Method of transporting hydrogen

Patent metadata

Field	Value
Publication number	US-11801474-B2
Application number	US-202117522977-A
Country	US
Kind code	B2
Filing date	Nov 10, 2021
Priority date	Nov 11, 2020
Publication date	Oct 31, 2023
Grant date	Oct 31, 2023

Abstract

A method of transporting hydrogen and natural gas by means of a natural gas conduit system is proposed, especially by means of an existing natural gas conduit system. According to the invention, the hydrogen is recovered only downstream of one or preferably multiple natural gas consumers. This resulted in a stepwise increase in the hydrogen content in the natural gas-hydrogen mixture transported, and the subsequent recovery of the pure hydrogen can be affected more easily and efficiently.

First claim

What is claimed is:

1. A method of transporting hydrogen by means of a natural gas conduit system and of recovering pure hydrogen and on-spec natural gas, comprising the following steps:
(a) providing a natural gas conduit system comprising:
at least one transport conduit through which a natural gas transport stream flows,
a hydrogen introduction site,
at least one natural gas withdrawal site downstream of the hydrogen introduction site and
a hydrogen withdrawal site downstream of the at least one natural gas withdrawal site,

(b) introducing a hydrogen introduction stream into the transport conduit through which the natural gas transport stream flows via the hydrogen introduction site,
(c) discharging a first natural gas withdrawal stream comprising at least a portion of the natural gas transport stream from the transport conduit via a first natural gas withdrawal site,
(d) feeding the first natural gas withdrawal stream to a first membrane separation apparatus, separating the first natural gas withdrawal stream in the first membrane separation apparatus into a first, hydrogen-depleted retentate stream and a first, hydrogen-enriched permeate stream,
(e) discharging the first, hydrogen-enriched retentate stream from the first membrane separation apparatus and feeding the first, hydrogen-enriched retentate stream to a first natural gas consumer,
(f) recycling the first permeate stream into the transport conduit downstream of the first natural gas withdrawal site, which gives a hydrogen-enriched natural gas transport stream that is passed onward,
(g) discharging a first hydrogen withdrawal stream comprising at least a portion of the hydrogen-enriched natural gas transport stream from the transport conduit via the hydrogen withdrawal site,
(h) feeding the first hydrogen withdrawal stream to a second membrane separation apparatus, separating the first hydrogen withdrawal stream in the second membrane separation apparatus into a second, hydrogen-depleted retentate stream and a second, hydrogen-enriched permeate stream,
(i) discharging the second, hydrogen-enriched permeate stream from the second membrane separation apparatus as hydrogen discharge stream, and
(j) discharging the second, hydrogen-depleted retentate stream from the second membrane separation apparatus and recycling the second, hydrogen-enriched retentate stream into the transport conduit downstream of the hydrogen withdrawal site.

2. The method according to claim 1 , wherein the hydrogen discharge stream is fed to and introduced into a PSA system, and a pure hydrogen stream and at least one PSA offgas stream are discharged from the PSA system.

3. The method according to claim 1 , wherein steps (c) to (f), for further natural gas consumers, are repeated at least once, which affords a repeatedly hydrogen-enriched natural gas transport stream that is passed onward.

4. The method according to claim 1 , wherein the second, hydrogen-depleted retentate stream is transported to a second natural gas consumer that is a steam reforming plant, where the second, hydrogen-depleted retentate stream forms part of a steam reforming feed stream.

5. The method according to claim 4 , wherein a crude hydrogen stream is produced by means of the steam reforming plant and is introduced into a PSA system for further purification.

6. The method according to claim 1 , wherein the first, hydrogen-enriched permeate stream and/or the second, hydrogen-enriched permeate stream are compressed.

7. The method according to claim 1 , wherein a hydrogen content of the natural gas transport stream after step (b) is between 5 mol % and 50 mol %, and in that a hydrogen content of the first, hydrogen-depleted retentate stream fed to the first natural gas consumer is less than 1 mol %.

8. The method according to claim 1 , wherein a hydrogen content of the hydrogen discharge stream that is introduced into a PSA system is at least 35 mol %.

9. The method according to claim 1 , wherein the second, hydrogen-depleted retentate stream is recycled into the transport conduit downstream of the first hydrogen withdrawal site, which gives a hydrogen-depleted natural gas transport stream that is passed onward.

Assignees

• Air Liquide
• Lair Liquide Sa Pour Letude Et Lexploitation Georges Claude

Inventors

• Bauer André
• Jozwik Piotr
• Pedzich Dominik

Classifications

• B01D53/229 Primary

  Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption) · CPC title

• B01D53/047

  Pressure swing adsorption · CPC title

• B01D53/225

  Multiple stage diffusion · CPC title

• B01D2256/16

  Hydrogen · CPC title

• B01D2257/104

  Oxygen · CPC title