Apparatus and method for mixing recycling material into a polyester melt

Patent metadata

Field	Value
Publication number	US-11814486-B2
Application number	US-201916969813-A
Country	US
Kind code	B2
Filing date	Feb 19, 2019
Priority date	Feb 20, 2018
Publication date	Nov 14, 2023
Grant date	Nov 14, 2023

Abstract

Apparatuses and processes may be utilized for mixing used polyester into a polyester melt. In some processes an intermediate product stream is branched off from an intermediate stage in a virgin polyester production process. The intermediate product stream is then mixed with recycled polyester flakes in a dynamic mixer, where not more than 60% of a melting energy required to melt all the recycled polyester flakes is generated and/or supplied in the dynamic mixer. The mixture produced in this way is fed into a subsequent stage downstream of the intermediate stage and converted up to the desired degree of polycondensation. In this way, it is possible to physically reutilize used polyester or polyester waste.

First claim

What is claimed is:

1. A process for producing polyester using recycled polyester flakes, the process comprising:
branching off an intermediate product stream from an intermediate stage in a virgin polyester production process;
mixing the intermediate product stream with recycled polyester flakes in a dynamic mixer to form a mixture, wherein not more than 60% of a melting energy required to melt the recycled polyester flakes is generated and/or supplied;
feeding the mixture into a downstream stage downstream of the intermediate stage and/or recycling the mixture into a reaction stage from which the intermediate product stream was taken; and
converting the mixture up to a desired level of polycondensation.

2. The process of claim 1 wherein upon entry into the dynamic mixer the recycled polyester flakes have an average temperature of 0 to 200° C.

3. The process of claim 1 comprising supplying the intermediate product stream with at least 40% of the melting energy prior to the mixing, wherein the intermediate product stream transfers less than 40% of the melting energy to the recycled polyester flakes during a dwell time in the dynamic mixer.

4. The process of claim 1 comprising supplying the mixture with at least 40% of the melting energy after the mixing.

5. The process of claim 1 wherein a dwell time of the intermediate product stream and the recycled polyester flakes in the dynamic mixer is not more than 60 seconds.

6. The process of claim 1 wherein the mixing is performed at an absolute pressure of 3 to 100 mbar.

7. The process of claim 1 comprising filtering the mixture prior to attainment of the desired level of polycondensation.

8. The process of claim 1 wherein at least one of:
the desired level of polycondensation is 100 to 200, or
the mixture converted up to the desired level of polycondensation has an intrinsic viscosity measured according to ASTM D-4603-03 of 0.6 to 0.9 dL/g.

9. The process of claim 1 wherein 10% to 100% of an overall stream is branched off as the intermediate product stream at the intermediate stage.

10. The process of claim 1 wherein the intermediate product stream contains a diol.

11. The process of claim 1 wherein the mixture contains 5% to 60% by weight recycled polyester flakes.

12. The process of claim 1 comprising mixing the intermediate product stream and the recycled polyester flakes in the dynamic mixer with an additive selected from a group consisting of catalysts, stabilizers, dyes, flatting agents, optical brighteners, or mixtures thereof, wherein the additive is used in a proportion of not more than 5% by weight based on a resulting mixture.

13. An apparatus for producing polyester using recycled polyester flakes, the apparatus comprising:
an apparatus for producing virgin polyester having multiple successive reaction vessels; and
a dynamic mixer with a first inlet, a second inlet, and an outlet, wherein the first inlet is connected to a first reaction vessel of the multiple successive reaction vessels, wherein the first inlet is connected to an intermediate stage of the apparatus for producing virgin polyester, wherein the second inlet is connected to an apparatus for dosage of bulk material, wherein the outlet is connected downstream to a second reaction vessel of the multiple successive reaction vessels.

14. The apparatus of claim 13 comprising an apparatus for comminution of recycled polyester that is connected upstream of the apparatus for dosage of bulk material.

15. The apparatus of claim 13 comprising:
a first heat exchanger disposed between the apparatus for comminution of recycled polyester and the apparatus for dosage of bulk material; and
a second heat exchanger disposed between the first reaction vessel and the dynamic mixer.

16. The apparatus of claim 13 comprising an apparatus for generating a reduced pressure that is connected to the dynamic mixer.

17. The apparatus of claim 13 , wherein the outlet is connected downstream of the intermediate stage to the second reaction vessel of the multiple successive reaction vessels.

18. The apparatus of claim 13 , wherein the first reaction vessel is an intermediate stage of the apparatus for producing virgin polyester.

Assignees

• Uhde Inventa Fischer Gmbh
• Thyssenkrupp Ag

Inventors

• Pawelski Alexander
• Hittorff Martin
• Koch Heinrich
• Hess Christopher

Classifications

• C08J11/04 Primary

  of polymers · CPC title

• B01F35/80

  Forming a predetermined ratio of the substances to be mixed (controlling ratio of two or more flows of fluid or fluent material G05D11/02) · CPC title

• B01F35/92

  for heating the outside of the receptacle, e.g. heated jackets or burners · CPC title

• B01J19/0013

  Controlling the temperature of the process · CPC title

• B01J19/06

  Solidifying liquids (making microcapsules B01J13/02) · CPC title