Endothermic salt regeneration for cooling and air-conditioning

Patent metadata

Field	Value
Publication number	US-11815307-B2
Application number	US-201916968951-A
Country	US
Kind code	B2
Filing date	Feb 18, 2019
Priority date	Feb 16, 2018
Publication date	Nov 14, 2023
Grant date	Nov 14, 2023

Abstract

The invention is directed to a method and a system for regenerating an endothermic salt composition from an aqueous solution thereof, said method comprising a) contacting a switchable-polarity compound with the aqueous solution of the endothermic salt composition to obtain a raffinate phase and an extract phase, wherein the raffinate phase comprises said endothermic salt composition in a higher concentration than said aqueous solution and said extract phase comprises the switchable-polarity compound and water; and b) separating the raffinate phase and the extract phase into a separated raffinate and a separated extract. The endothermic salt can be used in systems for cooling food, milk, medicines and/or air.

First claim

The invention claimed is:

1. A method of operating an endothermic cooling system, said method comprising:
contacting an endothermic salt composition with water to obtain an aqueous solution of the endothermic salt composition and to generate cooling; and
regenerating the endothermic salt composition from the aqueous solution thereof comprising the steps of
contacting a switchable-polarity compound with the aqueous solution of the endothermic salt composition to obtain a raffinate phase and an extract phase, wherein the raffinate phase comprises said endothermic salt composition in a higher concentration than said aqueous solution and said extract phase comprises the switchable-polarity compound and water; and
separating the raffinate phase and the extract phase into a separated raffinate and a separated extract.

2. The method in accordance with claim 1 , further comprising recycling the endothermic salt composition in the separated raffinate into the phase of contacting said endothermic salt composition with water.

3. The method in accordance with claim 1 , further comprising recycling of the switchable-polarity compound in the separated extract phase into the phase of contacting the switchable-polarity compound with the aqueous solution of the endothermic salt composition.

4. The method in accordance with claim 1 , further comprising recycling of the water in the separated extract phase into the phase of contacting the endothermic salt composition with water.

5. The method in accordance with claim 1 , wherein the endothermic salt composition comprises an endothermic salt selected from the group consisting of sodium nitrite, ammonium nitrate, potassium nitrite, ammonium chloride, potassium chloride, ammonium phosphate and combinations thereof.

6. The method in accordance with claim 1 , wherein the switchable-polarity compound comprises a switchable polymeric compound.

7. The method in accordance with claim 1 , which method is carried out in a closed system.

8. The method in accordance with claim 1 , wherein the endothermic salt composition comprises at least two endothermic salts and wherein phase e) of contacting the endothermic salt composition with water comprises at least two sub-phases.

9. The method in accordance with claim 1 , wherein the switchable-polarity compound comprises a switchable polymeric compound selected from the group consisting of polyethylene glycol (PEG), polypropylene glycol (PPG), block-copolymer of PEG and PPG, in particular poloxamers, poly(tetramethyleenether)glycol, poly(vinyl alcohol), polyvinyl pyrrolidone (PVP), polyethylenimine, poly(diallydimethyl ammonium chloride), octylphenol ethoxylate, dialkyl sulfosuccinate such as dioctyl sulfosuccinate, sorbitan monostearate, alkoxylated fatty alcohol such as C 16-18 fatty alcohol-(EO) 10 , C 12 fatty alcohol-(EO) 5 (PO), C 12 fatty alcohol-(EO) 4 (PO) 5 , C 12 fatty alcohol-(EO) 2 (PO) 4 , fatty alcohol alkoxylate mixture, oleyl cetyl alcohol polyglycol ether, C 12 fatty alcohol-(EO) 10 C 4 H 9 , 2-hexyldecanol-(EO) 2 , C 12 fatty alcohol-(EO) 2 , poly(acrylic acid) partial sodium salt-graft-poly((EO)), O,O′-Bis(2-aminopropyl) polypropylene glycol-block-polyethylene glycol-block-polypropylene glycol, hyperbranched bis-dimethylolpropionic acid (MPA), polyester hydroxyl amine or functionalized polyester hydroxyl amine, and combinations thereof.

10. The method in accordance with claim 1 , wherein the switchable-polarity compound comprises poloxamers.

11. The method in accordance with claim 1 , regenerating the endothermic salt composition from the aqueous solution carried out in a closed system under atmospheric pressure.

12. The method in accordance with claim 1 , wherein said method further comprises:
heating the separated extract to obtain an aqueous phase and a switchable-polarity compound phase, and
separating said aqueous phase and switchable-polarity compound phase into a separated aqueous phase and a separated switchable-polarity compound phase.

13. The method in accordance with the claim 12 , wherein the heating is carried out with heat from a solar thermal collector.

14. The method in accordance with claim 12 , comprising a heat exchange between the separated extract and the aqueous liquid, and/or a heat exchange between the separated extract and the switchable-polarity compound phase.

Assignees

• TNO

Inventors

• Goetheer Earl Lawrence Vincent
• Bhardwaj Rajat
• Roelands Cornelis Petrus Marcus
• De Jong Adriaan Jan

Classifications

• F25D5/00 Primary

  Devices using endothermic chemical reactions, e.g. using frigorific mixtures · CPC title

• F28D20/003 Primary

  using thermochemical reactions · CPC title

• C09K5/066

  Cooling mixtures; De-icing compositions · CPC title

• Y02E60/14

  Thermal energy storage · CPC title