Optical fibre having a crosslinked polyester coating

Patent metadata

Field	Value
Publication number	US-11834367-B2
Application number	US-201815733385-A
Country	US
Kind code	B2
Filing date	Jan 19, 2018
Priority date	Jan 19, 2018
Publication date	Dec 5, 2023
Grant date	Dec 5, 2023

Abstract

An optical fibre comprising: an optical waveguide comprising a glass core surrounded by a glass cladding; a coating surrounding said optical waveguide comprising a polymer material comprising a cured polyester obtained by: (a) esterification of a reactant (A) selected from carboxylic acids, triglycerides, and mixtures thereof, having a C16-C24 aliphatic chain comprising at least two conjugated double bonds, with a reactant (B) selected from polyols having at least 3 hydroxyl groups, the polyols being thermally stable up to 300° C.; (b) curing of the 10 so obtained polyester, in the presence of a transition metal salt, the transition metal being selected from Mn, Fe, Co, Cu, and Ni. Preferably, the step of curing is a thermal curing, preferably up to 300° C. The transition metal salt acts as curing accelerator, i.e. it increases the curing rate so as to match the optical fibre drawing speed, the temperature of the glass exiting the drawing step and the drawing tower height commonly used in industrial plants for optical fibre production.

First claim

The invention claimed is:

1. An optical fibre comprising:
an optical waveguide comprising a glass core surrounded by a glass cladding; and
a coating surrounding said optical waveguide comprising a polymer material comprising a cured polyester obtained by:
(a) esterification of a reactant (A) selected from the group consisting of carboxylic acids, triglycerides, and mixtures thereof, having a C 16 -C 24 aliphatic chain comprising at least two conjugated double bonds, with a reactant (B) selected from the group consisting of polyols having at least 3 hydroxyl groups, the polyols being thermally stable up to 300° C., to obtain a polyester; and
(b) curing of the obtained polyester, in the presence of a transition metal salt, the transition metal being selected from the group consisting of Mn, Fe, Co, Cu, and Ni.

2. The optical fibre according to claim 1 , wherein said step of curing is a thermal curing.

3. The optical fibre according to claim 2 , wherein thermal curing is carried out at a temperature within the range of 80° C. to 300° C.

4. The optical fibre according to claim 1 , wherein the reactant (A) is a monocarboxylic acid.

5. The optical fibre according to claim 1 , wherein the reactant (A) is an acid selected from the group consisting of alpha-eleostearic acid, calendic acid, punicic acid and licanic acid.

6. The optical fibre according to claim 1 , wherein the reactant (A) is a mixture of triglycerides containing at least 70 wt %, based on the total weight of said mixture, of C 16 -C 24 aliphatic chains comprising at least two conjugated double bonds.

7. The optical fibre according to claim 1 , wherein the reactant (B) is a polyol having from 3 to 9 hydroxyl groups.

8. The optical fibre according to claim 1 , wherein the hydroxyl groups of the polyols are primary hydroxyl groups.

9. The optical fibre according to claim 1 , wherein said reactant (B) is selected from the group consisting of: glycerol ethoxylate, glycerol propoxylate, trimethylolpropane ethoxylate, dipentaerythritol and mixtures thereof.

10. The optical fibre according to claim 1 , wherein the transition metal salt is present in an amount ranging from 100 ppm to 2000 ppm.

11. The optical fibre according to claim 1 , wherein said coating is selected from the group consisting of: a primary coating and a single coating.

12. The optical fibre according to claim 1 , wherein said coating is a primary coating which is surrounded by a secondary coating, said secondary coating comprising a polymer selected from the group consisting of: methacrylate polymer, acrylate polymer and mixtures thereof.

13. A process for coating an optical fibre comprising:
providing an optical waveguide comprising a glass core surrounded by a glass cladding;
applying a curable coating composition on the cladding, said coating composition comprising a polyester obtained by esterification of a reactant (A) selected from the group consisting of carboxylic acids, triglycerides, and mixtures thereof, having a C 16 -C 24 aliphatic chain comprising at least two conjugated double bonds, with a reactant (B) selected from the group consisting of polyols having at least 3 hydroxyl groups, the polyols being thermally stable up to 300° C.;
curing said curable coating composition in the presence of a transition metal salt, the transition metal being selected from the group consisting of Mn, Fe, Co, Cu, and Ni, so as to crosslink said polyester and to form the coating.

14. The process for coating an optical fibre according to claim 13 , wherein reactant (A) is a carboxylic acid having a C 16 -C 24 aliphatic chain comprising at least two conjugated double bonds, and the ratio between reactant (A) and reactant (B) is of one mole of reactant A per each hydroxyl group comprised in the reactant B.

15. The process for coating an optical fibre according to claim 13 , wherein reactant (A) is a triglyceride or mixture of triglycerides containing at least one C 16 -C 24 aliphatic chain comprising at least two conjugated double bonds, and the reactant A is made to react with reactant (B) in a molar ratio A/B within the range from 1:1 to 1:3, wherein A is expressed as number of moles of triglycerides having at least one chain comprising at least two conjugated double bonds and B is expressed as number of moles of polyol.

16. The process for coating an optical fibre according to claim 13 , wherein curing of the curable composition is a thermal curing at a temperature up to 300° C.

Assignees

• Prysmian Spa
• Milano Politecnico

Inventors

• Terruzzi Lidia
• De Martino Pamela
• Citterio Attilio
• Gola Massimo

Classifications

• C03C25/323 Primary

  Polyesters, e.g. alkyd resins · CPC title

• C03C25/106

  Single coatings · CPC title

• C09D167/08

  Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids · CPC title

• G02B6/02395

  Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture (G02B6/02052, G02B6/02057, G02B6/024, G02B6/032, G02B6/105, G02B6/14 take precedence; coating on fibre gratings G02B6/02104; multilayer core or cladding G02B6/036; reinforcing splice joints G02B6/2558; optical cables, i.e. comprising protective structures external to the protective coating such as a jacket or plural coated optical fibres G02B6/44; coating of glass to obtain optical fibres C03C25/104) · CPC title

• C03C25/1065

  Multiple coatings · CPC title