Method of manufacturing core-shell particles by a microwave plasma process

Patent metadata

Field	Value
Publication number	US-11801555-B2
Application number	US-202217697379-A
Country	US
Kind code	B2
Filing date	Mar 17, 2022
Priority date	Nov 9, 2016
Publication date	Oct 31, 2023
Grant date	Oct 31, 2023

Abstract

Methods are disclosed for producing core-shell particles having a uniform size using a microwave plasma process. More particularly, methods of the present technology are used to manufacture core-shell particles having a core at least partially surrounded by a shell. The core and shell of the core-shell particles are chemically distinct. Methods of the present technology occur within a plasma chamber of a microwave plasma reactor and a microwave formed plasma is utilized to vaporize core precursor material.

First claim

What is claimed is:

1. A method of manufacturing core-shell particles by a microwave plasma process, the core-shell particles having a core at least partially surrounded by a shell, wherein core material and shell material are chemically distinct; the method comprising:
providing a microwave plasma reactor at least having a plasma chamber;
introducing a gas or vapor to the plasma chamber;
generating a plasma with a microwave energy source within the plasma chamber using the gas or vapor to create a microwave formed plasma;
injecting core precursor material into the microwave formed plasma within the plasma chamber;
vaporizing of the core precursor material within the plasma chamber by the microwave formed plasma;
forming a plurality of cores from the vaporized core precursor material;
introducing shell precursor material to the plurality of cores; and
forming a plurality of core-shell particles, each core-shell particle having one core at least partially surrounded by shell material;
wherein the plurality of core-shell particles comprises a cadmium containing core and a zinc containing shell.

2. The method of claim 1 , wherein forming a plurality of cores from the vaporized core precursor material comprises quenching the vaporized core precursor material.

3. The method of claim 2 , wherein quenching the vaporized core precursor material occurs in a quenching chamber comprising one or more exterior walls and a cooling fluid source, at least one exterior wall comprising a plurality of holes, the plurality of holes disposed to receive a flow of cooling fluid from the cooling source.

4. The method of claim 1 , wherein forming a plurality of core-shell particles comprises quenching the plurality of cores after introduction of shell precursor material.

5. The method of claim 4 , wherein quenching the plurality of cores after introduction of shell precursor material comprises introducing a cooling fluid.

6. The method of claim 1 , wherein introducing shell precursor material comprises introducing a fluid to the plurality of cores.

7. The method of claim 6 , wherein the fluid includes the shell precursor material.

8. The method of claim 6 , wherein the fluid reacts with the plurality of cores to form the shell.

9. The method of claim 6 , wherein the fluid is a solution.

10. The method of claim 6 , wherein the fluid is a gas.

11. A method of manufacturing core-shell particles having a core at least partially surrounded by a shell, wherein core material and shell material are chemically distinct; the method comprising:
providing a core precursor material to a material feeding system, the core precursor material being in the form of particles;
introducing a gas or vapor into a first plasma chamber;
generating a plasma in the first plasma chamber using a first energy source, the first energy source in communication with the first plasma chamber and disposed to apply energy to the gas or vapor in the first plasma chamber to form the plasma;
injecting the core precursor material from the material feeding system into the plasma;
vaporizing the core precursor material to form a plurality of cores from the injected core precursor material;
cooling the plurality of cores downstream of the first plasma chamber; and
introducing a shell precursor material to the plurality of cores after cooling to form a plurality of core-shell particles, each core-shell particle having a shell covered core.

12. The method of claim 11 , wherein introducing a shell precursor material comprises injecting the shell precursor material into a second plasma chamber, the second plasma chamber disposed to receive the plurality of cores downstream of the first plasma chamber.

13. The method of claim 12 , further comprising generating a microwave plasma in the second plasma chamber.

14. The method of claim 13 , further comprising quenching of the plurality of product particles downstream of the second plasma chamber.

15. The method of claim 11 , wherein the first energy source comprises a microwave energy source having a radiation frequency from about 900 MHz to about 5900 MHz.

16. The method of claim 11 , wherein the material feeding system is heated.

17. The method of claim 11 , wherein the shell precursor material comprises a fluid.

18. The method of claim 11 , wherein the core precursor material comprises cadmium.

19. The method of claim 11 , wherein the shell precursor material comprises zinc.

Assignees

• 6K Inc

Inventors

• Hadidi Kamal
• Wrobel Gregory

Classifications

• B22F9/082 Primary

  atomising using a fluid (using centrifugal force B22F9/10) · CPC title

• B22F1/00

  Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties · CPC title

• B22F1/145

  Chemical treatment, e.g. passivation or decarburisation · CPC title

• B22F9/14

  using electric discharge · CPC title

• B22F9/16

  using chemical processes · CPC title