Additive, electrolyte for lithium secondary battery and lithium secondary battery including the same

Patent metadata

Field	Value
Publication number	US-11830978-B2
Application number	US-202016887035-A
Country	US
Kind code	B2
Filing date	May 29, 2020
Priority date	May 31, 2019
Publication date	Nov 28, 2023
Grant date	Nov 28, 2023

Abstract

An electrolyte additive for a lithium secondary battery, an electrolyte, and a lithium secondary battery, the additive including a compound represented by Formula 1 below:

First claim

What is claimed is:

1. An electrolyte for a lithium secondary battery, the electrolyte comprising:
a lithium salt;
a non-aqueous organic solvent; and
an additive,
wherein the additive includes a compound represented by Formula 1,

wherein, in Formula 1,
X is S,
R 1 to R 3 are each independently a substituted or unsubstituted C 1 -C 30 alkyl group, a substituted or unsubstituted C 2 -C 30 alkenyl group, or a substituted or unsubstituted C 2 -C 30 alkynyl group, and
a substituent of the substituted C 1 -C 30 alkyl group, the substituted C 2 -C 30 alkenyl group, the substituted C 2 -C 30 alkynyl group, or the substituted vinyl group is a C 1 -C 10 alkyl group, a C 2 -C 10 alkenyl group, a C 2 -C 20 alkynyl group, a C 1 -C 10 alkoxy group, a halogen, a cyano group, a hydroxy group, or a nitro group, and
wherein the compound represented by Formula 1 is included in the electrolyte in an amount of about 0.1 wt % to about 5 wt %, based on a total weight of the electrolyte.

2. The electrolyte as claimed in claim 1 , wherein, in Formula 1, R 1 to R 3 are each independently an unsubstituted C 1 -C 30 alkyl group or a C 1 -C 30 alkyl group substituted with a methyl group, an ethyl group, a propyl group, a butyl group, —F, —Cl, —Br, —I, a cyano group, a hydroxy group, or a nitro group.

3. The electrolyte as claimed in claim 1 , wherein, in Formula 1, R 1 to R 3 are each independently an unsubstituted C 1 -C 30 alkyl group.

4. The electrolyte as claimed in claim 1 , wherein the lithium salt includes at least one of LiPF 6 , LiBF 4 , LiSbF 6 , LiAsF 6 , LiClO 4 , LiCF 3 SO 3 , Li(CF 3 SO 2 ) 2 N, LiC 4 F 9 SO 3 , LiAlO 2 , LiAlCl 4 , LiN(C x F 2x+1 SO 2 )(CyF 2y+1 SO 2 ), in which 2≤x≤20 and 2≤y≤20, LiCl, LiI, lithium bis(oxalato) borate, or LiPO 2 F 2 .

5. The electrolyte as claimed in claim 1 , wherein the non-aqueous organic solvent includes at least one of ethyl methyl carbonate (EMC), methyl propyl carbonate, ethyl propyl carbonate, dimethyl carbonate (DMC), diethyl carbonate (DEC), dipropyl carbonate, propylene carbonate (PC), ethylene carbonate (EC), fluoroethylene carbonate (FEC), vinylene carbonate (VC), vinylethylene carbonate (VEC), butylene carbonate, ethyl propionate, ethyl butyrate, dimethyl sulfoxide, dimethyl formamide, dimethylacetamide, gamma-valerolactone, gamma-butyrolactone, or tetrahydrofuran.

6. The electrolyte as claimed in claim 1 , wherein the non-aqueous organic solvent includes a mixed solvent of about 50 vol % to about 95 vol % of a chain carbonate and about 5 vol % to about 50 vol % of a cyclic carbonate.

7. A lithium secondary battery, comprising:
a cathode;
an anode; and
the electrolyte as claimed in claim 6 .

8. The lithium secondary battery as claimed in claim 7 , wherein the cathode includes a cathode active material having a layered structure.

9. The lithium secondary battery as claimed in claim 8 , wherein the cathode active material is represented by Formula 2:
Li s Ni 1−t M t O 2   <Formula 2>

wherein, in Formula 2,
M is Co, Mn, Al, Cu, Fe, Mg, Cr, Zn, B, or Ga, and
0.9≤s≤1.2 and 0<t≤0.99 are satisfied.

10. The lithium secondary battery as claimed in claim 8 , wherein the cathode active material is represented by Formula 3 or Formula 4:
Li s′ Ni t′ Co 1−t′−u′ Al u′ O 2   <Formula 3>

Li s′ Ni t′ Co 1−t′−u′ Mn u′ O 2   <Formula 4>

wherein, in Formulae 3 and 4, 0.9≤s′≤1.2, 0.1<t′≤0.98, 0<u′≤0.5, and 0<1−t′−u′≤0.5 are satisfied.

11. The lithium secondary battery as claimed in claim 7 , wherein the anode includes at least one of an anode active material, the anode active material including a lithium metal, a metal alloyable with lithium, a transition metal oxide, a non-transition metal oxide, or a carbon material.

12. The lithium secondary battery as claimed in claim 11 , wherein the anode active material includes at least one of a silicon compound, a carbon compound, a composite of the silicon compound and the carbon compound, or a silicon oxide (SiO a , 0<a<2).

Assignees

• Samsung Sdi Co Ltd

Inventors

• Woo Myungheui
• Shatunov Pavel
• TSAY Olga
• Kang Younghye
• Kim Aeran
• Park Hyejin
• Shin Jeongmin
• You Duckjae
• Lee Taejin
• Lee Harim
• Lim Jinhyeok
• Cho Wonseok
• Choi Hyunbong

Classifications

• H01M10/0567 Primary

  characterised by the additives · CPC title

• H01M4/366

  as layered products · CPC title

• H01M4/386

  Silicon or alloys based on silicon · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title