Propylene copolymer with excellent optical properties

Patent metadata

Field	Value
Publication number	US-11827777-B2
Application number	US-201917273711-A
Country	US
Kind code	B2
Filing date	Sep 9, 2019
Priority date	Sep 26, 2018
Publication date	Nov 28, 2023
Grant date	Nov 28, 2023

Abstract

The present invention is directed to a polypropylene composition (P) comprising a first random propylene copolymer (A) and a second random propylene copolymer (B), said first random propylene copolymer (A) and said second random propylene copolymer (B) being copolymers of propylene and 1-hexene. Further, the present invention is directed to a blown film comprising said polypropylene composition (P).

First claim

The invention claimed is:

1. A polypropylene composition (P), comprising at least 90.0 wt-%, based on an overall weight of the polypropylene composition (P) of a copolymer (C) of propylene and 1-hexene, comprising
i) a first random propylene copolymer (A) of propylene and a 1-hexene having a 1-hexene content in a range of 0.1 to 3.0 wt-%, and
ii) a second random propylene copolymer (B) of propylene and 1-hexene having a higher 1-hexene content than that of the first random propylene copolymer (A), wherein the copolymer (C) has an overall 1-hexene content in a range of 3.8 to 10.0 wt-%,
and wherein the copolymer (C) has a xylene soluble content (XCS) in a range of 8.0 to 30.0 wt-%;
the polypropylene composition (P) fulfilling in-equation (1)
MFR( C )/MFR( A )≤1.0  (1),

wherein MFR(A) is melt flow rate MFR 2 (230° C., 2.16 kg) determined according to ISO 1133 in [g/10 min] of the first random propylene copolymer (A) and MFR(C) is melt flow rate MFR 2 (230° C., 2.16 kg) determined according to ISO 1133 in [g/10 min] of the copolymer (C).

2. The polypropylene composition (P) according to claim 1 , wherein the copolymer (C) has a melt flow rate MFR 2 (230° C., 2.16 kg) determined according to ISO 1133 in the range of 0.4 to 12.0 g/10 min.

3. The polypropylene composition (P) according to claim 1 , wherein a weight ratio between the first random propylene copolymer (A) and the second random propylene copolymer (B) within the copolymer (C) is in a range of 30:70 to 70:30.

4. The polypropylene composition (P) according to claim 1 , wherein the copolymer (C) has an amount of 2,1 erythro regio-defects of at least 0.4 mol-%.

5. The polypropylene composition (P) according to claim 1 , wherein
i) the first random propylene copolymer (A) has a melt flow rate MFR 2 (230° C., 2.16 kg) determined according to ISO 1133 in a range of 0.3 to 12.0 g/10 min, and/or
ii) the second random propylene copolymer (B) has a melt flow rate MFR 2 (230° C., 2.16 kg) determined according to ISO 1133 in a range of 0.2 to 9.0 g/10 min.

6. The polypropylene composition (P) according to claim 1 , wherein the copolymer (C) comprises 35.0 to 65.0 wt-% of the first random propylene copolymer (A) and 35.0 to 65.0 wt-% of the second random propylene copolymer (B), based on the overall weight of the copolymer (C).

7. The polypropylene composition (P) according to claim 1 , wherein the copolymer (C) fulfills in-equation (2)

4.5
≤

C
⁢

⁢
6
⁢

(
C
)

C
⁢

⁢
6
⁢

(
A
)

*

[
A
]

[
C
]

≤

9
.
0

(
2
)

wherein
C6(A) is the 1-hexene content of the first random propylene copolymer (A) based on a total weight of the first random propylene copolymer (A) in wt-%;
C6(C) is the 1-hexene content of the copolymer (C) based on a total weight of the copolymer (C) in wt-%; and
[A]/[C] is a weight ratio between the first random propylene copolymer (A) and the copolymer (C) [in g/g].

8. The polypropylene composition (P) according to claim 1 , wherein the copolymer (C) has an amount of hexane hot solubles (HHS) measured according to FDA 177.1520 equal to or below 1.5 wt-%.

9. An article, comprising at least 90.0 wt-% of the polypropylene composition (P) according to claim 1 .

10. The article according to claim 9 , wherein the article is a film.

11. The article according to claim 10 , wherein the film has
i) a haze before steam sterilization determined according to ASTM D 1003-00 measured on a 50 μm blown film below 10.0%, and
ii) a haze after steam sterilization determined according to ASTM D 1003-00 measured on a 50 μm blown film below 12.0%.

12. The article according to claim 10 , wherein the article is a sealing layer in a multi-layer film.

13. A process for the preparation of a copolymer (C) according to claim 1 , wherein the process is a sequential polymerization process comprising at least two reactors connected in series, wherein said process comprises the steps of
(A) polymerizing in a first reactor (R-1) which is a slurry reactor (SR), propylene and 1-hexene, and obtaining a first random propylene copolymer (A),
(B) transferring said first random propylene copolymer (A) and unreacted comonomers of the first reactor (R-1) in a second reactor (R-2) which is a gas phase reactor (GPR-1),
(C) feeding to said second reactor (R-2) propylene and 1-hexene,
(D) polymerizing in said second reactor (R-2) and in the presence of said first random propylene copolymer (A) propylene and 1-hexene obtaining a second random propylene copolymer (B), said first random propylene copolymer (A) and said second random propylene copolymer (B) form the copolymer (C) of the polypropylene composition (P),
wherein further
in the first reactor (R-1) and the second reactor (R-2) the polymerization takes place in the presence of a solid catalyst system (SCS), said solid catalyst system (SCS) comprises a transition metal compound of formula (I)
R n (Cp) 2 MX 2   (I)

wherein
M is zirconium or hafnium,
each X is independently a monovalent anionic sigma-ligand,
each Cp is an organic ligand independently selected from the group consisting of unsubstituted or substituted cyclopentadienyl which may be fused, substituted or unsubstituted indenyl and substituted or unsubstituted fluorenyl, said organic ligand coordinating to transition metal M,
R is a bivalent bridging group linking said organic ligand Cp,
n is 1 or 2, and
(ii) optionally a cocatalyst (Co) comprising an element (E) of group 13 of the periodic table.

14. The process according to claim 13 , wherein the transition metal compound of formula (I) is an organo-zirconium compound of formula (II) or (II′):

wherein
M is Zr;
each X is a sigma ligand selected from the group consisting of a hydrogen atom, a halogen atom, a C 1 -C 6 alkoxy group, C 1 -C 6 alkyl, phenyl, and a benzyl group;

Assignees

• Borealis Ag

Inventors

• Wang Jingbo
• Gahleitner Markus
• Bernreitner Klaus
• Leskinen Pauli
• Niedersüss Peter

Classifications

• C08L23/142 Primary

  at least partially crystalline copolymers of propene with other olefins · CPC title

• C08F2/001

  Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer (C08F295/00, C08F297/00 take precedence) · CPC title

• C08F4/65927

  two cyclopentadienyl rings being mutually bridged · CPC title

• C08F210/06 Primary

  Propene · CPC title

• C08F210/14

  Monomers containing five or more carbon atoms · CPC title