Three-dimensional printing

Patent metadata

Field	Value
Publication number	US-11795338-B2
Application number	US-201816603342-A
Country	US
Kind code	B2
Filing date	Jan 26, 2018
Priority date	Jan 26, 2018
Publication date	Oct 24, 2023
Grant date	Oct 24, 2023

Abstract

An example of a build material composition for three-dimensional (3D) printing includes a polymeric or polymeric composite build material and a wetting modifying agent. The wetting modifying agent is: (i) incorporated into the polymeric component of the polymeric or polymeric composite build material and changes the wetting behavior of the polymeric component; or (ii) selected from the group consisting of: a fluorotelomer; a C 8 -C 20 alcohol; a methyltrialkyl ammonium chloride; docusate sodium salt; a polymer having a chemical structure of the polymeric component of the polymeric or polymeric composite build material modified to include a hydrophobic group or a hydrophilic group; and a combination thereof.

First claim

What is claimed is:

1. A build material composition for three-dimensional (3D) printing, comprising:
a polymeric or polymeric composite build material; and
a solid wetting modifying agent mixed with the polymeric or polymeric composite build material, wherein the solid wetting modifying agent is:
(i) present in the build material composition in an amount ranging from about 0.01 wt % to about 5 wt %, based on a total weight of the build material composition;
(ii) a surfactant that is incorporated into a polymeric component of the polymeric or polymeric composite build material by being embedded in a surface of the polymeric component and changes the wetting behavior of the polymeric component; and
(iii) selected from the group consisting of:
a fluorotelomer;
a C8-C20 alcohol;
a methyltrialkyl ammonium chloride;
docusate sodium salt;
a polymer having a chemical structure of the polymeric component of the polymeric or polymeric composite build material modified to include a hydrophobic group or a hydrophilic group; and
a combination thereof.

2. The build material composition as defined in claim 1 wherein the solid wetting modifying agent is selected from the group consisting of the fluorotelomer, the methyltrialkyl ammonium chloride, the docusate sodium salt, and a combination thereof.

3. The build material composition as defined in claim 1 wherein the solid wetting modifying agent is selected from the group consisting of silica nanopowder, polyvinyl alcohol, polyethylene glycol, and a combination thereof, and wherein the polymeric or polymeric composite build material is a powder material.

4. The build material composition as defined in claim 1 wherein the solid wetting modifying agent is the fluorotelomer, the C8-C20 alcohol, the methyltrialkyl ammonium chloride, the docusate sodium salt, or a combination thereof, and the amount ranges from about 0.01 wt % to about 0.05 wt %, based on the total weight of the build material composition.

5. The build material composition as defined in claim 1 wherein the solid wetting modifying agent is the polymer having the chemical structure of the polymeric component modified to include the hydrophobic group or the hydrophilic group, and the amount ranges from about 0.5 wt % to about 5 wt %, based on the total weight of the build material composition, and wherein the polymeric or polymeric composite build material is a powder material.

6. The build material composition as defined in claim 1 wherein the solid wetting modifying agent includes the polymer having the chemical structure of the polymeric component modified to include the hydrophobic group or the hydrophilic group, and the solid wetting modifying agent has an average particle size ranging from about 2 μm to about 200 μm, and wherein the polymeric or polymeric composite build material is a powder material.

7. The build material composition as defined in claim 1 wherein the polymeric component of the polymeric or polymeric composite build material is selected from the group consisting of polyamides, polyethylene, polyoxomethylene, polystyrene, polycarbonate, polyester, polyurethanes, and mixtures thereof.

8. A method of forming the build material composition for three-dimensional (3D) printing of claim 1 , comprising:
mixing the surfactant, a solvent, and the polymeric component of the polymeric or polymeric composite build material, whereby the solvent softens the surface of the polymeric component and the surfactant becomes embedded in the softened surface of the polymeric component; and
then, removing the solvent.

9. A method of forming a build material composition for three-dimensional (3D) printing, comprising:
mixing a polymeric or polymeric composite build material with a solid wetting modifying agent, wherein the solid wetting modifying agent is:
(i) present in the build material composition in an amount ranging from about 0.01 wt % to about 5 wt %, based on a total weight of the build material composition;
(ii) a surfactant that is incorporated into a polymeric component of the polymeric or polymeric composite build material by being embedded in a surface of the polymeric component and changes the wetting modifying behavior of the polymeric component; and
(iii) selected from the group consisting of:
a fluorotelomer;
a C 8 -C 20 alcohol;
a methyltrialkyl ammonium chloride;
docusate sodium salt;
a polymer having a chemical structure of a polymeric component of the polymeric or polymeric composite build material modified to include a hydrophobic group or a hydrophilic group; and
a combination thereof.

10. A method for three-dimensional (3D) printing, comprising:
applying a build material composition to form a layer, the build material composition including:
a polymeric or polymeric composite build material; and
a solid wetting modifying agent initially mixed with the build material as part of the build material composition; wherein the solid wetting modifying agent is a surfactant that:
(i) is present in the build material composition in an amount ranging from about 0.01 wt % to about 5 wt %, based on a total weight of the build material composition;
(ii) becomes incorporated into a polymeric component of the polymeric or polymeric composite build material by being embedded in a surface of the polymeric component and changes the wetting behavior of the polymeric component; and
(iii) is selected from the group consisting of:
a fluorotelomer;
a C 8 -C 20 alcohol;
a methyltrialkyl ammonium chloride;
docusate sodium salt;
a polymer having a chemical structure of the polymeric component of the polymeric or polymeric composite build material modified to include a hydrophobic group or a hydrophilic group; and

a combination thereof;
based on a 3D object model, selectively applying a liquid functional agent on the at least the portion of the build material composition, wherein the solid wetting modifying agent controls the penetration of the liquid functional agent; and
based on the 3D object model, forming a 3D part layer from at least the portion of the build material composition.

11. The method as defined in claim 10 wherein:
the liquid functional agent is a fusing agent;
the solid wetting modifying agent controls penetration of the fusing agent into the build material composition; and
the forming of the 3D part layer involves exposing the build material composition to radiation to fuse the at least the portion to form a 3D part layer.

12. The method as defined in claim 10 wherein the solid wetting modifying agent one of:
prevents the liquid functional agent from penetrating beyond a fill volume of the build material composition that corresponds to a portion of the 3D object model; or
causes the liquid functional agent to penetrate all or substantially all of a fill volume of the build material composition that corresponds to a portion of the 3D object model.

Assignees

• Hewlett Packard Development Co

Inventors

• Chaffins Sterling
• Holden Anthony P
• Donovan Katrina
• Hinch Garry

Classifications

• C09D11/38 Primary

  characterised by non-macromolecular additives other than solvents, pigments or dyes · CPC title

• B29C64/165

  using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber · CPC title

• B33Y70/00 Primary

  Materials specially adapted for additive manufacturing · CPC title

• C09D11/102

  containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds · CPC title

• B29K2075/00

  Use of {PU, i.e.} polyureas or polyurethanes {or derivatives thereof}, as moulding material · CPC title