Strengthened glass articles and methods of forming the same

Patent metadata

Field	Value
Publication number	US-11807573-B2
Application number	US-202217893798-A
Country	US
Kind code	B2
Filing date	Aug 23, 2022
Priority date	May 15, 2020
Publication date	Nov 7, 2023
Grant date	Nov 7, 2023

Abstract

A glass article (and methods for forming the same) includes a glass body having first and second opposing primary surfaces and a thickness defined between the primary surfaces. The glass body includes a compressive stress region that includes: a surface stress of greater than about 900 MPa (compressive), a spike region having a first slope, and a tail region having a second slope. The spike region and the tail region can intersect at a knee region having a stress of greater than about 35 MPa (compressive), wherein the stress at the knee region is defined as the point where the asymptotic extrapolation of the spike region and the tail region intersect. The first slope of the spike region can be steeper than about −30 MPa/μm.

First claim

What is claimed is:

1. A glass article, comprising:
a glass body having first and second opposing primary surfaces and a thickness defined between the primary surfaces, and
wherein the glass body comprises a compressive stress region that comprises:
a surface stress of greater than about 900 MPa (compressive);
a spike region having a first slope; and
a tail region having a second slope,
wherein the spike region and the tail region intersect at a knee region having a stress of greater than about 35 MPa (compressive), and wherein the stress at the knee region is defined as the point where the asymptotic extrapolation of the spike region and the tail region intersect,
wherein the first slope of the spike region is steeper than about −50 MPa/μm,
wherein the glass body comprises a tension at a center of the glass body (CT) according to formula (I):
CT<( E/ 68 GPa)*75 MPa*1 mm 0.5 /( Th ) 0.5   (I),

wherein E is the Young's modulus of the glass body, measured in GPa, and Th is the thickness of the glass body, measured in millimeters, and
wherein the compressive stress region comprises a depth of compression where the stress inside the glass body is 0 of greater than about 0.16*(Th).

2. The glass article of claim 1 , wherein the second slope of the tail region from the knee region to the depth of compression is greater than about 50/(Th) MPa/μm, when Th is expressed in μm.

3. The glass article of claim 1 , wherein the surface stress is greater than or equal to 950 MPa and less than or equal to 1200 MPa.

4. The glass article of claim 1 , wherein a depth of layer of the spike region is greater than 10 μm.

5. The glass article of claim 1 , wherein the tail region extends from depth of layer (DOL k ) through the center, wherein DOL k is greater than or equal to 15 μm and less than or equal to 40 μm.

6. The glass article of claim 5 , wherein the stress at the knee region is greater than or equal to 50 MPa and less than or equal to 100 MPa.

7. The glass article of claim 1 , wherein depth of compression is greater than or equal to 0.18*(Th) and less than or equal to 0.2115*(Th).

8. The glass article of claim 1 , wherein CT is greater than or equal to 40 MPa and less than or equal to 50 MPa.

9. The glass article of claim 1 , wherein the glass body comprises a tensile energy (W el tens ) of less than about 20 J/m 2 .

10. The glass article of claim 1 , wherein the glass body comprises a normalized tensile energy per thickness (WT norm tens ) of less than about 60 MPa 2 m 0.5 .

11. The glass article of claim 1 , wherein the glass body is a planar article.

12. The glass article of claim 1 , further comprising a metal frame coupled to the glass body.

13. The glass article of claim 12 , wherein, when the glass body is impacted by an impactor having a diameter of 165 mm and a weight of 6.8 km at a 90 degree orientation and a speed of 6.67 m/s such that deformation of the metal frame caused by the impactor is negligible, the glass body does not exhibit surface failure.

14. The glass article of claim 1 , wherein the glass body comprises a curved shape.

15. The glass article of claim 1 , wherein the second slope of the tail region is steeper than 100/(Th), when Th is expressed in μm.

16. The glass article of claim 1 , wherein the second slope of the tail region is steeper than 241/(Th), when Th is expressed in μm.

Assignees

• Corning Inc

Inventors

• Jin Yuhui
• Mccaslin Joshua James
• Park Jong Se
• Schneider Vitor Marino
• Sun Wei

Classifications

• C03C21/002 Primary

  to perform ion-exchange between alkali ions (C03C21/005 takes precedence) · CPC title

• C03C3/083

  containing aluminium oxide or an iron compound · CPC title

• C03C3/097

  containing phosphorus, niobium or tantalum · CPC title

• C03C3/085

  containing an oxide of a divalent metal · CPC title