columns when the valves are adjusted to the parallel configuration.

2. The system of claim 1 , further comprising a peristaltic pump in operative communication with the lines.

3. The system of claim 1 , further comprising a container at a leading end of the lines, the container comprising a plurality of openings.

4. The system of claim 3 , further comprising a heat source adjacent the container.

5. The system of claim 1 , wherein the plurality of chromatography columns comprises at least five chromatography columns.

6. The system of claim 1 , wherein:
the at least one acid source comprises a plurality of acid sources,
the valves, of the plurality of valves, are further adjustable to transition the system between the parallel configuration and an additional parallel configuration,
in the parallel configuration, at least some of the lines connect a respective inlet of a respective one of the chromatography columns to an acid source of the plurality of acid sources, and
in the additional parallel configuration, at least others of the lines connect the respective inlet of the respective one of at least some of the chromatography columns to at least one additional acid source of the plurality of acid sources.

7. The system of claim 1 , further comprising a receptacle at an outlet of the fluid passage of the series configuration, the receptacle comprising an acid to mix with fluid exiting the outlet of the fluid passage of the series configuration.

8. The system of claim 7 , wherein the fluid passage of the series configuration is defined through all but a last one of the chromatography columns of the system.

9. The system of claim 8 , wherein the lines comprise:
at least one line communicating:
from a final chromatography column of the chromatography columns in the series, and
to the receptacle; and

at least one additional line communicating:
from the receptacle, and
to the last one of the chromatography columns of the system.

10. A system for separating isotopes from a sample of fission products, the system comprising:
a container for a sample of fission products;
a plurality of chromatography columns comprising chromatographic resins of differing isotope selectivity, the container being operatively connectable into a chromatography column of the plurality of chromatography columns;
a plurality of acid sources, each operatively connectable, via at least one valve of a plurality of valves, into at least one of the chromatography columns of the plurality of chromatography columns;
a plurality of receptacles, each operatively connectable, via at least one other valve of the plurality of valves, out from at least one of the chromatography columns of the plurality of chromatography columns; and
the plurality of valves being adjustable to transition the system, without physically repositioning the chromatography columns, between:
a series configuration, wherein a continuous fluid passage is defined through a series of at least some of the chromatography columns to a receptacle of the plurality of receptacles; and
a parallel configuration, wherein a distinct fluid passage is defined, for each respective chromatography column of the chromatography columns:
from at least one of the acid sources, of the plurality of acid sources, through the respective chromatography column, and
to a respective additional receptacle, of the plurality of receptacles,

at least one additional valve, of the plurality of valves, adjustable to transition an inlet of the continuous fluid passage, of the series configuration, between the container and a preconditioning solution source comprising nitric acid.

11. The system of claim 10 , wherein the plurality of valves is further adjustable to transition the system, without physically repositioning the chromatography columns, between:
the parallel configuration; and
an additional parallel configuration, wherein an additional distinct fluid passage is defined, for each respective chromatography column of at least some of the chromatography columns:
from at least one other of the acid sources, of the plurality of acid sources, through the respective chromatography column, and
to a respective other receptacle, of the plurality of receptacles.

12. The system of claim 10 , further comprising a heat source adjacent the container.

13. A system for separating isotopes from a sample of fission products, the system comprising:
a plurality of chromatography columns reconfigurable, without physically repositioning the chromatography columns, between at least one series configuration and at least one parallel configuration, each chromatography column of the plurality of chromatographic columns containing a different chromatographic resin of a plurality of chromatographic resins comprising:
a first chromatographic resin conditionable for an isotope selectively specific to zirconium (Zr) isotopes and reconditionable for an isotope selectivity specific to uranium (U) isotopes;
a second chromatographic resin conditionable for an isotope selectivity specific to at least one lanthanide isotope;
a third chromatographic resin conditionable for an isotope selectivity specific to molybdenum (Mo) isotopes,
a fourth chromatographic rein conditionable for an isotope selectivity specific to barium (Ba) isotopes and reconditionable for an isotope selectivity specific to strontium (Sr) isotopes; and
a fifth chromatographic resin conditionable for an isotope selectivity specific to tellurium (Te) isotopes;

the at least one series configuration defining a continuous fluid passage through at least some of the chromatography columns of the plurality of chromatography columns, and
the at least one parallel configuration defining, through each respective chromatography column of the plurality of chromatography columns, an individual fluid passage.

14. The system of claim 13 , wherein:
the first chromatographic resin is disposed in a first chromatography column, of the plurality of chromatography columns;
the second chromatographic resin is disposed in a second chromatography column, of the plurality of chromatography columns;
the third chromatographic resin is disposed in a third chromatography column, of the plurality of chromatography columns;
the fourth chromatographic resin is disposed in a fourth chromatography column, of the plurality of chromatography columns;
the fifth chromatographic resin is disposed in a

Assignees

• Battelle Energy Alliance Llc

Inventors

• Snow Mathew S
• Ward Jessica L

Classifications

• B01D59/30 Primary

  by ion exchange · CPC title

• B01D15/22

  relating to the construction of the column · CPC title

• B01D15/24

  relating to the treatment of the fractions to be distributed · CPC title

• C22B60/0265

  extraction by solid resins · CPC title

• B01D15/1864 Primary

  using two or more columns · CPC title