Biaxially oriented polyester film and manufacturing method thereof

Patent metadata

Field	Value
Publication number	US-11806909-B2
Application number	US-202117320247-A
Country	US
Kind code	B2
Filing date	May 14, 2021
Priority date	Dec 22, 2020
Publication date	Nov 7, 2023
Grant date	Nov 7, 2023

Abstract

A biaxially oriented polyester film having the following physical property is provided: when cooled from the molten state at a cooling rate of 20° C./min, an observed recrystallization temperature is 175° C.-200° C. The biaxially oriented polyester film is formed by a thick sheet before bidirectional stretching that is melted and extruded by an extruder and then cooled and formed on a casting roll. The thick sheet before stretching having the following physical property as analyzed by differential scanning calorimetry: a crystallization rate is less than 10%.

First claim

What is claimed is:

1. A biaxially oriented polyester film, wherein the biaxially oriented polyester film has a following physical property:
when cooled from a molten state at a cooling rate of 20° C./min, an observed recrystallization temperature (Tc(A)) is 177° C.-200° C., and the biaxially oriented polyester film is formed by a thick sheet before bidirectional stretching that is melted and extruded by an extruder and then cooled and formed on a casting roll, wherein the thick sheet before stretching has a following physical property as analyzed by differential scanning calorimetry:
a crystallization rate is less than 10%.

2. The biaxially oriented polyester film as described in claim 1 , formed of at least a polyester resin mixture, wherein the polyester resin mixture comprises:
an electrostatic pinning agent with metal ions and a polyester material, and a weight concentration of the metal ions of the electrostatic pinning agent in the polyester resin mixture is 40 ppm to 50 ppm.

3. The biaxially oriented polyester film as described in claim 2 , manufactured at least by an electrostatic pinning method, and comprising:
providing the casting roll and an electrostatic device configured corresponding to the casting roll; and
forming the molten polyester resin mixture on the casting roll, and providing an electrostatic voltage between the casting roll and the electrostatic device.

4. The biaxially oriented polyester film as described in claim 2 , wherein the metal ion is an alkali metal ion, an alkaline earth metal ion, or a combination thereof.

5. The biaxially oriented polyester film as described in claim 2 , wherein the polyester material is at least made up of a recycled polyester material.

6. The biaxially oriented polyester film as described in claim 5 , wherein a weight ratio of the recycled polyester material to the polyester resin mixture is greater than 80% and less than or equal to 100%.

7. The biaxially oriented polyester film as described in claim 2 , wherein the polyester resin mixture further comprises a slipping agent, and a weight concentration of the slipping agent in the polyester resin mixture is 500 ppm to 3000 ppm.

8. The biaxially oriented polyester film as described in claim 3 , wherein the electrostatic voltage between the casting roll and the electrostatic device is greater than or equal to 1 kilovolt.

9. The biaxially oriented polyester film as described in claim 8 , wherein the metal ion is an alkali metal ion, an alkaline earth metal ion, or a combination thereof.

10. The biaxially oriented polyester film as described in claim 8 , wherein the polyester material is at least made up of a recycled polyester material.

11. The biaxially oriented polyester film as described in claim 10 , wherein a weight ratio of the recycled polyester material to the polyester resin mixture is greater than 80% and less than or equal to 100%.

12. The biaxially oriented polyester film as described in claim 8 , wherein the polyester resin mixture further comprises a slipping agent, and a weight concentration of the slipping agent in the polyester resin mixture is 500 ppm to 3000 ppm.

13. The biaxially oriented polyester film as described in claim 8 , wherein the thick sheet is an unstretched sheet formed after cooling the molten polyester resin mixture on the casting roll and before stretching for forming the biaxially oriented polyester film.

14. The biaxially oriented polyester film as described in claim 13 , wherein a thickness of the thick sheet is greater than a thickness of the biaxially oriented polyester film.

15. The biaxially oriented polyester film as described in claim 1 , wherein the thick sheet is an unstretched sheet formed after cooling the molten polyester resin mixture on the casting roll and before stretching for forming the biaxially oriented polyester film.

16. The biaxially oriented polyester film as described in claim 15 , wherein a thickness of the thick sheet is greater than a thickness of the biaxially oriented polyester film.

Assignees

• Nan Ya Plastics Corp

Inventors

• Yang Wen-Cheng
• Wu Chen An
• Yang Chun-Cheng
• HSIAO Chia-Yen

Classifications

• B29C48/0018 Primary

  combined with shaping by orienting, stretching or shrinking, e.g. film blowing (B29C48/0017 takes precedence) · CPC title

• B29C48/022

  characterised by the choice of material · CPC title

• B29C48/9165

  Electrostatic pinning · CPC title

• B29C55/146

  firstly transversely to the direction of feed and then parallel thereto · CPC title

• B29C55/18

  by squeezing between surfaces, e.g. rollers · CPC title