Battery with shear thickening, impact resistant electrolytes

Patent metadata

Field	Value
Publication number	US-11824162-B2
Application number	US-202217570972-A
Country	US
Kind code	B2
Filing date	Jan 7, 2022
Priority date	Apr 20, 2018
Publication date	Nov 21, 2023
Grant date	Nov 21, 2023

Abstract

A battery includes an anode, a cathode, and a porous separator having a surface and percolating pores providing a porosity of from 20% to 80%. A passively impact resistant composite electrolyte includes an electrolyte and electrically non-conducting particles that enable shear thickening. The particles can have a polydispersity index of no greater than 0.1, an average particle size in a range of from 50 nm to 1 um, and an absolute zeta potential of greater than ±40 mV. The shear thickening enabling particles can be from 10 wt. % to 40 wt. % of the total weight of the separator and shear thickening particles. Between 20-40 wt. % of the shear thickening enabling particles are located in the pores of the separator.

First claim

We claim:

1. A shear thickening battery, comprising:
an anode;
a cathode;
a porous separator material having a surface and percolating pores providing a porosity of from 20% to 80%;
shear thickening enabling particles having a polydispersity index of no greater than 0.1, an average particle size of in a range of 50 nm to 1 um, and an absolute zeta potential of greater than ±40 mV, the shear thickening enabling particles being distributed at the surface and within the pores of the separator, the shear thickening enabling particles comprising from 10 wt. % to 40 wt. % of the total weight of the separator and shear thickening particles, and wherein between 20-40 wt. % of the shear thickening enabling particles are located in the pores of the separator, and wherein the shear thickening enabling particles have an average hydrocluster diameter, and wherein the average pore diameter is from 1 to 100 times the size of the hydrocluster diameter; and,
an electrolyte.

2. The shear thickening battery of claim 1 , wherein the shear thickening particle loaded separator comprises a particle suspension agent, the particle suspension agent comprising at least one selected from the group consisting of stabilization polymers covalently bonded to at ie surface of the shear thickening particles, and a stabilizing surfactant, wherein the shear thickening particles have an electrochemical double layer, and the particle suspension agent has a chain length of greater than double a thickness of the electrochemical double layer.

3. The shear thickening battery of claim 1 , wherein the shear thickening enabling particles comprise at least one ceramic material selected from the group consisting of TiO 2 , Al 2 O 3 , ZrO 2 , Y 2 O 3 , HfO 2 , GeO 2 , Sc 2 O 3 , CeO 2 , MgO, BN and SiO 2 .

4. The shear thickening battery of claim 1 , wherein the shear thickening particles have a polydispersity index of no greater than 0.09.

5. The shear thickening battery of claim 1 , wherein the shear thickening enabling particles have an average particle size of from 100 nm to 900 nm.

6. The shear thickening battery of claim 1 , wherein the shear thickening enabling particles have an absolute zeta potential of greater than ±50 mV.

7. The shear thickening battery of claim 1 wherein said shear thickening enabling particles are essentially free of materials that volatilize at 80° C.

8. The shear thickening battery of claim 1 , wherein the porosity of the separator is from 20% to 40%.

9. The shear thickening battery of claim 1 , wherein the shear thickening enabling particles comprise from 10 wt. % to 40 wt. % based on the total weight of the shear thickening enabling particles and the electrolyte.

10. The shear thickening battery of claim 1 , further comprising an electrolyte salt in the electrolyte.

11. The shear thickening battery of claim 10 , wherein the electrolyte salt comprises at least one material selected from the group consisting of lithium hexafluorophosphate, lithium triflate, lithium perchlorate, lithium tetrafluoro borate, lithium hexafluoro lithium arsenate, lithium bis(trifluoromethane sulphone)imide, lithium bis(oxalate) borate, sodium perchlorate, sodium tetrafluoro borate, sodium hexafluoro arsenate, sodium bis(trifluoromethane sulphone)imide, sodium bis(oxalate) borate, sodium hexafluorophosphate and sodium triflate.

Assignees

• Ut Battelle Llc

Inventors

• Armstrong Beth L
• Veith Gabriel M
• Kalnaus Sergiy
• Wang Hsin
• Browning Katie L
• Cooley Kevin M

Classifications

• H01M10/0567 Primary

  characterised by the additives · CPC title

• C04B41/88

  Metals · CPC title

• H01M10/052

  Li-accumulators · CPC title

• H01M10/0568 Primary

  characterised by the solutes · CPC title

• H01M10/0569

  characterised by the solvents · CPC title