Method for producing polymerizable composition

Patent metadata

Field	Value
Publication number	US-11834549-B2
Application number	US-201916642802-A
Country	US
Kind code	B2
Filing date	Mar 29, 2019
Priority date	Mar 29, 2018
Publication date	Dec 5, 2023
Grant date	Dec 5, 2023

Abstract

A method for producing a polymerizable composition, the method including: step (1) of preparing composition A having a water content of 200 ppm by mass or less, the composition A including a polyisocyanate component but not including a polymerization catalyst; step (2) of preparing composition B having a water content of 1,000 ppm by mass or less, the composition B including a polythiol component; and step (3) of mixing the composition A and the composition B and obtaining a polymerizable composition, and also a method for producing an optical component, the method including: a step of injecting the above-mentioned polymerizable composition into a molding die; and a step of polymerizing the polymerizable composition.

First claim

The invention claimed is:

1. A method for producing a polymerizable composition, the method comprising:
step (1) of adjusting a water content of a composition A comprising a polyisocyanate component to be 200 ppm by mass or less, the composition A not including a polymerization catalyst;
step (2) of mixing a polythiol component and a polymerization catalyst, thereby obtaining a composition B and then adjusting a water content of the composition B to be 1,000 ppm by mass or less; and
step (3) of mixing the composition A and the composition B, thereby obtaining a polymerizable composition,
wherein the polyisocyanate component is at least one selected from the group consisting of 2,5-bis(isocyanatomethyl)-bicyclo[2.2.1]heptane, 2,6-bis(isocyanatomethyl)-bicyclo[2.2.1]heptane, 1,3-bis(isocyanatomethyl)cyclohexane, 1,4-bis(isocyanatomethyl)cyclohexane, 1,3-bis(isocyanatomethyl)benzene, 1,4-bis(isocyanatomethyl)benzene, dicyclohexylmethane-4,4′-diisocyanate, isophorone diisocyanate, and hexamethylene diisocyanate,
the polythiol component is at least one selected from the group consisting of 2,5-bis(mercaptomethyl)-1,4-dithiane, pentaerythritol tetrakis(2-mercaptoacetate), pentaerythritol tetrakis(3-mercaptopropionate), 4-mercaptomethyl-1,8-dimercapto-3,6-dithiaoctane, 4,7-bis(mercaptomethyl)-3,6,9-trithia-1,11-undecanedithiol, 4,8-bis(mercaptomethyl)-3,6,9-trithia-1,11-undecanedithiol, 5,7-bis(mercaptomethyl)-3,6,9-trithia-1,11-undecanedithiol trimethylolpropane tris(2-mercaptoacetate), trimethylolpropane -tris(3-mercaptopropionate), butanediol bis(2-mercaptoacetate), butanediol bis(3-mercaptopropionate), dipentaerythritol hexakis(2-mercaptoacetate), and dipentaerythritol hexakis(3-mercaptopropionate), and
the polymerization catalyst is a tin compound or a nitrogen-containing compound.

2. The method for producing a polymerizable composition according to claim 1 , wherein in the step (1), the water content of the composition A is 40 ppm by mass or less.

3. The method for producing a polymerizable composition according to claim 1 , wherein in step (1), the water content is reduced under reduced pressure conditions.

4. The method for producing a polymerizable composition according to claim 1 , wherein in step (2), the water content is reduced under reduced pressure conditions.

5. The method for producing a polymerizable composition according to claim 1 , wherein the composition A further includes a mold release agent.

6. The method for producing a polymerizable composition according to claim 1 , wherein the composition A further includes an ultraviolet absorber.

7. The method for producing a polymerizable composition according to claim 1 , wherein the polymerizable composition has a water content of 300 ppm by mass or less.

Assignees

• Hoya Lens Thailand Ltd

Inventors

• Kageyama Yukio
• Yamada Masahide

Classifications

• C08G18/7642 Primary

  containing at least two isocyanate or isothiocyanate groups linked to the aromatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate groups, e.g. xylylene diisocyanate or homologues substituted on the aromatic ring · CPC title

• B29D11/00009

  Production of simple or compound lenses · CPC title

• C08G18/10

  Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step · CPC title

• C08G18/3876 Primary

  containing mercapto groups · CPC title

• C08K5/3475

  condensed with carbocyclic rings · CPC title