Syntactic foams as mechanically-triggered capture vehicles

Patent metadata

Field	Value
Publication number	US-11828685-B2
Application number	US-202117184887-A
Country	US
Kind code	B2
Filing date	Feb 25, 2021
Priority date	Feb 25, 2020
Publication date	Nov 28, 2023
Grant date	Nov 28, 2023

Abstract

Syntactic foams are materials including hollow microspheres distributed throughout a cured polymeric resin. Hollow microspheres within syntactic foams, including collapsible shells that enclose empty cavities, can serve as receptacles to capture environmental constituents upon applied temperature and pressure. An epoxy formulation including of EPON™ 828, HELOXY™ 61, and TETA was combined with hollow glass microspheres with isostatic crush strengths of 300, 3000, and 10,000 psi. Effects of pressure and temperature on the mechanical properties were evaluated via dynamic mechanical analysis. Storage modulus and glass transition temperature depended on formulation. Upon exposure to specific temperature and pressures, the hollow glass spheres embedded within the resin lose mechanical integrity and collapse, resulting in the generation of unencapsulated void spaces, primed to capture embedded liquid. Controllable loss of mechanical integrity enables syntactic foams to serve as on-demand receptacles to retain constituents in the surrounding environment, resulting from externally triggered pressures and temperatures.

First claim

That which is claimed:

1. An environmental constituent collecting vehicle comprising a syntactic foam, the syntactic foam comprising: a polymer matrix; and hollow microspheres, wherein the polymer matrix is prepared from an epoxy resin formulation comprising a diglycidyl ether of bisphenol A or bisphenol F, butyl glycidyl ether, and triethylene tetraamine (TETA).

2. The environmental constituent collecting vehicle of claim 1 , wherein the hollow microspheres comprise between 30 and 60 volume percent of the syntactic foam.

3. The environmental constituent collecting vehicle of claim 1 , wherein the hollow microspheres comprise glass microspheres.

4. The environmental constituent collecting vehicle of claim 3 , wherein the glass microspheres have a crush strength in a range of 250 psi to 28,000 psi.

5. The environmental constituent collecting vehicle of claim 1 , wherein the epoxy resin formulation comprises the diglycidyl ether of bisphenol A.

6. The environmental constituent collecting vehicle of claim 1 , wherein the syntactic foam has a glass transition temperature in a range of 70° C. to 85° C.

7. A method of collecting and analyzing an environmental constituent comprising: providing a vehicle for collecting the environmental constituent comprising a syntactic foam to an environment, the syntactic foam comprising a polymer matrix and hollow microspheres; collecting the environmental constituent from the environment with the vehicle; and analyzing the environmental constituent, wherein the polymer matrix is prepared from an epoxy resin formulation comprising a diglycidyl ether of bisphenol A or bisphenol F, butyl glycidyl ether, and triethylene tetraamine (TETA), and wherein collecting of the environmental constituent is initiated by pressure and/or temperature in the environment, and wherein pressure in the environment at which the environmental constituent is collected exceeds a crush strength of the hollow microspheres, and/or wherein temperature in the environment at which the environmental constituent is collected exceeds a glass transition temperature of the syntactic foam.

8. The method of claim 7 , wherein the hollow microspheres comprise between 30 and 60 volume percent of the syntactic foam.

9. The method of claim 7 , wherein the hollow microspheres comprise glass microspheres.

10. The method of claim 9 , wherein the glass microspheres have a crush strength in a range of 250 psi to 28,000 psi.

11. The method of claim 7 , wherein the epoxy resin formulation comprises the diglycidyl ether of bisphenol A.

12. The method of claim 7 , wherein the syntactic foam has a glass transition temperature in a range of 70° C. to 85° C.

13. The method of claim 7 , wherein the environment is a deep-sea marine environment.

14. The method of claim 7 , wherein the environment comprises an oil or gas well pipeline, and the environmental constituent is collected from the oil or gas well pipeline.

15. The method of claim 7 , wherein the environment is a marine water environment, and the environmental constituent collected is analyzed for impurities or pollutants to monitor quality of marine water.

16. The method of claim 7 , wherein the environmental constituent collected is analyzed for metal contamination to determine if metal contamination is present in the environment.

17. A method of collecting and analyzing a sample from an oil or gas well or pipeline comprising:
providing a vehicle for collecting the sample comprising a syntactic foam to the oil or gas well or pipeline, the syntactic foam comprising a polymer matrix and hollow microspheres;
collecting the sample from the oil or gas well or pipeline with the vehicle; and
analyzing the sample collected from the oil or gas well or pipeline,
wherein the polymer matrix is prepared from an epoxy resin formulation comprising a diglycidyl ether of bisphenol A or bisphenol F, butyl glycidyl ether, and triethylene tetraamine (TETA), and
wherein collecting of the sample is initiated by pressure and/or temperature in the oil or gas well or pipeline, and wherein pressure at which the sample is collected exceeds a crush strength of the hollow microspheres, and/or wherein temperature at which the sample is collected exceeds a glass transition temperature of the syntactic foam.

18. The method of claim 17 , wherein the epoxy resin formulation comprises the diglycidyl ether of bisphenol A.

Assignees

• Res Triangle Inst

Inventors

• Johnson Leah Marie
• Huffman Nicolas Daniel

Classifications

• G01N1/10 Primary

  in the liquid or fluent state {(burettes, pipettes B01L3/02; sampling of ground water E02D1/06; metering by volume of fluids or fluent solid material G01F11/00, G01F13/00)} · CPC title

• C08J9/32

  from compositions containing microballoons, e.g. syntactic foams · CPC title

• C08K7/28

  Glass · CPC title

• G01N33/1886

  using probes, e.g. submersible probes, buoys · CPC title

• G01N33/2858 Primary

  Metal particles · CPC title