Dielectric fluids comprising natural bio-sourced oil with increased stability

Patent metadata

Field	Value
Publication number	US-11820951-B2
Application number	US-201916982215-A
Country	US
Kind code	B2
Filing date	Mar 20, 2019
Priority date	Mar 21, 2018
Publication date	Nov 21, 2023
Grant date	Nov 21, 2023

Abstract

A dielectric fluid is provided comprising a natural bio-sourced oil and one or more compounds selected from the group consisting of phosphite compounds. It has been discovered that addition of one or more compounds selected from the group consisting of phosphite compounds to dielectric fluids comprising oil impart a stabilizing effect that reduces, inhibits or prevents formation of stray gases in the dielectric fluid during ordinary use.

First claim

What is claimed is:

1. A dielectric fluid comprising a vegetable oil selected from the group consisting of canola oil, rapeseed oil, sunflower oil, soybean oil, and mixtures thereof;
a phosphite component comprising one or more phosphite compounds selected from phosphite compounds having one to three aryloxy groups; and
a phenolic antioxidant component,
wherein the phosphite component is present in an amount of from 0.1 to 0.5 wt % and the amount of the phosphite component is sufficient to reduce the stray gassing of the dielectric fluid as determined by dissolved gas analysis (ATSM D3612-02, Method C) by at least 60% as compared to a like dielectric fluid composition that does not contain a phosphite component, wherein the stray gas is hydrogen, ethane, methane or ethylene, and wherein the dielectric fluid has a breakdown voltage of at least 45 kV as determined by IEC 60156.

2. The dielectric fluid of claim 1 , wherein the phosphite component comprises three aryloxy groups.

3. The dielectric fluid of claim 1 , wherein the phenolic antioxidant component is selected from the group consisting of butylated hydroanisole; butylated hydrotoluene; tertiary butylhydroquinone; tetrahydrobutrophenone; propyl gallate; alpha-, beta- or delta-tocopherol; and mixtures thereof.

4. The dielectric fluid of claim 1 , wherein the phenolic antioxidant component is selected from the group consisting of Pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate); Hexamethylene bis[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]; Octadecyl-[3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate]; Ethylene bis(oxyethylene) bis-(3-(5-tert-butyl-4-hydroxy-m-tolyl)propionate); 2,6-Di-tert-butyl-4-(4,6-bis(octylthio)-1,3,5-triazin-2-ylamino)phenol; N,N′-hexane-1,6-diylbis(3-3,5-di-tert-butyl-4-hydroxyphenylpropionamide); 4,6-Bis(octylthiomethyl)-o-cresol; 4,4′-methylene-bis-2,6-di-tert-butyl phenol; and 2,6-Di-tert-butyl-4-methylphenol.

5. The dielectric fluid of claim 1 , wherein the dielectric fluid comprises a vegetable oil selected from the group consisting of canola oil, rape seed oil, and sunflower oil, and mixtures thereof.

6. The dielectric fluid of claim 1 , wherein the dielectric fluid comprises a vegetable oil selected from the group consisting of rape seed oil, canola oil, and mixtures thereof.

7. The dielectric fluid of claim 1 , wherein the dielectric fluid comprises a vegetable oil having an IV of from 50 to 200.

8. The dielectric fluid of claim 1 , wherein the dielectric fluid has a peroxide value of less than 5; or wherein the dielectric fluid has a peroxide value of less than 3; or wherein the dielectric fluid has a peroxide value of less than 2; or wherein the dielectric fluid has a peroxide value of less than 1; or wherein the dielectric fluid has a peroxide value of from about 0.01 to 5; or wherein the dielectric fluid has a peroxide value of from about 0.01 to 3; or wherein the dielectric fluid has a peroxide value of from about 0.01 to 2; or wherein the dielectric fluid has a peroxide value of from about 0.01 to 1; or wherein the dielectric fluid has a peroxide value of from about 0.1 to 1.

9. A dielectric fluid formulated for use in an electrical distribution or power device, the dielectric fluid comprising a vegetable oil selected from the group consisting of rape seed oil, canola oil, sunflower oil, soybean oil, and mixtures thereof;
a phosphite component comprising one or more phosphite compounds selected from phosphite compounds having one to three aryloxy groups; and
a phenolic antioxidant component,
wherein the phosphite component is present in an amount of from 0.1 to 0.5 wt % and the amount of the phosphite component is sufficient to reduce the stray gassing of the dielectric fluid as determined by dissolved gas analysis (ATSM D3612-02, Method C) by at least 60% as compared to a like dielectric fluid composition that does not contain a phosphite component, wherein the stray gas is hydrogen, ethane, methane or ethylene, and wherein the dielectric fluid has a breakdown voltage of at least 45 kV as determined by IEC 60156.

10. An electrical distribution or power device comprising a dielectric fluid of claim 1 .

11. The electrical distribution or power device of claim 10 , wherein the device is selected from a capacitor and a transformer.

12. The electrical distribution or power device of claim 10 , wherein the device is a transformer.

13. The dielectric fluid of claim 1 , wherein the phosphite component is present in an amount of from 0.1 to 0.5 wt % and the amount of the phosphite component is sufficient to reduce the stray gassing of the dielectric fluid as determined by dissolved gas analysis (ATSM D3612-02, Method C) by at least 60% as compared to a like dielectric fluid composition that does not contain a phosphite component, wherein the stray gas is ethane.

Assignees

• Cargill Inc

Inventors

• Kurth Todd L
• Wirtz Kevin R

Classifications

• C10M137/02 Primary

  having no phosphorus-to-carbon bond · CPC title

• C10M101/00

  Lubricating compositions characterised by the base-material being a mineral or fatty oil (containing more than 10% water C10M173/00) · CPC title

• C10M105/00

  Lubricating compositions characterised by the base-material being a non-macromolecular organic compound · CPC title

• C10M105/74

  containing phosphorus · CPC title

• C10M111/02

  at least one of them being a non-macromolecular organic compound · CPC title