Method of making polymer matrix composites

Patent metadata

Field	Value
Publication number	US-11807732-B2
Application number	US-201816760468-A
Country	US
Kind code	B2
Filing date	Nov 15, 2018
Priority date	Nov 16, 2017
Publication date	Nov 7, 2023
Grant date	Nov 7, 2023

Abstract

Method of making a polymer matrix composite comprising a porous polymeric network structure; and a plurality of particles distributed within the polymeric network structure, the method comprising: combining a thermoplastic polymer, a solvent that the thermoplastic polymer is soluble in, and a plurality of particles to provide a slurry; forming the slurry in to an article; heating the article in an environment to retain at least 90 percent by weight of the solvent, based on the weight of the solvent in the slurry, and inducing phase separation of the thermoplastic polymer from the solvent to provide the polymer matrix composite.

First claim

What is claimed is:

1. A method of making a polymer matrix composite comprising a porous polymeric network structure and a plurality of particles distributed within the porous polymeric network structure, the method comprising:
combining a thermoplastic polymer, a solvent, and a plurality of thermally conductive particles to provide a slurry;
forming the slurry into a formed article;
heating the formed article in an environment to retain at least 90 percent by weight of the solvent in the formed article, based on the weight of the solvent in the formed article, and solubilize at least 50 weight percent of the thermoplastic polymer, based on the total weight of the thermoplastic polymer;
inducing phase separation of the thermoplastic polymer from the solvent to provide the polymer matrix composite, and
further comprising compressing the polymer matrix composite.

2. The method of claim 1 , further comprising removing at least a portion of the solvent from the formed article after inducing phase separation of the thermoplastic polymer from the solvent.

3. The method of claim 2 , wherein at least 90 percent by weight of the solvent, based on the weight of the solvent in the formed article, is removed, wherein the formed article before, removing at least 90 percent by weight of the solvent, based on the weight of the solvent in the formed article, of the solvent has a first volume, wherein the formed article after removing at least 90 percent by weight of the solvent, based on the weight of the solvent in the formed article, has a second volume, and wherein the difference between the first and second volume is less than 10 percent.

4. The method of claim 3 , wherein the formed article after the solvent removal has a porosity at least 5 percent.

5. The method of claim 1 , wherein no solvent is removed from the formed article.

6. The method of claim 1 , wherein the inducing phase separation includes thermally induced phase separation.

7. The method of claim 1 , wherein the thermoplastic polymer in the slurry has a melting point, wherein the solvent has a boiling point, and wherein combining is conducted below the melting point of the thermoplastic polymer in the slurry, and below the boiling point of the solvent.

8. The method of claim 1 , wherein the thermoplastic polymer in the slurry has a melting point, and wherein the inducing phase separation is conducted at less than the melting point of the thermoplastic polymer in the slurry.

9. The method of claim 1 , further comprising applying vibratory energy to the polymer matrix composite simultaneously with applying a compressive force.

10. The method of claim 1 , wherein the polymer matrix composite has a density in a range from 0.05 to 10 g/cm 3 .

11. The method of claim 1 , wherein the polymer matrix composite has a porosity of at least 5 percent.

12. The method of claim 1 , wherein the particles are acoustically active particles.

13. The method of claim 12 , wherein the acoustically active particles comprise acoustically active metal oxide particles.

14. The method of claim 1 , wherein the particles are soft magnetic particles.

15. The method of claim 1 , wherein the porous polymeric network structure comprises at least one of polyacrylonitrile, polyurethane, polyester, polyamide, polyether, polycarbonate, polyimide, polysulfone, polyphenylene oxide, polyacrylate, polymethacrylate, polyolefin, styrene or styrene-based random and block copolymer, chlorinated polymer, fluorinated polymer, or copolymers of ethylene and chlorotrifluoroethylene.

16. The method of claim 1 , wherein the porous polymeric network structure comprises a plurality of interconnected morphologies.

17. The method of claim 1 , wherein the thermoplastic polymer has a number average molecular weight in a range from of 5×10 4 to 1×10 7 g/mol, and wherein the polymer matrix composite is in the form of a sheet having a thickness in a range from 50 to 7000 micrometers.

18. The method of claim 1 , wherein the porous polymeric network structure is produced by an induced phase separation of a miscible thermoplastic polymer-solvent solution.

19. The method of claim 1 , wherein the particles are present in a weight fraction in a range from 15 to 99, based on the total weight of the polymer matrix composite.

Assignees

• 3M Innovative Properties Company

Inventors

• Dehn Derek J
• Waller Jr Clinton P
• Bruss Jeanne M
• Acharya Bharat R
• Bartling Brandon A
• Graff Michael S
• Shanti Noah O
• Stolzenburg Fabian
• Nayar Satinder K

Classifications

• C08J9/28 Primary

  by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum · CPC title

• C08J9/0004

  Use of compounding ingredients, the chemical constitution of which is unknown, broadly defined, or irrelevant · CPC title

• C08J9/0066

  Use of inorganic compounding ingredients · CPC title

• C08K3/22

  of metals · CPC title

• C08J2201/0522

  the liquid phase being organic · CPC title