Organic acid surfactant booster for contaminant removal from hydrocarbon-containing stream

Patent metadata

Field	Value
Publication number	US-11820940-B2
Application number	US-202217902133-A
Country	US
Kind code	B2
Filing date	Sep 2, 2022
Priority date	Sep 15, 2021
Publication date	Nov 21, 2023
Grant date	Nov 21, 2023

Abstract

Provided are extraction methods and systems to remove contaminants in a subterranean formation. The method of contaminant removal comprises introducing one or more organic acids and one or more organic acid surfactant boosters into a hydrocarbon-containing stream, recovering the hydrocarbon-containing stream from a subterranean formation, and separating at least a portion of the contaminants from the hydrocarbon-containing stream. The organic acids and the organic acid surfactant boosters have a synergistic effect that improves the contaminant removal efficacy of the organic acid.

First claim

What is claimed is:

1. A method of contaminant removal, wherein contaminant comprises amines and metals, comprising:
introducing one or more organic acids and one or more organic acid surfactant boosters into a hydrocarbon-containing stream, wherein the one or more organic acids and the one or more organic acids surfactant boosters are introduced into the hydrocarbon-containing stream at about a 0.01 to about 5% mol ratio surfactant to organic acid;
recovering the hydrocarbon-containing stream from a subterranean formation; and
separating at least a portion of contaminants from the hydrocarbon-containing stream, wherein at least the one or more organic acids and/or the one or more organic acid surfactant boosters interact with the contaminants in the hydrocarbon-containing stream to promote greater solubility of cationic contaminants in water and anionic contaminants in oil.

2. The method of claim 1 , wherein the one or more organic acids comprises at least one organic acid selected from the group consisting of acetic acid, citric acid, formic acid, maleic acid, glycolic acid, oxalic acid, lactic acid, uric acid, malic acid, and tartaric acid, and any combination thereof.

3. The method of claim 1 , wherein the one or more organic acid surfactant boosters comprise at least one surfactant selected from the group consisting of a betaine, phosphate ester, a quaternary amine, a polyol, a complex polyol ester, sulfonate, a sulfosuccinate, a thiophosphate ester, an alcohol alkoxylate, a sorbitan monooleate, and any combination thereof.

4. The method of claim 1 , wherein the one or more organic acid surfactant boosters comprise a betaine.

5. The method of claim 1 , wherein the one or more organic acid surfactant boosters comprise a thiophosphate ester.

6. The method of claim 1 , wherein the one or more organic acids and one or more organic acid surfactant boosters are injected in an injector well.

7. The method of claim 1 , wherein the one or more organic acids and the one or more organic acids surfactant boosters are separately added to the hydrocarbon-containing stream.

8. The method of claim 1 , wherein the introducing the one or more organic acids and one or more organic acid surfactant boosters into the hydrocarbon-containing stream comprises introducing the one or more organic acids and the one or more organic acid surfactant boosters into a wellbore to contact the hydrocarbon-containing stream in the wellbore.

9. The method of claim 8 , wherein the separating is performed in the wellbore.

10. The method of claim 1 , wherein the separating is performed subsea.

11. The method of claim 1 , wherein the introducing one or more organic acids and one or more organic acid surfactant boosters into the hydrocarbon-containing stream comprises flowing the one or more organic acids and one or more organic acid surfactant boosters through and umbilical to a subsea wellhead.

12. The method of claim 1 , wherein one or more organic acids and one or more organic acid surfactant boosters are added to a treatment fluid that is pumped into a well bore.

13. The method of claim 1 , wherein the separating further comprises removing salt from the hydrocarbon-containing stream.

14. The method of claim 1 , wherein the separating removes amines from the hydrocarbon-containing stream in an amount of about 50% or more by weight of the hydrocarbon-containing stream and further removes calcium from the hydrocarbon-containing stream in an amount of about 30% or more by weight of the hydrocarbon-containing stream.

15. The method of claim 1 , wherein the separating removes the amines from the hydrocarbon-containing stream in an amount of about 80% or more by weight of the hydrocarbon-containing stream and further calcium from the hydrocarbon-containing stream in an amount of about 70% or more by weight of the hydrocarbon liquid.

16. A method of contaminant removal, wherein contaminant comprises amines and metals, comprising:
introducing one or more organic acids and one or more betaines into a wellbore to contact a hydrocarbon-containing stream, wherein the one or more organic acids and the one or more betaines are introduced into the treatment fluid at an organic acid to organic acid surfactant booster mole ratio of about 0.01:0.5 thereby promoting greater solubility of cationic contaminants in water and anionic contaminants in oil; and
separating salt from the hydrocarbon-containing stream, wherein the separating salt further removes at least amines and calcium from the hydrocarbon-containing stream.

17. The method of claim 16 , wherein the one or more organic acids and one or more betaines are introduced into the wellbore through coiled tubing.

18. The method of claim 16 , wherein the one or more betaines comprise a cocamidopropyl betaine.

Assignees

• Halliburton Energy Services Inc

Inventors

• Hanak Vincent Andrew
• Kiser Chad
• Saulnier Richard
• Bosch Ronald
• Anderson George

Classifications

• C09K8/602 Primary

  containing surfactants · CPC title

• C09K8/74

  combined with additives added for specific purposes · CPC title

• C10G17/02 Primary

  with acids or acid-containing liquids, e.g. acid sludge · CPC title

• E21B43/35

  specially adapted for separating solids (down-hole drilling fluid separation systems E21B21/002; separating solids from drilling fluids E21B21/065) · CPC title

• E21B43/36

  Underwater separating arrangements (E21B43/38 takes precedence) · CPC title