Carbon-sulfur composite, preparation method therefor, and lithium secondary battery comprising same

Patent metadata

Field	Value
Publication number	US-11831010-B2
Application number	US-202217964649-A
Country	US
Kind code	B2
Filing date	Oct 12, 2022
Priority date	Sep 28, 2017
Publication date	Nov 28, 2023
Grant date	Nov 28, 2023

Abstract

A carbon-sulfur composite including a carbonized metal-organic framework (MOF); and a sulfur compound introduced to at least a part of an outside surface and an inside of the carbonized metal-organic framework, wherein the carbonized metal-organic framework has a specific surface area of 2500 m2/g to 4000 m2/g, and the carbonized metal-organic framework has a pore volume of 0.1 cc/g to 10 cc/g, and a method for preparing the same.

First claim

The invention claimed is:

1. A carbon-sulfur composite comprising:
a carbonized metal-organic framework; and
a sulfur compound introduced to at least a part of an outside surface and an inside of the carbonized metal-organic framework,
wherein the specific surface area of 3000 m 2 /g to 4000 m 2 /g according to N 2 adsorption BET analysis, and
the pore volume of 0.1 cc/g to 10 cc/g.

2. The carbon-sulfur composite of claim 1 , wherein the specific surface area of the carbonized metal-organic framework is 3000 m 2 /g.

3. The carbon-sulfur composite of claim 1 , wherein the pore volume of the carbonized metal-organic framework is 2.2 cc/g to 3.0 cc/g.

4. The carbon-sulfur composite of claim 1 , wherein the metal-organic framework comprises a structural unit represented by the following Chemical Formula 1:
[M x (L) y ]  [Chemical Formula 1]

wherein
M is one or more metal selected from the group consisting of copper (Cu), zinc (Zn), iron (Fe), nickel (Ni), chromium (Cr), scandium (Sc), cobalt (Co), titanium (Ti), manganese (Mn), vanadium (V), aluminum (Al), magnesium (Mg), gallium (Ga) and indium (In);
L is one or more organic metal ligand selected from the group consisting of 1,4-benzenedicarboxylate (BDC), 1,3,5-benzenetricarboxlate (BTC), 1,1′-biphenyl-3,3′,5,5′-tetracarboxylate (BPTC) and 2-(N,N,N′,N′-tetrakis(4-carboxyphenyl)-biphenyl-4,4′-diamine (TCBTDA); and
x is an integer of 2 to 6, and y is an integer of 2 to 12.

5. The carbon-sulfur composite of claim 1 , wherein the carbonized metal-organic framework and the sulfur compound are present in a weight ratio of 9:1 to 1:9.

6. A method for preparing a carbon-sulfur composite according to claim 1 , comprising:
(a) preparing a carbonized metal-organic framework by carbonizing a metal-organic framework at a temperature of 950° C. or higher; and
(b) preparing a carbon-sulfur composite by mixing the carbonized metal-organic framework of (a) with a sulfur compound.

7. The method for preparing a carbon-sulfur composite of claim 6 , wherein, in (a), the metal-organic framework is carbonized at 950° C. to 2,000° C.

8. The method for preparing a carbon-sulfur composite of claim 6 , wherein, in (a), the metal-organic framework is carbonized at 950° C. to 1,500° C.

9. The method for preparing a carbon-sulfur composite of claim 6 , wherein, in (a), the carbonized metal-organic framework has a pore volume of 2.2 cc/g to 3.0 cc/g.

10. The method for preparing a carbon-sulfur composite of claim 6 , wherein the metal-organic framework comprises a structural unit represented by the following Chemical Formula 1:
[M x (L) y ]  [Chemical Formula 1]

wherein
M is one or more metal selected from the group consisting of copper (Cu), zinc (Zn), iron (Fe), nickel (Ni), chromium (Cr), scandium (Sc), cobalt (Co), titanium (Ti), manganese (Mn), vanadium (V), aluminum (Al), magnesium (Mg), gallium (Ga) and indium (In);
L is one or more organic metal ligand selected from the group consisting of 1,4-benzenedicarboxylate (BDC), 1,3,5-benzenetricarboxlate (BTC), 1,1′-biphenyl-3,3′,5,5′-tetracarboxylate (BPTC) and 2-(N,N,N′,N′-tetrakis(4-carboxyphenyl)-biphenyl-4,4′-diamine (TCBTDA); and
x is an integer of 2 to 6, and y is an integer of 2 to 12.

11. The method for preparing a carbon-sulfur composite of claim 6 , wherein, in (b), the carbonized metal-organic framework and the sulfur compound are mixed in a weight ratio of 9:1 to 1:9.

12. A positive electrode comprising the carbon-sulfur composite of claim 1 .

13. The positive electrode of claim 12 , which is suitable for a lithium-sulfur battery.

14. A lithium secondary battery comprising:
the positive electrode of claim 12 ;
a negative electrode; and
an electrolyte.

Assignees

• Lg Energy Solution Ltd
• Univ Yonsei Iacf

Inventors

• Cho Eunkyung
• Han Suenghoon
• Song Myeong Jun
• Kim Il To
• Sohn Kwonnam
• Yang Doo Kyung
• Kim Jiwon
• Shin Moo Whan

Classifications

• H01M4/364 Primary

  as mixtures · CPC title

• C01B32/05

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• H01M4/38

  of elements or alloys · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/60

  of organic compounds · CPC title