Apparatus and process for the enhanced production of aromatic compounds

Patent metadata

Field	Value
Publication number	US-11820949-B2
Application number	US-202117149789-A
Country	US
Kind code	B2
Filing date	Jan 15, 2021
Priority date	Jan 15, 2021
Publication date	Nov 21, 2023
Grant date	Nov 21, 2023

Abstract

Embodiments of the present disclosure are directed to a process for the upgrading of petroleum products comprising subjecting a diesel feed to a hydrocracking process, thereby producing a hydrocrackate fraction; subjecting the hydrocrackate fraction to a catalytic reforming process, thereby producing a reformate; and recovering aromatics from the reformate. In accordance with another embodiment of the present disclosure, a method of producing aromatics may comprise introducing a diesel feed to a hydrocracking unit to produce a hydrocrackate fraction, passing the hydrocrackate fraction to a catalytic reforming unit to produce a reformate, and passing the reformate to an aromatic recovery complex to produce an aromatic fraction. In accordance with yet another embodiment of the present disclosure, an apparatus for the upgrading of petroleum products may comprise a hydrocracker, a catalytic reformer, and an aromatic recovery complex. The hydrocracker may be in fluid communication with the catalytic reformer, the catalytic reformer may be in fluid communication with an aromatic recovery complex, and the hydrocracker may be structurally configured to receive a diesel feed.

First claim

What is claimed is:

1. A process for the upgrading of petroleum products, the process comprising:
subjecting a diesel feed to a hydrocracking process, thereby producing a hydrocrackate fraction, wherein at least 90 wt. % of hydrocarbon molecules in the diesel feed have between 12 and 22 carbon atoms per molecule;
separating a naphtha feed into a light naphtha stream and a heavy naphtha stream, the heavy naphtha stream having a higher average number of carbons per molecule than the light naphtha stream;
subjecting the hydrocrackate fraction and the heavy naphtha stream to a catalytic reforming process, thereby producing a reformate; and
recovering aromatics from the reformate via an aromatic recovery complex,

wherein the heavy naphtha stream is subjected to the catalytic reforming process in conjunction with the hydrocrackate fraction, and wherein the heavy naphtha stream is sent directly to the catalytic reforming process after being separated from the naphtha feed.

2. The process of claim 1 , wherein the diesel feed is subjected to a hydrodesulphurization process prior to the hydrocracking process.

3. The process of claim 1 , wherein the hydrocrackate fraction has a boiling point of less than or equal to 180° C.

4. The process of claim 1 , wherein recovering aromatics from the reformate comprises producing a benzene/toluene/xylene (BTX) stream and an aromatic bottoms stream.

5. The process of claim 4 , wherein the aromatic bottoms stream is subjected to the hydrocracking process in conjunction with the diesel feed.

6. The process of claim 1 , wherein subjecting the diesel feed to the hydrocracking process further comprises producing a light gas fraction and the light gas fraction is subjected to a steam cracking process.

7. The process of claim 1 , wherein subjecting the diesel feed to the hydrocracking process further comprises producing a fuel fraction and a mass flow rate of the fuel fraction is less than 10 wt. % of a mass flow rate of the diesel feed.

8. The process of claim 1 , wherein the naphtha feed is subjected to a hydrodesulphurization process.

9. The process of claim 1 , wherein:
hydrocracking the diesel feed further comprises producing a light gas fraction,
the light gas fraction is subjected to a steam cracking process, and
the light naphtha stream is subjected to a steam cracking process in conjunction with the light gas fraction.

10. The process of claim 1 , wherein:
recovering aromatics from the reformate comprises producing a BTX stream and an aromatic bottoms stream, and
a mass flow rate of the BTX stream is at least 70% of a mass flow rate of the naphtha feed.

11. A method of producing aromatics comprising:
introducing a diesel feed to a hydrocracking unit to produce a hydrocrackate fraction, wherein at least 90 wt. % of hydrocarbon molecules in the diesel feed have between 12 and 22 carbon atoms per molecule;
separating, by a naphtha splitter, a naphtha feed into a light naphtha stream and a heavy naphtha stream, the heavy naphtha stream having a higher average number of carbons per molecule than the light naphtha stream;
passing the hydrocrackate fraction and the heavy naphtha stream to a catalytic reforming unit to produce a reformate; and
passing the reformate to an aromatic recovery complex to produce an aromatic fraction, wherein the heavy naphtha stream and hydrocrackate fraction are reformed simultaneously in the catalytic reforming unit, and wherein the heavy naphtha stream is passed directly to the catalytic reforming unit after being separated from the naphtha feed.

12. The method of claim 11 , wherein the diesel feed is subjected to a hydrodesulphurization process prior to the hydrocracking process.

13. The method of claim 11 , wherein the hydrocrackate fraction has a boiling point of less than or equal to 180° C.

14. The method of claim 11 , wherein the aromatic fraction comprises benzene/toluene/xylene (BTX) stream and an aromatic bottoms stream, wherein the aromatic bottoms stream is subjected to the hydrocracking process in conjunction with the diesel feed.

15. The method of claim 11 , wherein the hydrocracking unit further produces a light gas fraction and a fuel fraction, wherein the light gas fraction is subjected to a steam cracking process, and wherein a mass flow rate of the fuel fraction is less than 10 wt. % of a mass flow rate of the diesel feed.

16. The method of claim 11 , wherein:
the hydrocracking unit further produces a light gas fraction that is subjected to a steam cracking process, and
the light naphtha stream is subjected to a steam cracking process in conjunction with the light gas fraction.

17. The process of claim 1 , wherein the naphtha feed is an overhead liquid distillate from a first crude oil distillation unit within a refinery.

18. The method of claim 11 , wherein the naphtha feed is an overhead liquid distillate from a first crude oil distillation unit within a refinery.

Assignees

• Saudi Arabian Oil Co

Inventors

• Koseoglu Omer Refa

Classifications

• C10G69/10 Primary

  hydrocracking of higher boiling fractions into naphtha and reforming the naphtha obtained · CPC title

• C10G9/36

  with heated gases or vapours · CPC title

• C10G35/04

  Catalytic reforming · CPC title

• C10G45/02 Primary

  to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing · CPC title

• C10G2300/1055

  Diesel having a boiling range of about 230 - 330 °C · CPC title