Display device

Patent metadata

Field	Value
Publication number	US-11837119-B2
Application number	US-202017090829-A
Country	US
Kind code	B2
Filing date	Nov 5, 2020
Priority date	Nov 20, 2019
Publication date	Dec 5, 2023
Grant date	Dec 5, 2023

Abstract

A display device including a display panel, a variable adhesive layer disposed on the display panel and a cover member disposed on the variable adhesive layer is provided. The variable adhesive layer includes a block copolymer and a plasticizer mixture, and the plasticizer mixture has a low critical solution temperature (LCST) of 60° C. to 80° C. The plasticizer mixture is phase-separated into two phases at a temperature equal to or higher than the low critical solution temperature, thereby significantly lowering adhesion of the variable adhesive layer. Accordingly, the display device of the present disclosure has excellent adhesion reliability and provides an advantage of easy reworking since the adhesion significantly decreases at a temperature equal to or higher than the low critical solution temperature. In addition, the display device has excellent folding characteristics due to the presence of the plasticizers.

First claim

What is claimed is:

1. A display device, comprising:
a display panel having a flexibility;
a variable adhesive layer disposed on the display panel; and
a cover member disposed on the variable adhesive layer,

wherein:
the variable adhesive layer includes a block copolymer and a plasticizer mixture;
the plasticizer mixture has a low critical solution temperature (LCST) of 60° C. to 80° C.;
the plasticizer mixture comprises a first plasticizer and a second plasticizer, wherein a molecular weight of the first plasticizer is four times or more higher than a molecular weight of the second plasticizer;
the first plasticizer and the second plasticizer are present in a single phase in the variable adhesive layer at a temperature lower than the low critical solution temperature, and are phase-separated into two phases in the variable adhesive layer at a temperature equal to or higher than the low critical solution temperature; and
the second plasticizer migrates to a surface of the variable adhesive layer at a temperature equal to or higher than the low critical solution temperature.

2. The display device of claim 1 , wherein a weight ratio of the first plasticizer to the second plasticizer is from 25:75 to 50:50.

3. The display device of claim 1 , wherein the molecular weight of the first plasticizer is 5,000 g/mol or more, and the molecular weight of the second plasticizer is 500 g/mol or less.

4. The display device of claim 1 , wherein the first plasticizer comprises polyisobutylene, polyisoprene, an isobutylene-isoprene copolymer, polyethylene glycol, polyethylene, polyester, polybutene, or combinations thereof.

5. The display device of claim 1 , wherein the second plasticizer comprises a phthalate-based compound, an aliphatic diester, a phosphate-based compound, or combinations thereof.

6. The display device of claim 1 , wherein the block copolymer comprises two types of blocks having different glass transition temperatures to form a hard domain and a soft domain in the variable adhesive layer.

7. The display device of claim 1 , wherein the block copolymer comprises a first block having a glass transition temperature of −20° C. or less and a second block having a glass transition temperature of 80° C. or more.

8. The display device of claim 7 , wherein a weight ratio of the first block to the second block is from 65:35 to 85:15.

9. The display device of claim 7 , wherein the first block is an alkyl acrylate compound.

10. The display device of claim 7 , wherein the second block comprises an alkyl methacrylate compound, a vinyl aromatic compound, or a combination thereof.

11. The display device of claim 1 , wherein the block copolymer is a diblock copolymer or a triblock copolymer.

12. The display device of claim 1 , wherein the block copolymer has a weight average molecular weight of from 70,000 g/mol to 100,000 g/mol.

13. The display device of claim 1 , wherein a polydispersity index (PDI) of the block copolymer is from 1.00 to 1.15.

14. The display device of claim 1 , wherein the variable adhesive layer comprises from 50 to 150 parts by weight of the plasticizer mixture in 100 parts by weight of the block copolymer.

15. The display device of claim 1 , wherein an adhesion of the variable adhesive layer is reduced by 50% or more, as compared to an initial adhesion of the variable adhesive layer at room temperature, at a temperature equal to or higher than the low critical solution temperature.

16. The display device of claim 15 , wherein the adhesion of the variable adhesive layer is 0.4 kgf/in or less at the temperature equal to or higher than the low critical solution temperature.

Assignees

• Lg Display Co Ltd

Inventors

• Youn Yeoo
• Park Jeongbeom

Classifications

• H10K59/8722

  Peripheral sealing arrangements, e.g. adhesives, sealants · CPC title

• H10K59/87 Primary

  Passivation; Containers; Encapsulations · CPC title

• G09F9/301 Primary

  flexible foldable or roll-able electronic displays, e.g. thin LCD, OLED · CPC title

• G06F1/1652 Primary

  the display being flexible, e.g. mimicking a sheet of paper, or rollable · CPC title

• C08L53/00

  Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers · CPC title