Gel extruded articles made from high density polyethylene with narrow molecular weight distribution

Patent metadata

Field	Value
Publication number	US-11814508-B2
Application number	US-202117410138-A
Country	US
Kind code	B2
Filing date	Aug 24, 2021
Priority date	Aug 24, 2020
Publication date	Nov 14, 2023
Grant date	Nov 14, 2023

Abstract

A polymer composition for producing gel extruded articles is described. The polymer composition contains polyethylene particles combined with a plasticizer. The polyethylene polymer has a narrow molecular weight distribution. Polymer articles made in accordance with the present disclosure have enhanced strength properties. In one embodiment, the polymer composition is used to form a porous membrane for use as a separator in electronic devices.

First claim

What is claimed:

1. A polymer composition for producing gel extruded articles comprising:
a plasticizer;
polymer particles comprising a high density polyethylene polymer, the high density polyethylene polymer having a narrow molecular weight distribution such that the high density polyethylene polymer has a polydispersity index (PDI) of less than about 8, the high density polyethylene polymer having an intercrossing point (ICP) of greater than about 150 kPa.

2. A polymer composition as defined in claim 1 , wherein the high density polyethylene polymer has a polydispersity index (PDI) of less than about 7.5.

3. A polymer composition as defined in claim 1 , wherein the high density polyethylene polymer has an intercrossing point (ICP) of greater than about 168 kPa and has a polydispersity index (PDI) of less than about 6.5.

4. A polymer composition as defined in claim 1 , wherein the high density polyethylene particles have a median particle size by volume of from about 70 microns to about 210 microns.

5. A polymer composition as defined in claim 1 , wherein the high density polyethylene particles are present in the composition in an amount up to about 50% by weight.

6. A polymer composition as defined in claim 1 , wherein the plasticizer comprises mineral oil, a paraffinic oil, a hydrocarbon, an alcohol, an ether, an ester, or mixtures thereof.

7. A polymer composition as defined in claim 1 , wherein the high density polyethylene has a molecular weight of greater than about 400,000 g/mol and less than about 4,000,000 g/mol.

8. A polymer composition as defined in claim 7 , wherein the composition only contains a single high density polyethylene polymer.

9. A polymer composition as defined in claim 1 , wherein the polymer composition is polypropylene-free.

10. A polymer composition as defined in claim 1 , wherein the high density polyethylene polymer has been Ziegler-Natta catalyzed.

11. A molded article formed from the polymer composition as defined in claim 1 , wherein the molded article contains the plasticizer in an amount of less than about 2% by weight, such as in an amount less than about 1% by weight.

12. A molded article as defined in claim 11 , wherein the molded article comprises a film or a fiber.

13. A process for producing polymer articles comprising:
forming the polymer composition as defined in claim 1 into a gel-like composition;
extruding the gel-like composition through a die to form a polymer article, the polymer article comprising a film.

14. A process as defined in claim 13 , further comprising the step of removing at least part of the plasticizer from the polymer article.

15. A porous membrane comprising:
a high density polyethylene having a polydispersity index (PDI) of less than about 8, the high density polyethylene polymer having an intercrossing point (ICP) of greater than about 150 kPa, the high density polyethylene polymer having been Ziegler-Natta catalyzed, the high density polyethylene having a molecular weight of greater than about 400,000 g/mol and less than about 900,000 g/mol, the porous membrane having a tensile strength in at least one direction of greater than about 90 MPa and having a puncture strength of greater than about 500 mN/μm.

16. A porous membrane as defined in claim 15 , wherein the membrane has a thickness of from about 7 microns to about 11 microns.

17. A porous membrane as defined in claim 15 , wherein the membrane has a Gurley permeability of greater than about 105 sec/100 ml.

18. A porous membrane as defined in claim 15 , wherein the porous membrane has a puncture strength of greater than about 700 mN/μm.

19. A porous membrane as defined in claim 15 , wherein the porous membrane has been biaxially stretched.

Assignees

• Celanese Int Corp

Inventors

• Ohm Christian
• Yadav Arvind

Classifications

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08L23/06 Primary

  Polyethylene · CPC title

• B29C48/022

  characterised by the choice of material · CPC title

• B29C48/08 Primary

  flexible, e.g. films · CPC title

• B29K2023/065

  HDPE, i.e. high density polyethylene · CPC title