Boiler plant and carbon dioxide removal method

Patent metadata

Field	Value
Publication number	US-11833467-B2
Application number	US-202017779430-A
Country	US
Kind code	B2
Filing date	Dec 7, 2020
Priority date	Dec 27, 2019
Publication date	Dec 5, 2023
Grant date	Dec 5, 2023

Abstract

A boiler plant includes a carbon dioxide capture system. The carbon dioxide capture system has an absorbing-liquid regeneration device and an absorber. The absorbing-liquid regeneration device includes a regenerator, a first circulation line in which the absorbing liquid is taken out from the regenerator and is returned to the regenerator, and a second circulation line in which the absorbing liquid is taken out from the regenerator and is returned to the regenerator, a heat exchanger, a heater, and a switcher. The heat exchanger heats the absorbing liquid by exchanging heat between the absorbing liquid flowing through the first circulation line and steam from the boiler. The heater heats the absorbing liquid flowing in the second circulation line. The switcher switches between a first heating state, in which the absorbing liquid flows in the first circulation line, and a second heating state, in which the absorbing liquid flows in the second circulation line.

First claim

The invention claimed is:

1. A boiler plant comprising:
a boiler configured to generate steam with heat of a combustion gas generated through combustion of a fossil fuel; and
a carbon dioxide capture system configured to remove carbon dioxide contained in an exhaust gas exhausted from the boiler,
wherein the carbon dioxide capture system includes:
an absorbing-liquid regeneration device configured to separate the carbon dioxide from an absorbing liquid that has absorbed the carbon dioxide, and
an absorber configured to allow the exhaust gas from the boiler to flow thereinto, absorb the carbon dioxide in the exhaust gas in the absorbing liquid from the absorbing-liquid regeneration device, and discharge the exhaust gas from which the carbon dioxide has been removed, and

wherein the absorbing-liquid regeneration device includes:
a regenerator configured to allow the absorbing liquid, which has absorbed the carbon dioxide in the absorber, to flow thereinto, separate the carbon dioxide from the absorbing liquid in a high-temperature environment to discharge the carbon dioxide, and return the absorbing liquid from which the carbon dioxide has been separated to the absorber,
a first circulation line configured to take out the absorbing liquid from an inside of the regenerator and then return the taken-out absorbing liquid to the inside of the regenerator,
a second circulation line configured to take out the absorbing liquid from the inside of the regenerator and then return the taken-out absorbing liquid to the inside of the regenerator,
a heat exchanger in the first circulation line to heat the absorbing liquid by exchanging heat between the absorbing liquid flowing through the first circulation line and the steam from the boiler,
a heater in the second circulation line to heat the absorbing liquid flowing through the second circulation line, and
a switcher configured to switch between a first heating state in which the absorbing liquid flows through the first circulation line and a second heating state in which the absorbing liquid flows through the second circulation line.

2. The boiler plant according to claim 1 , wherein the absorbing-liquid regeneration device includes a switching controller configured to instruct the switcher to bring about the first heating state when a steam condition that a temperature of the steam sent from the boiler to the heat exchanger is equal to or higher than a predetermined temperature and a pressure of the steam is equal to or higher than a predetermined pressure is satisfied, and to instruct the switcher to bring about the second heating state when the steam condition is not satisfied.

3. The boiler plant according to claim 2 , wherein the absorbing-liquid regeneration device includes:
a temperature sensor configured to detect a temperature of the absorbing liquid reserved in the regenerator, and
a second heating controller configured to heat the absorbing liquid by the heater when the temperature detected by the temperature sensor becomes lower than a predetermined temperature in the second heating state.

4. The boiler plant according to claim 2 ,
wherein the absorbing-liquid regeneration device includes a secondary battery, and a charging and discharging controller configured to control charging and discharging of the secondary battery, and
wherein the heater has an electric heater configured to generate heat by supplying power from the secondary battery.

5. The boiler plant according to claim 4 , wherein the charging and discharging controller is configured to bring about a chargeable state in which a power generation facility and the secondary battery are electrically connected to each other such that power is chargeable from the power generation facility to the secondary battery when the power generation facility is generating power, and to bring about a dischargeable state in which the secondary battery and the electric heater are electrically connected to each other such that power is dischargeable from the secondary battery to the electric heater when the steam condition is not satisfied.

6. The boiler plant according to claim 5 , further comprising:
a steam turbine to be driven with the steam from the boiler; and
a generator configured to generate power by driving the steam turbine, wherein the power generation facility includes the generator.

7. The boiler plant according to claim 5 ,
wherein the power generation facility includes a carbon-free power generation facility, and
wherein the carbon-free power generation facility is configured to discharge carbon dioxide having a concentration lower than a carbon dioxide concentration in exhaust gas from a facility configured to generate power by using the combustion gas generated through the combustion of the fossil fuel, or the carbon-free power generation facility is is configured to not exhaust carbon dioxide during power generation.

8. The boiler plant according to claim 1 , further comprising:
a gas turbine to be driven with the combustion gas generated through the combustion of the fossil fuel,
wherein the boiler is a heat recovery system generator configured to generate steam with heat of the combustion gas exhausted from the gas turbine.

9. A carbon dioxide removal method comprising:
an absorbing-liquid regeneration step in which carbon dioxide is separated from an absorbing liquid that has absorbed the carbon dioxide, and
an absorption step in which the carbon dioxide in exhaust gas from a boiler is absorbed in the absorbing liquid processed in the absorbing-liquid regeneration step, and the exhaust gas from which the carbon dioxide has been removed is capable of being discharged,
wherein the absorbing-liquid regeneration step is executed by an absorbing-liquid regeneration device, the absorbing-liquid regeneration device including:
a regenerator configured to allow the absorbing liquid, which has absorbed the carbon dioxide via the absorption step, to flow thereinto, to separate the carbon dioxide from the absorbing liquid in a high-temperature environment to exhaust the carbon dioxide, and to cause the absorbing liquid from which the carbon dioxide has been separated to be used in the absorption step,
a first circulation line configured to take out the absorbing liquid from an inside of the regenerator and then return the taken-out absorbing liquid to the inside of the regenerator,
a second circulation line configured to take out the absorbing liquid from the inside of the regenerator and then return the taken-out absorbing liquid to the inside of the regenerator,
a heat exchanger in the first circulation line to heat the absorbing liquid by exchanging heat between the absorbing liquid flowing through the first circulation line and steam from the boiler, and
a heater in the second circulation line to heat the absorbing liquid flowing through the second circulation line,

wherein the absorbing-liquid regeneration step includes:
a first heating step in which the absorbing liquid flows through the first circulation line such that the absorbing liquid is heated by the heat exchanger, and
a second heating step in which the absorbing liquid flows through the second circulation line such that the absorbing liquid is heated by the heater, and

wherein, in the absorbing-liquid regeneration step, the first heating step and the second heating step are performed by switching heating states between a first heating state, in which the absorbing liquid flows through the first circulation line, and a second heating state, in which the absorbing liquid flows through the second circulation line.

10. A carbon dioxide removal method comprising:
an absorbing-liquid regeneration step in which carbon

Assignees

• Mitsubishi Heavy Ind Ltd
• Mitsubishi Heavy Ind Eng Ltd

Inventors

• Tsutsumi Atsushi
• Ishii Hiromi
• Tanaka Tetsuya
• Nagafuchi Naoyuki
• Kamijo Takashi

Classifications

• B01D53/1425 Primary

  Regeneration of liquid absorbents · CPC title

• B01D53/1412

  Controlling the absorption process · CPC title

• B01D53/1475

  Removing carbon dioxide · CPC title

• B01D53/18

  Absorbing units; Liquid distributors therefor (B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32) · CPC title

• F01K11/02

  the engines being turbines · CPC title