Aluminum-based coating for flat steel products for press mold hardening components, and method for producing same

Patent metadata

Field	Value
Publication number	US-11795535-B2
Application number	US-201917420344-A
Country	US
Kind code	B2
Filing date	Dec 27, 2019
Priority date	Jan 4, 2019
Publication date	Oct 24, 2023
Grant date	Oct 24, 2023

Abstract

An aluminum-based coating of a flat steel product is applied in a hot-dipping method and comprises a mass percentage of silicon within a given range. The coating for a flat steel product, in particular for press mold hardening components, offers a shortened required minimum oven dwell time and a sufficiently large processing window when heating in an oven. This is achieved in that the surface of the coating has a degree of absorption for thermal radiation ranging between 0.35 and 0.95 prior to an annealing treatment, where the degree of absorption relates to an oven temperature ranging from 880 to 950° C. during the austenitizing annealing treatment. The invention additionally relates to an improved method for producing a flat steel product with an aluminum-based coating, to an inexpensive method for producing press-hardened components from such flat steel products, and to a press-hardened component made of such flat steel products.

First claim

The invention claimed is:

1. A flat steel product for a subsequent annealing treatment in an austenitizing manner in a furnace at a furnace temperature in the range of 880° C. to 950° C., the flat steel product comprising:
an aluminum-based coating, wherein the coating comprises an aluminum-based coat applied by hot-dipping and has 1.8 to 15 mass percent silicon, wherein the surface of the coating has a degree of absorption for thermal radiation between 0.35 and 0.95, and wherein the degree of absorption is related to the furnace temperature in the aforementioned range during the austenitizing annealing treatment.

2. The flat steel product as claimed in claim 1 , wherein the degree of absorption is 0.40 to 0.80.

3. The flat steel product as claimed in claim 1 , wherein an iron proportion in the coat is less than 5 mass percent.

4. The flat steel product as claimed in claim 1 , wherein the coat additionally comprises admixtures of one or more of Zn, Mg, Mn, Ti, Pb, Ni, Zr, Hf, Ce, and La at a maximum of 30 mass percent in total.

5. The flat steel product as claimed in claim 1 , wherein the coat has, starting from the surface within the first 0.05 μm, an average silicon content between 25 and 70 mass percent.

6. The flat steel product as claimed in claim 5 , wherein the coat has, starting from the surface within the first 0.05 μm, an average silicon content between 30 and 60 mass percent.

7. The flat steel product as claimed in claim 1 , further comprising a cover layer formed on the surface of the coat and wherein the cover layer has a mass proportion of aluminum oxide and/or aluminum hydroxide of at least 50%, said cover layer having been produced by electrochemical anodising, plasma oxidation or plasma-electrolytic oxidation.

8. The flat steel product as claimed in claim 7 , wherein the average layer thickness of the cover layer is less than 1 μm and greater than 0.05 μm.

9. A method for producing a flat steel product for a subsequent annealing treatment in an austenitizing manner in a furnace at a furnace temperature in the range of 880° C. to 950° C., the flat steel product comprising an aluminum-based coating having 1.8 to 15 mass percent silicon, comprising:
applying as a coating an aluminum-based coat to the flat steel product in a hot-dipping process;
subjecting the flat steel product with the coat to an erosive surface treatment after the hot-dipping process, in which, starting from the surface of the coating, aluminum is at least partially removed chemically or electrochemically from the coating in order to increase the percentage proportion of silicon in comparison with the proportion of aluminum in the surface of the coat such that the surface of the coating has a degree of absorption for thermal radiation between 0.35 and 0.95, wherein the degree of absorption is related to the furnace temperature in the aforementioned range during the austenitizing annealing treatment.

10. The method as claimed in claim 9 , wherein by reason of the erosive surface treatment in the coating starting from the surface of the coating within the first 0.05 μm an average silicon content is set between 25 and 70 mass percent.

11. The method as claimed in claim 9 , wherein for the erosive surface treatment an aqueous medium containing alkali metal hydroxides or alkali carbonates is used to at least partially remove aluminum.

12. The method as claimed in claim 11 , wherein the aqueous medium has a pH value >10.

13. The method as claimed in claim 11 , wherein the aqueous medium contains fluorides.

14. The method as claimed in claim 11 , wherein the aqueous medium contains surfactants and/or wetting agents.

15. The method as claimed in claim 11 , wherein the erosive surface treatment is performed in a dipping or injection method.

16. The method as claimed in claim 9 , wherein the erosive surface treatment is effected in a continuous process following the hot-dipping process.

17. The method as claimed in claim 9 , wherein, during the erosive surface treatment, a mass loss of the coat of 0.2 to 20 g/m 2 is maintained for each side of the flat steel product on which the coat is applied.

18. The method as claimed in claim 17 , wherein, during the erosive surface treatment, a mass loss of the coat of 1.0 to 5 g/m 2 is maintained for each side of the flat steel product on which the coat is applied.

19. The method as claimed in claim 9 , further comprising producing an oxidic cover layer on the surface of the coat following the erosive surface treatment, wherein the oxidic cover layer is produced by electrochemical anodising, plasma oxidation or plasma-electrolytic oxidation of the surface of the coat.

20. The method as claimed in claim 19 , wherein an average layer thickness of the cover layer of less than 1 μm and greater than 0.05 μm is produced.

21. Using a flat steel product according to claim 1 for producing press-hardened components,
wherein the flat steel product is heated at least in sections to a temperature above austenitization temperature Ac3; and
wherein the heated sections are subsequently formed and cooled at a rate which is above the critical cooling rate for martensite formation.

Assignees

• Salzgitter Flachstahl Gmbh

Inventors

• Debeaux Marc
• Luther Friedrich
• Koll Thomas

Classifications

• C21D8/04

  to produce plates or strips for drawing, e.g. for deep-drawing · CPC title

• C21D8/02

  during manufacturing of plates or strips (C21D8/12 takes precedence) · CPC title

• C21D8/00

  Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment (hardening articles or materials formed by forging or rolling with no further heating beyond that required for the formation C21D1/02) · CPC title

• C23C2/12 Primary

  Aluminium or alloys based thereon · CPC title

• B32B3/00

  Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form · CPC title