Systems and methods for refurbishing fuel cell stack components

Patent metadata

Field	Value
Publication number	US-11824205-B2
Application number	US-202117151373-A
Country	US
Kind code	B2
Filing date	Jan 18, 2021
Priority date	Jan 18, 2021
Publication date	Nov 21, 2023
Grant date	Nov 21, 2023

Abstract

A method of refurbishing a singulated fuel cell stack interconnect includes scanning a first pulsed laser beam on an air side of the interconnect to vaporize seal and corrosion barrier layer residue without vaporizing a metal oxide layer located on the air side of the interconnect below the corrosion barrier layer residue, and scanning a second pulsed laser beam which is different from the first pulsed laser beam on the exposed metal oxide layer on the air side of the interconnect to reflow the metal oxide layer without removing the metal oxide layer.

First claim

What is claimed is:

1. A method of refurbishing a singulated fuel cell stack interconnect, comprising:
scanning a first pulsed laser beam on an air side of the interconnect to vaporize seal and corrosion barrier layer residue without vaporizing a metal oxide layer located on the air side of the interconnect below the corrosion barrier layer residue; and
scanning a second pulsed laser beam which is different from the first pulsed laser beam on the exposed metal oxide layer on the air side of the interconnect to reflow the metal oxide layer without removing the metal oxide layer,
wherein the metal oxide layer comprises at least one of lanthanum strontium manganite or manganese cobalt oxide spinel.

2. The method of claim 1 , wherein the second pulsed laser beam has least one of a lower peak power, a shorter pulse width, a higher scanning speed, a smaller beam spot size, or a higher pulse frequency than the first pulsed laser beam.

3. The method of claim 2 , wherein the second pulsed laser beam has at least two of the lower peak power, the shorter pulse width, the higher scanning speed, the smaller beam spot size, or the higher pulse frequency than the first pulsed laser beam.

4. The method of claim 2 , wherein the second pulsed laser beam has the smaller beam spot size and a higher power density than the first pulsed laser beam.

5. The method of claim 4 , wherein the first pulsed laser beam has a beam spot size less than 1.5 mm, and the second pulsed laser beam has a beam spot size of less than 0.5 mm.

6. The method of claim 2 , wherein:
the first pulsed laser beam has:
a peak power ranging from about 800 W to about 1250 W;
a frequency ranging from about 5 kHz to about 15 kHz;
a scanning speed ranging from about 2500 mm/s to about 3500 mm/s;
a beam spot size ranging from about 0.5 mm to about 1 mm; and
a pulse width ranging from about 50 ns to about 150 ns; and

the second pulsed laser beam has:
a peak power ranging from about 250 W to about 750 W;
a frequency ranging from about 20 kHz to about 40 kHz;
a scanning speed ranging from about 4500 mm/s to about 5500 mm/s;
a beam spot size ranging from about 0.05 mm to about 0.15 mm; and
a pulse width ranging from about 15 ns to about 35 ns.

7. The method of claim 1 , wherein the interconnect comprises:
fuel holes extending through the interconnect;
air channels, strip seal regions disposed on opposing sides of the air channels, and ring seal regions surrounding the fuel holes located on the air side of the interconnect; and
fuel channels and a frame seal region surrounding the fuel channels located on a fuel side of the interconnect which is opposite to the air side of the interconnect.

8. The method of claim 7 , wherein:
the step of scanning the first pulsed laser beam comprises scanning the first pulsed laser beam in at least one of the ring seal regions and the strip seal regions; and
the step of scanning the second pulsed laser beam comprises scanning the second pulsed laser beam in the air channels and in at least one of the ring seal regions and the strip seal regions such that the metal oxide layer becomes smoother and denser in the air channels and in at least one of the ring seal regions and the strip seal regions.

9. The method of claim 7 , wherein:
the interconnect comprises a chromium-iron alloy; and
the corrosion barrier layer residue comprises a glass-ceramic material.

10. The method of claim 9 , further comprising removing solid oxide fuel cell ceramic electrolyte debris from the interconnect.

11. The method of claim 10 , further comprising singulating a solid oxide fuel cell stack comprising interconnects and solid oxide fuel cells to obtain the singulated fuel cell stack interconnect.

12. The method of claim 11 , further comprising vaporizing stack residue from the fuel side of the interconnect by scanning a third pulsed laser beam on the frame seal region followed by scanning a fourth pulsed laser beam on the frame seal region.

13. The method of claim 12 , wherein the third pulsed laser beam has at least one of a slower scanning speed and a higher peak power than the fourth laser beam.

14. The method of claim 12 , further comprising scanning a fifth pulsed laser beam on the fuel channels and the frame seal region on the fuel side of the interconnect to vaporize a chromium oxide layer.

15. The method of claim 14 , where the fifth pulsed laser beam has at least one of faster scanning speed, a lower peak power, a higher frequency and a shorter pulse width than the fourth pulsed laser beam.

16. A method of refurbishing a singulated fuel cell stack interconnect comprising fuel holes extending through the interconnect, air channels, strip seal regions disposed on opposing sides of the air channels, and ring seal regions surrounding the fuel holes located on the air side of the interconnect, the method comprising:
scanning a first pulsed laser beam on an air side of the interconnect to vaporize seal and corrosion barrier layer residue without vaporizing a metal oxide layer located on the air side of the interconnect below the corrosion barrier layer residue;
scanning a second pulsed laser beam which is different from the first pulsed laser beam on the exposed metal oxide layer on the air side of the interconnect to reflow the metal oxide layer without removing the metal oxide layer; and
forming microcavities through the metal oxide layer in the-seal ring regions by laser drilling after the step of scanning the second pulsed laser beam.

17. The method of claim 16 , wherein the microcavities have a diameter of about 25 μm to about 200 μm, and extend into the air side of the interconnect through the metal oxide layer.

18. The method of claim 16 , further comprising:
depositing a corrosion barrier layer on the metal oxide layer and into the microcavities at least in the seal ring regions; and
depositing a seal material on the corrosion barrier layer in the seal ring regions.

19. The method of claim 1 , wherein the first and the second pulsed laser beams are generated by an infrared pulsed fiber laser having a wavelength greater than 800 nm and less than 5,000 nm.

Assignees

• Bloom Energy Corp

Inventors

• Paran Drew
• Delkaninia Ali
• Lui Kendall
• Akin Tulin

Classifications

• H01M4/8878 Primary

  Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body · CPC title

• B23K26/06

  Shaping the laser beam, e.g. by masks or multi-focusing · CPC title

• B23K26/0622

  by shaping pulses · CPC title

• B23K26/0626

  Energy control of the laser beam (B23K26/0622 takes precedence) · CPC title

• B23K26/354

  by melting · CPC title