Methods for conditioning an ethylene epoxidation catalyst and associated methods for the production of ethylene oxide

Patent metadata

Field	Value
Publication number	US-11801493-B2
Application number	US-201716465445-A
Country	US
Kind code	B2
Filing date	Nov 29, 2017
Priority date	Dec 2, 2016
Publication date	Oct 31, 2023
Grant date	Oct 31, 2023

Abstract

Methods for conditioning an ethylene epoxidation catalyst are provided. The conditioning methods comprise contacting an ethylene epoxidation catalyst comprising a carrier, having silver and a rhenium promoter deposited thereon, with a conditioning feed gas comprising oxygen for a period of time of at least 2 hours at a temperature that is above 180° C. and at most 250° C., wherein the contacting of the ethylene epoxidation catalyst with the conditioning feed gas occurs in an epoxidation reactor and in the absence of ethylene. Associated methods for the epoxidation of ethylene are also provided.

First claim

That which is claimed is:

1. A method for the conditioning of an ethylene epoxidation catalyst comprising:
contacting an ethylene epoxidation catalyst comprising a carrier, having silver and a rhenium promoter deposited thereon, with a conditioning feed gas consisting essentially of oxygen, an inert gas and, optionally, an organic chloride, for a period of time of from 6 to 72 hours at a temperature that is, from at least 185° C. and at most 220° C., wherein the contacting of the ethylene epoxidation catalyst with the conditioning feed gas occurs in a catalyst bed within an epoxidation reactor and in the absence of ethylene, and wherein the catalyst bed comprises the ethylene epoxidation catalyst.

2. The method of claim 1 wherein the conditioning feed gas comprises oxygen in a concentration of from 0.5 to 21 mole %, relative to the total conditioning feed gas.

3. The method of claim 1 wherein the period of time is from 12 to 72 hours.

4. The method of claim 1 wherein the period of time is from 24 hours to 72 hours.

5. The method of claim 1 further comprising contacting the ethylene epoxidation catalyst with a sweeping gas.

6. The method of claim 1 , wherein the inert gas is selected from nitrogen, methane, argon, helium, and a combination thereof.

Assignees

• Shell Oil Co
• Shell Usa Inc

Inventors

• Matusz Marek
• Paddock Robert Lewis
• Yeates Randall Clayton
• Lockemeyer John Robert

Classifications

• B01J23/688 Primary

  with manganese, technetium or rhenium · CPC title

• B01J37/08

  Heat treatment {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J37/14 Primary

  with gases containing free oxygen · CPC title

• C07D301/10 Primary

  with catalysts containing silver or gold · CPC title

• C07D303/04

  containing only hydrogen and carbon atoms in addition to the ring oxygen atoms · CPC title