Anionic-cationic-nonionic surfactant,production and use thereof
US-2017313928-A1 · Nov 2, 2017 · US
US11795381B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11795381-B2 |
| Application number | US-202218053647-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 8, 2022 |
| Priority date | Jul 29, 2016 |
| Publication date | Oct 24, 2023 |
| Grant date | Oct 24, 2023 |
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The invention includes a method of reducing a need to re-acidize a hydrocarbon-containing formation. The method comprises providing a composition a HCl and lysine mixture and water wherein a molar ratio between the HCl and the lysine mixture ranges between 3:1 and 12.5:1, and the composition has an initial pH of less than 1; injecting the composition into the formation; allowing a sufficient time for the composition to become a spent acid composition and to subsequently create wormholes in the formation by dissolving calcium carbonate in the formation; maintaining the dissolved calcium carbonate in suspension in the spent acid composition to prevent reprecipitation of the calcium carbonate into the wormholes; removing the spent acid composition containing the dissolved calcium carbonate from the formation; and wherein a pH of the spent acid composition ranges between 4 and 6.
Opening claim text (preview).
The invention claimed is: 1. A method of reducing a need to re-acidize a hydrocarbon-containing formation, said method comprising: providing a composition comprising a HCl and lysine mixture and water; wherein a molar ratio between the HCl and the lysine mixture ranges between 3:1 and 12.5:1, and said composition has an initial pH of less than 1; injecting said composition downhole at a desired injection rate into said hydrocarbon-containing formation and injecting at a pressure below a fracking pressure of the hydrocarbon-containing formation; allowing a sufficient period of time for the injected composition to contact said hydrocarbon-containing formation to become a spent acid composition and to subsequently create wormholes in said hydrocarbon-containing formation by dissolving calcium carbonate in said hydrocarbon-containing formation; maintaining the dissolved calcium carbonate in suspension in the spent acid composition to prevent reprecipitation of the calcium carbonate into said wormholes; removing the spent acid composition containing the dissolved calcium carbonate from said hydrocarbon-containing formation; and wherein a pH of the spent acid composition ranges between 4 and 6.
combined with additives added for specific purposes · CPC title
inorganic depositions, e.g. sulfates or carbonates · CPC title
Compositions for in situ inhibition of corrosion in boreholes or wells · CPC title
containing inorganic compounds (proppants C09K8/80) · CPC title
containing organic compounds · CPC title
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