Catalyst for producing light olefins from C4-C7 hydrocarbons

Patent metadata

Field	Value
Publication number	US-11801499-B2
Application number	US-202117359360-A
Country	US
Kind code	B2
Filing date	Jun 25, 2021
Priority date	Dec 26, 2018
Publication date	Oct 31, 2023
Grant date	Oct 31, 2023

Abstract

The present invention relates to a catalyst for producing light olefins from C4-C7 hydrocarbons from catalytic cracking reaction and the production process of light olefins from said catalyst, wherein said catalyst has core-shell structure comprising a zeolite core with mole ratio of silicon to aluminium (Si/Al) between 2 to 250 and layered double hydroxide shell (LDH). The catalyst according to the invention provides high percent conversion of substrate to products and high selectivity to light olefins product.

First claim

The invention claimed is:

1. A catalyst for producing light olefins from C4-C7 hydrocarbons, wherein said catalyst has a core-shell structure comprising a zeolite core with mole ratio of silicon to aluminium (Si/Al) between 2 to 250 and a layered double hydroxide shell and said zeolite is a hierarchical zeolite.

2. The catalyst according to claim 1 , wherein said zeolite is the hierarchical zeolite comprising a micropore with size between 0.3 to 0.6 nm, a mesopore with size between 2 to 10 nm, and a macropore with size larger than 50 nm, wherein the mesopore and macropore proportions are greater than or equal to 15 to 60% when compared to a total pore volume.

3. The catalyst according to claim 1 , wherein said zeolite has the mole ratio of silicon to aluminium between 15 to 30.

4. The catalyst according to claim 3 , wherein said zeolite has the mole ratio of silicon to aluminium of equal to 15.

5. The catalyst according to claim 1 , wherein said zeolite is selected from zeolite types ZSM-5, FAU, MOR, BETA or FER.

6. The catalyst according to claim 1 , wherein said zeolite has a crystal size between 100 to 3,000 nm.

7. The catalyst according to claim 1 , wherein the primary metals presented in said layered double hydroxide are the group 2 metals and the group 3 metals.

8. The catalyst according to claim 7 , wherein the primary metals presented in said layered double hydroxide are magnesium (Mg) and aluminium (Al).

9. The catalyst according to claim 1 , wherein said layered double hydroxide has a mole ratio of magnesium to aluminium between 1 to 3.

10. The catalyst according to claim 9 , wherein said layered double hydroxide has the mole ratio of magnesium to aluminium between 1 to 2.

11. The catalyst according to claim 1 , wherein said layered double hydroxide has a thickness between 100 to 1,000 nm.

12. The catalyst according to claim 1 , wherein the catalyst comprises a core and a shell which has a mass ratio of shell:core between 1:1 to 1:7.

13. The catalyst according to claim 1 , wherein the catalyst comprises a core and a shell which has a mass ratio of shell:core between 1:2 to 1:6.

14. A production process of light olefins from catalytic cracking reaction of C4-C7 hydrocarbons comprising: contacting C4-C7 hydrocarbons with a catalyst, wherein said catalyst has a core-shell structure comprising a zeolite core with mole ratio of silicon to aluminium (Si/Al) between 2 to 250 and a layered double hydroxide shell and said zeolite is a hierarchical zeolite.

15. The process according to claim 14 , wherein said process is operated at temperature between 450 to 650° C. and pressure between atmospheric pressure 1 to 5 bars.

16. The process according to claim 14 or 15 , wherein the C4-C7 hydrocarbons are selected from butane, pentane, hexane, or heptane.

17. The process according to claim 16 , wherein the C4-C7 hydrocarbons are pentane.

18. The process according to claim 14 , wherein the light olefins are ethylene and propylene.

Assignees

• Ptt Global Chemical Public Co Ltd

Inventors

• Wattanakit Chularat
• Rodaum Chadatip
• Thivasasith Anawat
• Pengpanich Sitthiphong

Classifications

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• C07C2529/18

  of the mordenite type · CPC title

• C07C2529/04

  having base-exchange properties, e.g. crystalline zeolites, pillared clays · CPC title

• C07C2529/08

  of the faujasite type, e.g. type X or Y · CPC title

• C07C2529/65

  of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38 · CPC title