Cable comprising crosslinked layer obtained from a polymer composition comprising nitrile rubber and ethylene methyl acrylate copolymer

Patent metadata

Field	Value
Publication number	US-11798709-B2
Application number	US-202017102729-A
Country	US
Kind code	B2
Filing date	Nov 24, 2020
Priority date	Nov 28, 2019
Publication date	Oct 24, 2023
Grant date	Oct 24, 2023

Abstract

The present invention relates to a cable comprising a crosslinked layer obtained from a polymer composition, the polymer composition comprising: a polymer blend comprising an ethylene vinyl acetate (EVA) copolymer, nitrile rubber (NBR), and an ethylene-methyl acrylate (EMA) copolymer; a crosslinking agent; and a flame-retardant filler.

First claim

What is claimed is:

1. A cable comprising a crosslinked layer obtained from a polymer composition, the polymer composition comprising:
a polymer blend comprising an ethylene vinyl acetate (EVA) copolymer, nitrile rubber (NBR), and an ethylene-methyl acrylate (EMA) copolymer;
a crosslinking agent; and
a flame-retardant filler,
wherein the ethylene vinyl acetate copolymer has a vinyl acetate (VA) content of less than 40 wt %, over the total weight of the ethylene vinyl acetate copolymer,
wherein the polymer blend comprises, based on 100 parts by weight of the polymer blend, 15 to 30 parts by weight of the ethylene-vinyl acetate copolymer, 35 to 45 parts by weight of the nitrile rubber, and 25 to 50 parts by weight of the ethylene-methyl acrylate copolymer.

2. The cable of claim 1 , wherein the nitrile rubber is selected from among nitrile rubber having an acrylonitrile content of 42 to 46 wt %, nitrile rubber having an acrylonitrile content of 36 to 41 wt %, and nitrile rubber having an acrylonitrile content of 31 to 35 wt %, over the total weight of the nitrile rubber.

3. The cable of claim 1 , wherein the ethylene methyl acrylate copolymer is an amorphous polymer, and has an absorbance ratio of 1 to 6 as calculated by the following equation 1:
Absorbance ratio=(absorbance by C═O stretch bond)/(absorbance by C—H stretch bond)

4. The cable of claim 1 , wherein the ethylene-vinyl acetate copolymer comprises a modified ethylene-vinyl acetate copolymer grafted with a polar group-containing compound.

5. The cable of claim 1 , wherein the polymer composition comprises, as the flame-retardant filler, aluminum hydroxide (Al(OH) 3 ), magnesium hydroxide (Mg(OH) 2 ), or a mixture thereof.

6. The cable of claim 1 , wherein the polymer composition comprises organic peroxide as the crosslinking agent.

7. The cable of claim 1 , wherein the polymer composition further comprises one or more additives selected from the group consisting of a crosslinking coagent, a plasticizer, a processing aid, an antioxidant, an antiozonant, and an inorganic additive.

8. The cable of claim 1 , wherein the polymer composition comprises 100 parts by weight of the polymer blend, 120 to 180 parts by weight of the flame-retardant filler, 0.5 to 10 parts by weight of the crosslinking agent, 0.5 to 7 parts by weight of a crosslinking coagent, 5 to 20 parts by weight of a plasticizer, 0.5 to 5 parts by weight of a processing agent, 0.5 to 7 parts by weight of an antioxidant, 0.1 to 5 parts by weight of an antiozonant, and 1 to 20 parts by weight of an inorganic additive, wherein the parts by weight are based on 100 parts by weight of the polymer blend.

9. The cable of claim 1 , wherein the crosslinked layer is a sheath layer.

10. The cable of claim 1 , wherein the cable is a cable for a ship or an offshore plant.

11. A crosslinkable polymer composition for use in a cable, the crosslinkable polymer composition comprising: a polymer blend comprising an ethylene vinyl acetate (EVA) copolymer, nitrile rubber (NBR), and an ethylene-methyl acrylate (EMA) copolymer; a crosslinking agent; and a flame-retardant filler,
wherein the ethylene vinyl acetate copolymer has a vinyl acetate (VA) of less than 40 wt % over the total weight of the ethylene vinyl acetate copolymer,
wherein the polymer blend comprises, based on 100 parts by weight of the polymer blend, 15 to 30 parts by weight of the ethylene-vinyl acetate copolymer, 35 to 45 parts by weight of the nitrile rubber, and 25 to 50 parts by weight of the ethylene-methyl acrylate copolymer.

12. The crosslinkable polymer composition of claim 11 , which is for use in a cable for a ship or an offshore plant.

13. The crosslinkable polymer composition of claim 11 , which is for use in a sheath layer of a cable.

14. A cable comprising a crosslinked layer obtained from a polymer composition, the polymer composition comprising:
a polymer blend comprising an ethylene vinyl acetate (EVA) copolymer, nitrile rubber (NBR), and an ethylene-methyl acrylate (EMA) copolymer;
a crosslinking agent; and
a flame-retardant filler,
wherein the ethylene vinyl acetate copolymer has a vinyl acetate (VA) content of less than 40 wt %, over the total weight of the ethylene vinyl acetate copolymer,
wherein the polymer composition comprises 100 parts by weight of the polymer blend, 120 to 180 parts by weight of the flame-retardant filler, 0.5 to 10 parts by weight of the crosslinking agent, 0.5 to 7 parts by weight of a crosslinking coagent, 5 to 20 parts by weight of a plasticizer, 0.5 to 5 parts by weight of a processing agent, 0.5 to 7 parts by weight of an antioxidant, 0.1 to 5 parts by weight of an antiozonant, and 1 to 20 parts by weight of an inorganic additive, wherein the parts by weight are based on 100 parts by weight of the polymer blend.

15. A crosslinkable polymer composition for use in a cable, the crosslinkable polymer composition comprising: a polymer blend comprising an ethylene vinyl acetate (EVA) copolymer, nitrile rubber (NBR), and an ethylene-methyl acrylate (EMA) copolymer; a crosslinking agent; and a flame-retardant filler,
wherein the ethylene vinyl acetate copolymer has a vinyl acetate (VA) of less than 40 wt % over the total weight of the ethylene vinyl acetate copolymer,
wherein the polymer composition comprises 100 parts by weight of the polymer blend, 120 to 180 parts by weight of the flame-retardant filler, 0.5 to 10 parts by weight of the crosslinking agent, 0.5 to 7 parts by weight of a crosslinking coagent, 5 to 20 parts by weight of a plasticizer, 0.5 to 5 parts by weight of a processing agent, 0.5 to 7 parts by weight of an antioxidant, 0.1 to 5 parts by weight of an antiozonant, and 1 to 20 parts by weight of an inorganic additive, wherein the parts by weight are based on 100 parts by weight of the polymer blend.

16. The crosslinkable polymer composition of claim 15 , which is for use in a cable for a ship or an offshore plant.

17. The crosslinkable polymer composition of claim 15 , which is for use in a sheath layer of a cable.

Assignees

• Nexans

Inventors

• Ahn Dae-Up
• Lim Jong-Chan

Classifications

• H01B7/187 Primary

  Sheaths comprising extruded non-metallic layers · CPC title

• C08L23/0853

  Ethylene vinyl acetate copolymers · CPC title

• C08L33/12

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C08L33/20

  Homopolymers or copolymers of acrylonitrile (C08L55/02 takes precedence) · CPC title

• C08K5/14

  Peroxides · CPC title