Thermoplastic resin composition and molded product using same

Patent metadata

Field	Value
Publication number	US-11814513-B2
Application number	US-201917289364-A
Country	US
Kind code	B2
Filing date	Oct 28, 2019
Priority date	Oct 31, 2018
Publication date	Nov 14, 2023
Grant date	Nov 14, 2023

Abstract

Provided are a thermoplastic resin composition and a molded product using same, the thermoplastic resin composition comprising: (A) 30 to 50 wt % of an acrylate-based graft copolymer; (B) 20 to 50 wt % of a poly(methyl methacrylate) resin; (C) 0 to 40 wt % of a methyl methacrylate-styrene-acrylonitrile copolymer; and (D) 5 to 15 wt % of a styrene-methyl methacrylate-maleic anhydride copolymer having a maleic anhydride-derived component content of 20 to 25 wt %.

First claim

The invention claimed is:

1. A thermoplastic resin composition, comprising:
(A) 30 to 50 wt % of an acrylate-based graft copolymer;
(B) 20 to 50 wt % of a poly(methyl methacrylate) resin;
(C) 0 to 40 wt % of a methyl methacrylate-styrene-acrylonitrile copolymer; and
(D) 5 to 15 wt % of a styrene-methyl methacrylate-maleic anhydride copolymer including 20 to 25 wt % of a maleic anhydride-derived component.

2. The thermoplastic resin composition of claim 1 , wherein
the (A) acrylate-based graft copolymer comprises a core including an acrylate-based rubbery polymer, and
a shell formed by grafting a monomer mixture including an aromatic vinyl compound and a vinyl cyanide compound to the core.

3. The thermoplastic resin composition of claim 2 , wherein the acrylate-based rubbery polymer is a crosslinked polymer of monomers including ethyl acrylate, butyl acrylate, 2-ethylhexyl acrylate, hexyl acrylate, or a combination thereof.

4. The thermoplastic resin composition of claim 2 , wherein the (A) acrylate-based graft copolymer includes 20 to 60 wt % of the acrylate-based rubbery polymer based on 100 wt % of the (A) acrylate-based graft copolymer.

5. The thermoplastic resin composition of claim 2 , wherein the shell is a copolymer of a monomer mixture including an aromatic vinyl compound and a vinyl cyanide compound in a weight ratio of 5:5 to 8:2.

6. The thermoplastic resin composition of claim 2 , wherein the acrylate-based rubbery polymer has an average particle diameter of 200 to 400 nm.

7. The thermoplastic resin composition of claim 1 , wherein the (A) acrylate-based graft copolymer is an acrylonitrile-styrene-acrylate graft copolymer.

8. The thermoplastic resin composition of claim 1 , wherein the (B) poly(methyl methacrylate) resin has a glass transition temperature of 100 to 150° C.

9. The thermoplastic resin composition of claim 1 , comprising the (C) methyl methacrylate-styrene-acrylonitrile copolymer in an amount of 10 to 35 wt % based on 100 wt % of a sum of the components (A) to (D).

10. The thermoplastic resin composition of claim 1 , wherein the (C) methyl methacrylate-styrene-acrylonitrile copolymer is a copolymer of a monomer mixture including 60 to 80 wt % of methyl methacrylate, 10 to 30 wt % of styrene, and greater than 0 wt % and less than or equal to 10 wt % of acrylonitrile.

11. The thermoplastic resin composition of claim 1 , wherein the (C) methyl methacrylate-styrene-acrylonitrile copolymer has a weight average molecular weight of 50,000 to 200,000 g/mol.

12. The thermoplastic resin composition of claim 1 , wherein the (D) styrene-methyl methacrylate-maleic anhydride copolymer is a copolymer of a monomer mixture including 50 to 75 wt % of styrene, greater than 0 wt % and less than or equal to 25 wt % of methyl methacrylate, and 20 to 25 wt % of maleic anhydride.

13. The thermoplastic resin composition of claim 1 , wherein the (D) styrene-methyl methacrylate-maleic anhydride copolymer has a glass transition temperature of 120 to 180° C.

14. The thermoplastic resin composition of claim 1 , which further comprises at least one additive selected from flame retardants, nucleating agents, coupling agents, fillers, plasticizers, impact modifiers, lubricants, antibacterial agents, release agents, heat stabilizers, antioxidants, inorganic additives, ultraviolet stabilizers, antistatic agents, pigments, and dyes.

15. A molded product using the thermoplastic resin composition of claim 1 .

Assignees

• Lotte Chemical Corp

Inventors

• Shin Hyeongseob
• Kim In-Chol
• Kwon Keehae

Classifications

• C08L51/04 Primary

  grafted on to rubbers · CPC title

• C08F265/06

  Polymerisation of acrylate or methacrylate esters on to polymers thereof · CPC title

• C08L25/12

  with unsaturated nitriles · CPC title

• C08L33/12

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C08L35/06

  Copolymers with vinyl aromatic monomers · CPC title