Functional-agent-containing fiber and method for manufacturing same

Patent metadata

Field	Value
Publication number	US-11834779-B2
Application number	US-201816630316-A
Country	US
Kind code	B2
Filing date	Mar 26, 2018
Priority date	Jul 14, 2017
Publication date	Dec 5, 2023
Grant date	Dec 5, 2023

Abstract

Functional agent-containing fibers according to an embodiment of the present invention, wherein a functional agent is supported by silicone fixed to the fibers. The silicone includes an acrylic-modified organopolysiloxane having two or more acrylic groups per molecule. A rate of decrease in the functional agent after the functional agent-containing fibers are washed 10 times is less than 40%. In the present invention, the functional agent-containing fibers may be produced, e.g., by irradiating fibers impregnated with a fiber treatment agent A containing silicone with an electron beam so that the silicone is fixed to the fibers, and impregnating the fibers to which the silicone has been fixed with a fiber treatment agent B containing a functional agent. The functional agent-containing fibers may be produced, e.g., by impregnating fibers with a fiber treatment agent C containing silicone and a functional agent and irradiating the fibers impregnated with the fiber treatment agent C with an electron beam so that the silicone is fixed to the fibers and the functional agent is supported by the silicone fixed to the fibers. Thus, functional agent-containing fibers having improved washing resistance and a method for producing the fibers are provided.

First claim

The invention claimed is:

1. Functional agent-containing fibers comprising a functional agent,
wherein the functional agent is supported by silicone fixed to the fibers by structural entanglement or hydrophobic interaction,
the silicone comprises an acrylic-modified organopolysiloxane having two or more acrylic groups per molecule,
the acrylic-modified organopolysiloxane having two or more acrylic groups per molecule contains a unit represented by the following general formula (1) in the molecule:

wherein R 1 represents a same or different unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms, R 2 represents a hydrogen atom, m is an integer of 1 to 8, and a and b are positive numbers that satisfy a+b≤3,
the acrylic-modified organopolysiloxane has a viscosity of 50 to 5000 mPa·s at 25° C., and
a rate of decrease of the functional agent after the functional agent-containing fibers are washed 10 times is less than 40%.

2. The functional agent-containing fibers according to claim 1 , wherein the functional agent is at least one selected from the group consisting of a fatty acid, a polyphenol, a protein, and a polysaccharide.

3. The functional agent-containing fibers according to claim 1 , wherein the fibers comprise one or more natural fibers selected from the group consisting of cotton, silk, hemp, wool, angora, and mohair.

4. The functional agent-containing fibers according to claim 1 , wherein the fibers are in at least one form selected from the group consisting of staple, filament, tow, yarn, woven fabric, knitted fabric, wadding, and nonwoven fabric.

5. The functional agent-containing fibers according to claim 1 , wherein in the general formula (1), R 1 is a methyl group.

6. The functional agent-containing fibers according to claim 1 , wherein the functional agent is at least one selected from the group consisting of fucoidan and isosaponarin.

7. The functional agent-containing fibers according to claim 1 , wherein the functional agent is at least one selected from the group consisting of an oleic acid, sericin, fucoidan, and isosaponarin.

8. A method for producing functional agent-containing fibers comprising a functional agent,
the method comprising:
irradiating fibers impregnated with a fiber treatment agent (A) comprising silicone with an electron beam so as to fix the silicone to the fibers; and
impregnating the fibers to which the silicone has been fixed with a fiber treatment agent (B) comprising a functional agent,
wherein the silicone comprises an acrylic-modified organopolysiloxane having two or more acrylic groups per molecule,
the functional agent is supported by the silicone fixed to the fibers by structural entanglement or hydrophobic interaction,
the acrylic-modified organopolysiloxane having two or more acrylic groups per molecule contains a unit represented by the following general formula (1) in the molecule:

wherein R 1 represents a same or different unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms, R 2 represents a hydrogen atom, m is an integer of 1 to 8, and a and b are positive numbers that satisfy a+b≤3, and
the acrylic-modified organopolysiloxane has a viscosity of 50 to 5000 mPa·s at 25° C.

9. A method for producing functional agent-containing fibers comprising a functional agent,
the method comprising:
impregnating fibers with a fiber treatment agent (C) comprising silicone and a functional agent; and
irradiating the fibers impregnated with the fiber treatment agent (C) with an electron beam so as to fix the silicone to the fibers,
wherein the silicone comprises an acrylic-modified organopolysiloxane having two or more acrylic groups per molecule,
the functional agent is supported by the silicone fixed to the fibers by structural entanglement or hydrophobic interaction,
the acrylic-modified organopolysiloxane having two or more acrylic groups per molecule contains a unit represented by the following general formula (1) in the molecule:

wherein R 1 represents a same or different unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms, R 2 represents a hydrogen atom, m is an integer of 1 to 8, and a and b are positive numbers that satisfy a+b≤3, and
the acrylic-modified organopolysiloxane has a viscosity of 50 to 5000 mPa·s at 25° C.

10. The method according to claim 9 , wherein the functional agent is at least one selected from the group consisting of a fatty acid, a polyphenol, a protein, and polysaccharide.

11. The method according to claim 9 , wherein the fibers comprise one or more natural fibers selected from the group consisting of cotton, silk, hemp, wool, angora, and mohair.

12. The method according to claim 9 , wherein the fibers are in at least one form selected from the group consisting of staple, filament, tow, yarn, woven fabric, knitted fabric, wadding, and nonwoven fabric.

13. The method according to claim 8 , wherein the functional agent is at least one selected from the group consisting of a fatty acid, a polyphenol, a protein, and polysaccharide.

14. The method according to claim 8 , wherein the fibers comprise one or more natural fibers selected from the group consisting of cotton, silk, hemp, wool, angora, and mohair.

15. The method according to claim 8 , wherein the fibers are in at least one form selected from the group consisting of staple, filament, tow, yarn, woven fabric, knitted fabric, wadding, and nonwoven fabric.

Assignees

• Shinetsu Chemical Co
• Kurashiki Boseki Kk

Inventors

• Irifune Shinji
• KANAI Tomoya
• Tanaka Masaki
• Sugiyama Minoru
• Morishima Hidenobu
• Sato Kazuhiro

Classifications

• D06M15/643 Primary

  containing silicon in the main chain · CPC title

• D06M13/152

  having a hydroxy group bound to a carbon atom of a six-membered aromatic ring · CPC title

• D06M13/184

  Carboxylic acids; Anhydrides, halides or salts thereof · CPC title

• D06M14/18

  using wave energy or particle radiation · CPC title

• D06M15/03

  Polysaccharides or derivatives thereof · CPC title