Double perovskite

Patent metadata

Field	Value
Publication number	US-11820670-B2
Application number	US-202117167705-A
Country	US
Kind code	B2
Filing date	Feb 4, 2021
Priority date	Sep 2, 2015
Publication date	Nov 21, 2023
Grant date	Nov 21, 2023

Abstract

The present invention relates to a semiconductor device comprising a semiconducting material, wherein the semiconducting material comprises a compound comprising: (i) one or more first monocations [A]; (ii) one or more second monocations [B I ]; (iii) one or more trications [B III ]; and (iv) one or more halide anions [X]. The invention also relates to a process for producing a semiconductor device comprising said semiconducting material. Also described is a compound comprising: (i) one or more first monocations [A]; (ii) one or more second monocations [B I ] selected from Cu + , Ag + and Au + ; (iii) one or more trications [B III ]; and (iv) one or more halide anions [X].

First claim

The invention claimed is:

1. A semiconductor device comprising a semiconducting material, wherein the semiconducting material comprises a double perovskite compound having a formula selected from:
(H 2 N—C(H)═NH 2 ) 2 AgBiX 6(1-x) X′ 6x ,

(H 2 N—C(H)═NH 2 ) 2 AuBiX 6(1-x) X′ 6x ,

(H 2 N—C(H)═NH 2 ) 2 AgSbX 6(1-x) X′ 6x ,

(H 2 N—C(H)═NH 2 ) 2 AuSbX 6(1-x) X′ 6x ,

(CH 3 NH 3 ) 2 AgBiX 6(1-x) X′ 6x ,

(CH 3 NH 3 ) 2 AuBiX 6(1-x) X′ 6x ,

(CH 3 NH 3 ) 2 AgSbX 6(1-x) X′ 6x and

(CH 3 NH 3 ) 2 AuSbX 6(1-x) X′ 6x ,

wherein:
X is a first halide anion;
X′ is a second, different, halide anion; and
x is from 0.01 to 0.99.

2. The semiconductor device according to claim 1 , wherein X and X′ are selected from I − , Br − , Cl − and F − .

3. The semiconductor device according to claim 1 , wherein X is I − .

4. The semiconductor device according to claim 1 , wherein X′ is Br − or Cl − .

5. The semiconductor device according to claim 1 , wherein x is from 0.05 to 0.95 or from 0.2 to 0.8.

6. The semiconductor device according to claim 1 , wherein the semiconductor device is an optoelectronic device.

7. The semiconductor device according to claim 1 , wherein the semiconductor device is a photovoltaic device, a light-emitting device, or a photodetector.

8. The semiconductor device according to claim 1 , wherein the semiconductor device is a photovoltaic device.

9. The semiconductor device according to claim 1 , which semiconductor device comprises a layer of the semiconducting material.

10. The semiconductor device according to claim 9 , wherein the layer of the semiconducting material has a thickness of from 5 nm to 1000 nm.

11. The semiconductor device according claim 1 , which semiconductor device comprises:
an n-type region comprising at least one n-type layer;
a p-type region comprising at least one p-type layer; and, disposed between the n-type region and the p-type region:
a layer of the semiconducting material.

12. The semiconductor device according to claim 1 , which semiconductor device comprises a layer of said semiconducting material without open porosity.

13. The semiconductor device according to claim 11 , wherein the layer of the semiconducting material forms a planar heterojunction with the n-type region or the p-type region, or wherein the layer of the semiconducting material forms a first planar heterojunction with the n-type region and a second planar heterojunction with the p-type region.

14. The semiconductor device according to claim 1 , wherein the semiconductor device comprises:
an n-type region comprising at least one n-type layer;
a p-type region comprising at least one p-type layer; and, disposed between the n-type region and the p-type region:
(i) a porous scaffold material; and
(ii) said semiconducting material in contact with the scaffold material.

15. The semiconductor device according to claim 11 , wherein the n-type region comprises a compact layer of an n-type semiconductor, or wherein the p-type region comprises a layer of an organic p-type semiconductor.

16. The semiconductor device according to claim 1 , wherein said semiconducting material is a photoactive material.

17. A process for producing a semiconductor device comprising a semiconducting material, wherein the semiconducting material comprises a double perovskite compound having a formula selected from:
(H 2 N—C(H)═NH 2 ) 2 AgBiX 6(1-x) X′ 6x ,

(H 2 N—C(H)═NH 2 ) 2 AuBiX 6(1-x) X′ 6x ,

(H 2 N—C(H)═NH 2 ) 2 AgSbX 6(1-x) X′ 6x ,

(H 2 N—C(H)═NH 2 ) 2 AuSbX 6(1-x) X′ 6x ,

(CH 3 NH 3 ) 2 AgBiX 6(1-x) X′ 6x ,

(CH 3 NH 3 ) 2 AuBiX 6(1-x) X′ 6x ,

(CH 3 NH 3 ) 2 AgSbX 6(1-x) X′ 6x and

(CH 3 NH 3 ) 2 AuSbX 6(1-x) X′ 6x ,

wherein:
X is a first halide anion;
X′ is a second, different, halide anion; and
x is from 0.01 to 0.99,

which process comprises:
(a) disposing a second region on a first region, which second region comprises a layer of said semiconducting material.

18. The process according to claim 17 , wherein the process further comprises
(b) disposing a third region on the second region,
wherein:
said first region is an n-type region comprising at least one n-type layer and said third region is a p-type region comprising at least one p-type layer; or
said first region is a p-type region comprising at least one p-type layer and said third region is an n-type region comprising at least one n-type layer.

19. The process according to claim 17 , wherein (a) disposing a second region on a first region comprises:
(Ai) exposing the first region to vapour, which vapour comprises said semiconducting material or one or more reactants for producing said semiconducting material; and
(Aii) allowing deposition of the vapour onto the first region to produce a layer of said semiconducting material thereon; or
(Bi) disposing one or more precursor compositions on the first region, which one or more precursor compositions comprise: said semiconducting material and one or more solvents; or one or more reactants for producing said semiconducting material and one or more solvents; and
(Bii) removing the one or more solvents to produce on the first region a layer of said semiconducting material.

20. The process according to claim 19 , wherein the one or more reactants for producing the semiconducting material comprise one or more first precursor compounds, one or more second precursor compounds and one or more third precursor compounds,
which one or more first precursor compounds are selected from compounds of formula A[X];
which one or more second precursor compounds are selected from compounds of formula B I [X]; and
which one or more second precursor compounds are selected from compounds of formula B III [X] 3 ;
wherein
A is the first monocation;
B I is the second monocation which is Ag + or Au + ;
B III is the trication which is Sb 3+ or Bi 3+ ; and
each [X] is the one or more halide anions.

21. A semiconductor device obtainable by the process for producing a semiconductor device as defined in claim 17 .

22. A compound which is a double perovskite compound having a formula selected from:
(H 2 N—C(H)═NH 2 ) 2 AgBiX 6(1-x) X′ 6x ,

(H 2 N—C(H)═NH 2 ) 2 AuBiX 6(1-x) X′ 6x ,

(H 2 N—C(H)═NH 2 ) 2 AgSbX 6(1-x) X′ 6x ,

(H 2 N—C(H)═NH 2 ) 2 AuSbX 6(1-x) X′ 6x ,

(CH 3 NH 3 ) 2 AgBiX 6(1-x) X′ 6x ,

(CH 3 NH 3 ) 2 AUBiX 6(1-x) X′ 6x ,

(CH 3 NH 3 ) 2 AgSbX 6(1-x) X′ 6x and

(CH 3 NH 3 ) 2 AuSbX 6(1-x) X′ 6x ,

wherein:
X is a first halide anion;
X′ is a second, different, halide anion; and
x is from 0.01 to 0.99.

23. The compound according to claim 22 , wherein X and X′ are selected from I − , Br − , Cl − and F − .

24. The compound according to claim 22 , wherein X is I − .

25. The compound according to claim 22 , wherein X′ is Br − or Cl − .

26. The compound according to claim 22 , wherein x is from 0.05 to 0.95 or from 0.2 to 0.8.

Assignees

• Univ Oxford Innovation Ltd

Inventors

• Snaith Henry James
• Hagighirad Amir Abbas
• Giustino Feliciano
• Filip Marina
• Volonakis George

Classifications

• H10K85/50

  Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3 · CPC title

• H10K30/50

  Photovoltaic [PV] devices · CPC title

• C01G29/006 Primary

  Compounds containing bismuth, with or without oxygen or hydrogen, and containing two or more other elements · CPC title

• C01G30/006

  Halides (C01G30/001 takes precedence) · CPC title

• H01G9/0036

  Formation of the solid electrolyte layer · CPC title