Method for producing double metal cyanide catalysts

Patent metadata

Field	Value
Publication number	US-11813595-B2
Application number	US-201917264870-A
Country	US
Kind code	B2
Filing date	Aug 6, 2019
Priority date	Aug 8, 2018
Publication date	Nov 14, 2023
Grant date	Nov 14, 2023

Abstract

The present invention relates to a process for preparing a double metal cyanide catalyst (DMC) comprising the reaction of an aqueous solution of a cyanide-free metal salt, an aqueous solution of a metal cyanide salt, an organic complex ligand and a complex-forming component, to form a dispersion, wherein the reaction is effected using a mixing nozzle and wherein the process temperature of the dispersion during the reaction is between 26° C. and 49° C. The subject matter of the invention further encompasses double metal cyanide catalysts (DMC) obtained in accordance with the process according to the invention and also the use of the DMC catalysts for the preparation of polyoxyalkylene polyols.

First claim

The invention claimed is:

1. A process for preparing a double metal cyanide catalyst (DMC) comprising
i) reacting an aqueous solution of a cyanide-free metal salt, an aqueous solution of a metal cyanide salt, an organic complex ligand and a complex-forming component, in a first step to form a dispersion;
wherein the reaction is effected using a mixing nozzle;
wherein the dispersion during the reaction is at a process temperature of between 26° C. and 49° C.; and
wherein the complex-forming component comprises a polyether.

2. The process as claimed in claim 1 , wherein said mixing nozzle comprises a jet disperser.

3. The process as claimed in claim 2 , wherein said jet disperser has a pressure drop of 0.1 to 100 bar.

4. The process as claimed in claim 1 , wherein said polyether has a number-average molecular weight of ≥500 g/mol, with the number-average molecular weight being calculated from the OH number.

5. The process as claimed in claim 4 , wherein said polyether comprises a polyether polyol.

6. The process as claimed in claim 5 , wherein said polyether polyol comprises a poly(oxypropylene) polyol having a number-average molecular weight of ≥500 g/mol, with the number-average molecular weight being calculated from the OH number.

7. The process as claimed in claim 6 , wherein said poly(oxypropylene) polyol comprises a poly(oxypropylene) diol and/or a poly(oxypropylene) triol having a number-average molecular weight of 700 g/mol to 4000 g/mol, with number-average molecular weight being calculated from the OH number.

8. The process as claimed in claim 1 , wherein the process temperature in step i) ranges from 28° C. to 47° C.

9. The process as claimed in claim 1 , additionally comprising
(ii) separating the solid off from the dispersion obtained from (i) in a second step.

10. The process as claimed in claim 9 , additionally comprising
(iii) washing the separated solid from step (ii) with an aqueous solution of an organic complex ligand by means of a filtercake washing operation.

11. The process as claimed in claim 10 , additionally comprising
(iv) drying the solid obtained in (iii) in a fourth step.

12. The process as claimed in claim 10 , wherein (ii) and/or (iii) are performed in a filter press.

13. The process as claimed in 11 , wherein steps (ii), (iii) and/or (iv) are performed in a heatable filter press.

Assignees

• Covestro Intellectual Property Gmbh & Co Kg

Inventors

• Hofmann Joerg
• Gleixner Maria
• Asma Thomas

Classifications

• B01J27/26 Primary

  Cyanides · CPC title

• B01J37/0009

  Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst · CPC title

• B01J2208/00017

  Controlling the temperature · CPC title

• B01J2208/00539

  Pressure · CPC title

• C08G65/2663 Primary

  Metal cyanide catalysts, i.e. DMC's · CPC title