Method for producing polyamide with controlled activator addition, and polyamide produced thereby

Patent metadata

Field	Value
Publication number	US-11814480-B2
Application number	US-201816763793-A
Country	US
Kind code	B2
Filing date	Oct 29, 2018
Priority date	Nov 14, 2017
Publication date	Nov 14, 2023
Grant date	Nov 14, 2023

Abstract

The present invention provides a method for producing a polyamide with controlled activator addition, and a polyamide produced thereby, the method allowing a polymerization conversion rate and a polydispersity index (PDI) to be enhanced by controlling the addition of an activator so as to prevent a gelation phenomenon that occurs during anionic polymerization.

First claim

The invention claimed is:

1. A method for producing a polyamide with controlled activator addition through an anionic polymerization reaction, the method comprising polymerizing a lactam in the presence of, based on 100 parts by weight of the entire lactam, 0.01 parts by weight to 20 parts by weight of an alkali metal catalyst as an initiator, 0.3 parts by weight to 10 parts by weight of a molecular weight controller, and 0.01 parts by weight to 1.0 part by weight of an activator,
wherein the activator is injected by adjusting an addition amount at an interval of at least twice,
wherein an addition interval of the activator is within 1 minute to 10 minutes,
wherein the method does not use a separate solvent, and
wherein the activator is carbon dioxide (CO 2 ).

2. The method of claim 1 , wherein an addition rate of the activator is within a range of 0.001 L/min to 10 L/min with respect to a volume (1 m 3 ) of a reactor.

3. The method of claim 1 , wherein the activator is injected in a spraying method using a sparger.

4. The method of claim 1 , wherein the activator is injected into a polymer.

5. The method of claim 1 , wherein the alkali metal catalyst comprises one or more selected from the group consisting of metal hydride, metal hydroxide, and metal alkoxide.

6. The method of claim 1 , wherein the polymerization reaction is performed within a range of 0.5 minutes to 120 minutes.

7. The method of claim 1 , wherein the lactam in the polymerization reaction has a conversion rate of 95% or more.

8. The method of claim 1 , wherein the polymerization reaction is performed within a range of 180° C. to 300° C.

9. A polyamide produced by the method of claim 1 .

10. The polyamide of claim 9 , wherein the polyamide has a polydispersity index (PDI) of 3.0 or less.

11. The polyamide of claim 9 , wherein a weight average molecular weight (Mw) of the polyamide is in a range of 20,000 to 100,000.

12. The polyamide of claim 9 , wherein the polyamide has a linear, branched, hyperbranched, or dendritic structure.

13. A parts material selected from the group consisting of a vehicle material, an electronic device material, an industrial pipe material, a construction engineering material, a 3D printer material, a textile material, a cladding material, a machine tool material, a medical material, an aviation material, a photovoltaic material, a battery material, a sports material, a household appliance material, a household material, and a cosmetic material, which each include the polyamide of claim 9 .

Assignees

• Hanwha Chemical Corp

Inventors

• Lee Hye Yeon
• Kim Do Kyoung
• Do Seung Hoe
• Lee Jin Seo
• Kwon Kyung Ho
• Kim Dae Hak
• Yim Kyoung Won

Classifications

• C08G69/18 Primary

  Anionic polymerisation · CPC title

• C08G69/14

  Lactams · CPC title

• C08J2377/02

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08J2377/10 takes precedence) · CPC title

• C08L77/02

  Polyamides derived from omega-amino carboxylic acids or from lactams thereof (C08L77/10 takes precedence) · CPC title

• C08L77/00

  Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain (of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08); Compositions of derivatives of such polymers · CPC title