Integration of hydrogen liquefaction with gas processing units

Patent metadata

Field	Value
Publication number	US-11815309-B2
Application number	US-201816183236-A
Country	US
Kind code	B2
Filing date	Nov 7, 2018
Priority date	Nov 7, 2018
Publication date	Nov 14, 2023
Grant date	Nov 14, 2023

Abstract

A method including, compressing a first hydrogen stream, and expanding a portion to produce a hydrogen refrigeration stream, cooling a second hydrogen stream thereby producing a cool hydrogen stream, wherein at least a portion of the refrigeration is provided by a nitrogen refrigeration stream, further cooling at least a portion of the cool hydrogen stream thereby producing a cold hydrogen stream, and a warm hydrogen refrigeration stream wherein at least a portion of the refrigeration is provided by the hydrogen refrigeration stream, compressing the warm hydrogen refrigeration stream, mixing the balance of the compressed first hydrogen stream with a high-pressure gaseous nitrogen stream to form an ammonia synthesis gas stream, and wherein the first hydrogen stream and the warm hydrogen refrigeration stream are compressed in the same compressor.

First claim

What is claimed is:

1. A method comprising:
compressing a first hydrogen stream, and expanding a first portion to produce a hydrogen refrigeration stream, with the remainder forming a second portion
cooling a second hydrogen stream against nitrogen refrigeration cycle thereby producing a cool hydrogen stream, wherein at least a portion of the nitrogen refrigeration cycle is provided by a nitrogen refrigeration stream,
further cooling at least a portion of the cool hydrogen stream against a secondary refrigeration cycle thereby producing a cold hydrogen stream, and a warm hydrogen refrigeration stream, wherein at least a portion of the secondary refrigeration cycle is provided by the hydrogen refrigeration stream,
compressing the warm hydrogen refrigeration stream,
mixing the second portion with a high-pressure gaseous nitrogen stream to form an ammonia synthesis gas stream, and
wherein the first hydrogen stream and the warm hydrogen refrigeration stream are compressed in the same compressor.

2. The method of claim 1 , wherein the first portion is removed downstream of the compressor.

3. The method of claim 1 , wherein the portion of the first hydrogen stream is withdrawn between compression stages of the compressor.

4. The method of claim 1 , wherein the second portion is removed upstream of the compressor.

5. The method of claim 1 , wherein the second hydrogen stream is withdrawn between compression stages of the compressor.

6. The method of claim 1 , wherein the second portion is removed downstream of the compressor.

7. The method of claim 1 , wherein the first portion and the second portion are derived from a syngas stream produced in a hydrogen generator.

8. The method of claim 7 , wherein the hydrogen generator comprises a partial oxidation reactor or an autothermal reformer.

9. The method of claim 8 , wherein the first hydrogen stream and the second hydrogen stream are separated from the syngas stream by at least one pressure swing adsorption unit.

10. The method of claim 7 , wherein the nitrogen refrigeration stream is produced by the vaporization of a liquid nitrogen stream within an Air Separation Unit.

11. The method of claim 10 , wherein the high-pressure gaseous nitrogen stream is produced by pumping and vaporizing a liquid nitrogen stream within the air separation unit, and wherein no nitrogen compressor is required.

12. The method of claim 11 , wherein an oxygen-containing stream is provided to the hydrogen generator,
wherein both the nitrogen refrigeration stream and the high-pressure nitrogen stream are produced within the same air separation unit that produced the oxygen-containing stream, and wherein the mass ratio of liquid hydrogen produced to ammonia produced is less than 0.1.

13. The method of claim 7 , wherein the nitrogen refrigeration stream is a gaseous nitrogen stream produced within an air separation unit.

14. The method of claim 13 , wherein the nitrogen refrigeration stream is compressed downstream of the air separation unit.

15. The method of claim 13 , wherein the high-pressure gaseous nitrogen stream is produced by pumping and vaporizing a liquid nitrogen stream within the air separation unit, and wherein no nitrogen compressor is required.

16. The method of claim 15 , wherein an oxygen-containing stream is provided to the hydrogen generator,
wherein both the nitrogen refrigeration stream and the high-pressure nitrogen stream are produced within the same air separation unit that produced the oxygen-containing stream, and wherein the mass ratio of liquid hydrogen produced to ammonia produced is less than 0.1, preferably less than 0.05.

17. The method of claim 7 , wherein the nitrogen refrigeration stream is a liquid nitrogen stream.

18. The method of claim 17 , wherein the high-pressure gaseous nitrogen stream is produced by pumping and vaporizing a liquid nitrogen stream within an air separation unit, and wherein no nitrogen compressor is required.

19. The method of claim 18 , wherein an oxygen-containing stream is provided to the hydrogen generator,
wherein both the nitrogen refrigeration stream and the high-pressure nitrogen stream are produced within the same air separation unit that produced the oxygen-containing stream, and wherein the mass ratio of liquid hydrogen produced to ammonia produced is less than 0.2, preferably less than 0.15.

20. The method of claim 1 , wherein the ammonia synthesis gas stream is further compressed and cooled prior to being introduced into the ammonia production unit.

Assignees

• Air Liquide

Inventors

• Turney Mike
• Guillard Alain
• Roesch Alexander

Classifications

• F25J3/0655 Primary

  separation of hydrogen (production of hydrogen containing gas in general C01B3/00, e.g. separation of hydrogen or hydrogen containing gases form gaseous mixtures at low temperatures C01B3/506) · CPC title

• F25J1/001 Primary

  Hydrogen · CPC title

• F25J3/061

  Natural gas or substitute natural gas · CPC title

• F25J2210/18

  H2/CO mixtures, i.e. synthesis gas; Water gas, shifted synthesis gas or purge gas from HYCO synthesis · CPC title

• F25J2215/10

  Hydrogen · CPC title