Trace and low concentration CO2 removal methods and apparatus utilizing metal organic frameworks

Patent metadata

Field	Value
Publication number	US-11819795-B2
Application number	US-202017014330-A
Country	US
Kind code	B2
Filing date	Sep 8, 2020
Priority date	Sep 2, 2014
Publication date	Nov 21, 2023
Grant date	Nov 21, 2023

Abstract

Embodiments of the present disclosure describe a device for removing CO 2 comprising a gas flow inlet, a housing including a SIFSIX-3-Cu metal-organic framework (MOF) composition for sorbing and/or desorbing CO 2 , and a gas flow outlet. Embodiments of the present disclosure describe an anesthetic system comprising one or more regeneratable cartridges for sorbing and/or desorbing CO 2 , wherein each of the one or more regeneratable cartridge includes a metal-organic framework composition, wherein at least one of the regeneratable cartridges includes a SIFSIX-3-Cu MOF. Embodiments of the present disclosure describe an alkaline fuel cell comprising a catalyst layer including a SIFSIX-3-Cu MOF composition for sorbing and/or desorbing CO 2 .

First claim

What is claimed is:

1. A metal-organic framework (MOF) composition, the MOF composition comprising:
a SIFSIX-n-M MOF including a metal (M) and a ligand, wherein n is at least 2;
wherein the metal is selected from the group consisting of Co, Mn, Mo, Cr, Fe, Ca, Ba, Cs, Pb, Pt, Pd, Ru, Rh, and Cd.

2. The MOF composition of claim 1 , wherein the ligand is a nitrogen-containing heterocyclic ligand.

3. The MOF composition of claim 1 , wherein the ligand is selected from the group consisting of pyridine, 4,4′-Bipyridin, pyrazine, pyrimidine, pyridazine, triazine, thiazole, oxazole, pyrrole, imidazole, pyrazole, triazole, oxadiazole, thiadiazole, quinoline, benzoxazole, benzimidazole, 1,4-Diazabicyclo[2.2.2]octane (DABCO), 1,2-bis(4-pyridyl)acetylene (dpa), and tautomers thereof.

4. The MOF composition of claim 1 , wherein the ligand is pyridine, 4,4′-Bipyridin, pyrimidine, pyridazine, triazine, thiazole, oxazole, pyrrole, imidazole, pyrazole, triazole, oxadiazole, thiadiazole, quinoline, benzoxazole, benzimidazole, 1,4-Diazabicyclo[2.2.2]octane (DABCO), or tautomers thereof.

5. The MOF composition of claim 1 , wherein the ligand is dipryidilacetylene.

6. The MOF composition of claim 1 , wherein the ligand is pyrazine.

7. The MOF composition of claim 1 , wherein the MOF includes square grids pillared by (SiF 6 ) 2− anions.

8. The MOF composition of claim 7 , wherein the square grids include the metal and the ligand.

9. The MOF composition of claim 7 , wherein the square grids include pyrazine/M(II), wherein M(II) is Co, Mn, Mo, Cr, Fe, Ca, Ba, Cs, Pb, Pt, Pd, Ru, Rh, or Cd.

10. An anesthetic system comprising: one or more regeneratable cartridges for sorbing and/or desorbing CO 2 from a fluid, wherein the one or more regeneratable cartridges includes the MOF composition of claim 1 .

11. The anesthetic system of claim 10 , wherein the CO 2 in the fluid has a partial pressure of 125 mbar or less.

12. The anesthetic system of claim 10 , wherein the fluid includes exhaled air.

13. An alkaline fuel cell comprising: a catalyst layer for sorbing and/or desorbing CO 2 from a fluid, wherein the catalyst layer includes the MOF composition of claim 1 .

14. The alkaline fuel cell of claim 13 , wherein the CO 2 in the fluid has a partial pressure of 125 mbar or less.

15. The alkaline fuel cell of claim 13 , wherein the fluid is air.

16. A metal-organic framework (MOF) composition, the MOF composition comprising:
a SIFSIX-n-M MOF including a metal (M) and a ligand, wherein n is at least 2, M is Cu, and wherein the ligand is pyridine, pyrimidine, pyridazine, triazine, thiazole, oxazole, pyrrole, imidazole, pyrazole, triazole, oxadiazole, thiadiazole, quinoline, benzoxazole, benzimidazole, 1,4-Diazabicyclo [2.2.2]octane (DABCO), or tautomers thereof.

17. A metal-organic framework (MOF) composition, the MOF composition comprising:
a SIFSIX-n-M MOF including a metal (M) and a ligand, wherein n is at least 2, M is Zn, and wherein the ligand is pyridine, 4,4′-Bipyridin, pyrimidine, pyridazine, triazine, thiazole, oxazole, pyrrole, imidazole, pyrazole, triazole, oxadiazole, thiadiazole, quinoline, benzoxazole, benzimidazole, 1,4-Diazabicyclo [2.2.2]octane (DABCO), or tautomers thereof.

Assignees

• Univ King Abdullah Sci & Tech

Inventors

• Eddaoudi Mohamed
• Belmabkhout Youssef
• Shekhah Osama

Classifications

• B01D53/02 Primary

  by adsorption, e.g. preparative gas chromatography {(solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01)} · CPC title

• A61M16/22

  Carbon dioxide-absorbing devices {; Other means for removing carbon dioxide}(cartridges with absorbing substances for respiratory apparatus A62B19/00) · CPC title

• B01J20/226 Primary

  Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF] (preparation of metal complexes containing carboxylic acid moieties C07C51/418; MOF's per se C07F) · CPC title

• B01J20/28057

  Surface area, e.g. B.E.T specific surface area · CPC title

• B01J20/28083

  being in the range 2-50 nm, i.e. mesopores · CPC title